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The Morphology of Eutectic Copper Oxides I (Cu2O) in The Processing of Wire Rod and Wires made from ETP Grade Copper

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EN
Abstrakty
EN
Eutectic copper oxides (Cu2 O) crystallize during the copper solidification process in the ETP grade copper which leads to high oxygen concentrations in interdendritic spaces. It has been experimentally found that they can be regular or elongated, and their size reaches several micrometres. During the multi-cage hot rolling process, homogenization of the oxide distribution in the entire volume of the wire rod occurs. This process is carried out in the soft copper matrix. Throughout the drawing process the fragmentation of oxides transpires along with changes in the shape from angular to more oval in a degree depending on the size of the deformation (wire diameter). Microcracks, fissures and local stress fields in the reinforced copper matrix arise around the oxide particles. The article presents the results of research on the evolution of copper oxides in ingots, wire rods and wires. The results of investigations of the wires properties and the limitations of the drawing process, especially of microwires, are presented.
Twórcy
  • AGH University of Science and Technology in Krakow, Faculty of Non-Ferrous Metals, Al. Mickiewicza 30, 30-059 Kraków, Poland
autor
  • AGH University of Science and Technology in Krakow, Faculty of Non-Ferrous Metals, Al. Mickiewicza 30, 30-059 Kraków, Poland
Bibliografia
  • [1] Copper and copper alloys, ASM Speciality Handbook, Volume 15: Casting, 82 (2011).
  • [2] PN-EN 1976:2013-04, Miedź i stopy miedzi - Wyroby odlewane z miedzi nie przerobione plastycznie.
  • [3] ASTM B152/B152M-13, Standard Specification for Copper Sheet, Strip, Plate, and Rolled Bar
  • [4] M. Zasadzińska, T. Knych, P. Strzępek, B. Jurkiewicz, K. Franczak, Analysis of the strengthening and recrystallization of electrolytic copper (Cu-ETP) and oxygen free copper (Cu-OF), Archives of civil and mechanical engineering 19 (1), 186-193 (2019).
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  • [6] J. Ouyang, H. Yang, A. Tang, Shape controlled synthesis and optical properties of Cu2O micro-spheres and octahedrons, Materials and Design 92, 261-267 (2016).
  • [7] M. J. Siegfried, C. G. Read, K. Choi, Shape Control of Cuprous Oxide Crystals during Electrochemical Growth and Their Shape Dependent Electrochemical and Photoelectrochemical Properties, 212th ECS Meeting, Abstract #1353 (2007).
  • [8] Y. Bai, T. Yang, Q. Gu, G. Cheng, R. Zheng, Shape control mechanism of cuprous oxide nanoparticles in aqueous colloidal solutions, Powder Technology 227, 35-42 (2012).
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  • [12] S. Norasethasopon, K. Yoshida, Prediction of chevron crack initiation in inclusion copper shaped-wire drawing, Engineering Failure Analysis 15, 378-393 (2008).
  • [13] S. Norasethasopon, Chevron Crack Initiation in Multi-Pass Drawing of Inclusion Copper Shaped-Wire, Journal of Metals, Materials and Minerals 21 (1), 1-8 (2011).
  • [14] V. G. Garcia, J. M. Cabrera, J. M. Prado, Role of Cu2O during hot compression of 99.9% pure copper, Materials Science and Engineering A 488, 92-101 (2008).
  • [15] H. Choa, H. Joa, S. Leeb, B. Kimc, Y. Kimd, Effect of reduction ratio, inclusion size and distance between inclusions on wire breaks in Cu fine wiredrawing, Journal of Materials Processing Technology 130-131, 416-420 (2002).
  • [16] Yu. N. Loginov, S. L. Demakov, A. G. Illarionov, M. A. Ivanova, Interaction of a Copper Oxide Particle with Copper in Drawing, Russian Metallurgy (Metally) 11, 947-953 (2012).
  • [17] Y. Wua, X. Liua, J. Zhanga, J. Qina, C. Li, In situ formation of nano-scale Cu-Cu2O composites, Materials Science and Engineering A 527, 1544-1547 (2010).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c4c12fd2-6293-457f-ae7c-d789ef259937
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