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Assessment of Impact of Nickel Additions on Tin Bronzes

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
High prices of tin and its limited resources, as well as several valuable properties characterising Cu-Sn alloys, cause searching for materials of similar or better properties at lower production costs. The influence of various nickel additions to CuSn10 casting bronze and to CuSn8 bronze of a decreased tin content was tested. Investigations comprised melting processes and casting of tin bronzes containing various nickel additions (up to 5%). The applied variable conditions of solidification and cooling of castings (metal and ceramic moulds) allowed to assess these alloys sensitivity in forming macro and microstructures. In order to determine the direction of changes in the analysed Cu-Sn-Ni alloys, the metallographic and strength tests were performed. In addition, the solidification character was analysed on the basis of the thermal analysis tests. The obtained results indicated the influence of nickel in the solidification and cooling ways of the analysed alloys (significantly increased temperatures of the solidification beginning along with increased nickel fractions in Cu-Sn alloys) as well as in the microstructure pattern (clearly visible grain size changes). The hardness and tensile strength values were also changed. It was found, that decreasing of the tin content in the analysed bronzes to which approximately 3% of nickel was added, was possible, while maintaining the same ultimate tensile strength (UTS) and hardness (HB) and improved plasticity (A5).
Rocznik
Strony
53--60
Opis fizyczny
Bibliogr. 18 poz., rys., tab., wykr.
Twórcy
autor
  • AGH-University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland
  • AGH-University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland
autor
  • AGH-University of Science and Technology, Faculty of Foundry Engineering, Kraków, Poland
autor
  • Foundry Research Institute, Kraków, Poland
  • AGH-University of Science and Technology, Faculty of Non-Ferrous Metals, Kraków, Poland
Bibliografia
  • [1] Rzadkosz, S., Zych, J., Garbacz-Klempka, A., Kranc, M., Kozana, J., Piękoś, M., Kolczyk, J., Jamrozowicz, Ł. & Stolarczyk, T. (2015). Copper alloys in investment casting technology. Metalurgija Metallurgy. 54(1), 293-296.
  • [2] Wierzbicka-Miernik, A., Miernik, K., Wojewoda-Budka, J., Litynska-Dobrzynska, L. & Garzel, G. (2015) Microstructure and chemical characterization of the intermetallic phases in Cu/(Sn, Ni) diffusion couples with various Ni additions. Intermetallics. 59, 23-31.
  • [3] Wierzbicka-Miernik, A., Miernik, K., Filipek, R. & Szyszkiewicz, K. (2017). Kinetics of intermetallic phase growth and determination of diffusion coefficients in solid–solid-state reaction between Cu and (Sn+1at.%Ni) pads, Journal of Materials Science Metals. 52(17), 10533-10544. DOI:10.1007/s10853-017-1187-2.
  • [4] Shankar, K.V. & Sellamuthu, R. (2016). An investigation on the effect of nickel content on the wear behaviour and mechanical properties of spinodal bronze alloy cast in metal mould, International Journal of Materials Engineering Innovation. 7(2), 89-103.
  • [5] Baheti, V.A., Islam, S., Kumar, P., Ravi, R., Narayanan, R., Hongqun, D., Vuorinen, V., Laurila, T. & Paul, A. (2015). Effect of Ni content on the diffusion-controlled growth of the product phases in the Cu(Ni)–Sn system. Philosophical Magazine. 96(1), 1-16. DOI:10.1080/ 14786435.2015.1119905.
  • [6] Baheti, V.A., Kashyap, S., Kumar, P., Chattopadhyay, K. & Paul, A. (2017). Effect of Ni on growth kinetics, microstructural evolution and crystal structure in the Cu(Ni)–Sn system. Philosophical Magazine. 97(21), 1782-1802.
  • [7] Ilangovan, S. & Sellamuthu, R. (2012). An investigation of the effect of Ni content and hardness on the wear behaviour of sand cast Cu-Ni-Sn alloys, International Journal of Microstructure and Materials Properties. 7(40), 316-328. DOI: 10.1504/IJMMP.2012.048522.
  • [8] Romankiewicz, F. (1995). Solidification of copper and copper alloys. Material Sciences Commission of the Polish Academy of Sciences, Zielona Góra: WSI.
  • [9] Chakrabarti, D. J., Laughlin, D. E., Chen, S. W. & Chang, Y. A. (1994) Phase diagrams of binary copper alloys. In: Subramanian, P. R., Chakrabarti, D. J., Laughlin, D. E., (Eds.) Materials Park, Ohio: ASM International.
  • [10] Abriata, J.P. & Laughlin, D.E. (2004) The Third Law of Thermodynamics and low temperature phase stability. Progress in Materials Science. 49, 367–387.
  • [11] Szajnar, J., Kondracki, M. & Stawarz, M. (2003). Modification of CuSn8 tin bronze and its influence on tin segregation. Archives of Foundry. 3(10), 315-322.
  • [12] Romankiewicz, F. & Głazowska, I. (1998). Modification of CuSn10 tin bronze, Solidification of Metals and Alloys. 37. (in Polish).
  • [13] Nadolski, M. (2017). The evaluation of mechanical properties of high-tin bronzes. Archives of Foundry Engineering. 17(1), 127-130. DOI: 10.1515/afe-2017-0023.
  • [14] Audy, J. & Audy, K. (2009). Effects of microstructure and chemical composition on strength and impact toughness of tin bronzes. MM Science Journal. 6, 124-129.
  • [15] Rzadkosz, S., Garbacz-Klempka, A., Kozana, J., Piękoś, M. & Kranc, M. (2014). Structure and properties research of casts made with copper alloys matrix. Archives of Metallurgy and Materials. 59(2), 775-778.
  • [16] Garbacz-Klempka, A., Czekaj, E., Kozana, J., Perek-Nowak, M. & Piękoś, M. (2015). Influence of Al and Fe additions on structure and properties of Cu-Sn alloys. Key Engineering Materials. 682, 226-235.
  • [17] Eckerlin, P., Kandler, H. (1971) CuNiMg - CuSe. In: Hellwege, K. H., Hellwege, A.M. (Eds.) Structure Data of Elements and Intermetallic Phases Landolt-Börnstein - Group III Condensed Matter, vol. 6. Springer, Berlin, Heidelberg, 505-519. DOI: 10.1007/b19971
  • [18] Schmetterer, C., Rodriguez-Hortala, M. & Flandorfer, H. (2014). Enthalpies of Formation of (Cu,Ni)3Sn, (Cu,Ni)6Sn5- HT and (Ni,Cu)3Sn2- HT. Journal of Phase Equilibria and Diffusion. 35(4), 429-433. DOI: 10.1007/s11669-014-0305-y.
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018)
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c4f4c494-9df8-463a-9216-4999d67d7d99
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