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Heavy Metals Capture from Water Sludge by Kenaf Fibre Activated Carbon in Batch Adsorption

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The Malaysia’s wastewater treatment plant has yet to find an environmentally alternative for the sludge treatment before disposal. In majority of cases, the sludge containing a high amount of heavy metals including Fe, Ti, Mn, Zn, As, Cu, Ni, Zr, and Ga, is disposed to the environment through landfill. The recovery of valuable materials such as manganese from the sludge is an alternative path towards zero dumpings of schedule waste as well as a way of reducing the possible pollutant release to the environment. It can be achieved through adsorption, as it provides a cheap yet flexible, method which is simple and easy to implement. Kenaf derived from Hibiscus cannabis was proven as a good adsorbent material for the heavy metals recovery. This project aims at utilizing Kenaf fiber as activated carbon to recover heavy metals from wastewater sludge in batch adsorption. The adsorbent surface area and pore characteristics and elemental analysis were observed under adsorbent characterization. The effect of contact time, sludge pH and temperature to the removal efficiency was investigated. The adsorption isotherm was also studied. The result showed that the developed kenaf activated carbon is a promising adsorbent which might be used for some heavy metals. From batch adsorption study, it was observed that KFAC is able to remove an average 30% of the heavy metal element from the sludge. It was also found that the best removal is achieved in a neutral pH solution, increasing the contact time will increase the equilibrium uptake, while the increasing temperature will increase the percent removal of heavy metals. It was concluded that the Kenaf based activated carbon can be used for the recovery of heavy metals from the wastewater sludge through batch adsorption.
Rocznik
Strony
102--115
Opis fizyczny
Bibliogr. 21 poz., rys., tab.
Twórcy
  • Department of Chemical Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak, Malaysia
  • Department of Chemical Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak, Malaysia
  • Department of Chemical Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak, Malaysia
Bibliografia
  • 1. Ahmedna M., Marshall W.E., Rao R.M. 2000. Production of granular activated carbons from select agricultural by-products and evaluation of their physical, chemical and adsorption properties. Bioresource Technology, 71(2), 113-123.
  • 2. Asadi F., Shariatmadari H., Mirghaffari N. 2008. Modification of rice hull and sawdust sorptive characteristics for remove heavy metals from synthetic solutions and wastewater. Journal of Hazardous Materials, 154(1-3), 451-458.
  • 3. Chen X. et al. 2011. Adsorption of copper and zinc by biochars produced from pyrolysis of hardwood and corn straw in aqueous solution. Bioresource Technology, 102(19), 8877-8884.
  • 4. Chowdhury Z.Z. 2013. Preparation, characterization and adsorption studies of heavy metals onto activated adsorbent materials derived from agricultural residues. Thesis (Ph.D), Universiti Malaya.
  • 5. Chowdhury Z.Z. et al. 2012. Preparation and characterizations of activated carbon from kenaf fiber for equilibrium adsorption studies of copper from wastewater. Korean Journal of Chemical Engineering, 29(9), 1187-1195.
  • 6. Edokpayi, J.N., Ndlovu S.S., Odiyo J.O. 2019. Characterization of pulverized Marula seed husk and its potential for the sequestration of methylene blue from aqueous solution. BMC Chemistry, 13(1), 10.
  • 7. Everett, D.H., 1972. Manual of symbols and terminology for physicochemical quantities and units, appendix II: Definitions, terminology and symbols in colloid and surface chemistry. Pure and Applied Chemistry, 31(4), 577-638.
  • 8. Gautam R.K. et al. 2014. Biomass-derived biosorbents for metal ions sequestration: Adsorbent modification and activation methods and adsorbent regeneration. Journal of Environmental Chemical Engineering, 2(1), 239-259.
  • 9. Ghorpade A. et al. 2017. Water treatment sludge for removal of heavy metals from electroplating wastewater. Environmental Engineering Research, 23(1), 92-98.
  • 10. Hasfalina C.M. et al. 2010. The potential use of kenaf as a bioadsorbent for the removal of copper and nickel from single and binary aqueous solution. Journal of Natural Fibers, 7(4), 267-275.
  • 11. Hasfalina C.M. et al. 2012. Adsorption of copper (II) from aqueous medium in fixed-bed column by kenaf fibres. APCBEE Procedia, 3, 255-263.
  • 12. Igberase E., Osifo P., Ofomaja A. 2014. The adsorption of copper (II) ions by polyaniline graft chitosan beads from aqueous solution: Equilibrium, kinetic and desorption studies. Journal of Environmental Chemical Engineering, 2(1), 362-369.
  • 13. Khurshid S. et al. 2013. Adsorption study of Nymphaea alba for the removal of manganese from industrial waste water. International Journal of Physical Science, 8(45), 2052-2062.
  • 14. Mahmoud D.K. et al. 2012. Batch adsorption of basic dye using acid treated kenaf fibre char: Equilibrium, kinetic and thermodynamic studies. Chemical Engineering Journal, 181, 449-457.
  • 15. Martin M.J. et al. 2003. Activated carbons developed from surplus sewage sludge for the removal of dyes from dilute aqueous solutions. Chemical Engineering Journal, 94(3), 231-239.
  • 16. Saeed, A.A.H., Harun N.Y., Nasef M.M. 2019. Physicochemical characterization of different agricultural residues in malaysia for bio char production. International Journal of Civil Engineering and Technology (IJCIET), 10(10), 213-225.
  • 17. Sajab M.S. et al. 2010. Removal of copper (II) ions from aqueous solution using alkali-treated kenaf core fibres. Adsorption Science & Technology, 28(4), 377-386.
  • 18. Saravanane R., Sundararajan T., Reddy S.S. 2002. Efficiency of chemically modified low cost adsorbents for the removal of heavy metals from waste water: A comparative study. Indian Journal of Environmental Health, 44(2), 78-87.
  • 19. Shamsuddin M.S., Yusoff N.R.N., Sulaiman M.A. 2016. Synthesis and characterization of activated carbon produced from kenaf core fiber using H3PO4 activation. Procedia Chemistry, 19, 558-565.
  • 20. Shamsudin R., Abdullah H., Sinang S.C. 2015. Properties of oil sorbent material produced from kenaf fiber. International Journal of Environmental Science and Development, 6(7), 551-554.
  • 21. Thitame, P.V. and Shukla S.R., 2016. Porosity development of activated carbons prepared from wild almond shells and coir pith using phosphoric acid. Chemical Engineering Communications 203(6), 791-800.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c56787f2-f81b-4696-8e4c-2774b1868d34
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