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Compared to reverse cationic flotation, the advantages of reverse anionic flotation include relatively lower sensitivity to slimes and lower reagent cost. Besides, anionic collectors were found to have excellent capability of selectively separating an ultrafine magnetite ore. Addition of a small amount of cationic collector into the anionic collector as the collector mixture can improve the metallurgical results of removing silicates in reverse flotation. In this paper, NaOL and DDA were used for reverse flotation of the ultrafine magnetic concentrate. The separation performance of the collector mixture was investigated at different ratios of NaOL and DDA. The results showed that a better separation performance was obtained for the collector mixture than for NaOL alone. There was an optimal molar ratio between NaOL and DDA equal to 10:1. In the flotation system with the presence of the collector mixture, the good selectivity was found when starch was used as a depressor for magnetite and CaO was used as an activator for quartz. The influences of starch and CaO dosages on the separation performance of magnetite, quartz and chlorite had been investigated through micro-flotation tests. The infrared spectral analysis showed stretching vibration peaks of chemical adsorption of the collector mixture on the magnetite surface. The peaks were not present when starch was used as the depressor for magnetite. The closed flotation tests on the magnetic concentrate with the particle size of -25 μm were performed in the laboratory. The Fe concentrate assaying 64.52 % was obtained with Fe recovery of 80.66%, for the Fe content of feed equal to 52.98%.
Słowa kluczowe
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Tom
Strony
724--736
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
autor
- School of Minerals Processing and Bioengineering, Central South University, Changsha, China
autor
- School of Minerals Processing and Bioengineering, Central South University, Changsha, China
autor
- School of Minerals Processing and Bioengineering, Central South University, Changsha, China
autor
- School of Minerals Processing and Bioengineering, Central South University, Changsha, China
autor
- School of Minerals Processing and Bioengineering, Central South University, Changsha, China
autor
- School of Minerals Processing and Bioengineering, Central South University, Changsha, China
Bibliografia
- BHAGYALAXMI K., HRUSHIKESH S., SWAGAT S.R., DAS B., 2103, Investigations on different starches as depressants for iron ore flotation. Miner. Eng., 49, 1-6.
- BRADSHAW D.J., 1997, Synergistic effects between thiol collectors used in the flotation of pyrite, Ph.D. (Chem. Eng.) Thesis, University of Cape Town.
- CHERNYSHOVA I.V., HANUMANTHA RAO K., VIDYADHAR A., 2000, Mechanism of adsorption of long-chain alkylamines on silicates, Langmuir, 16, 8071-8084.
- CRITCHLEY J.K., RIAZ M., 1991, Study of synergism between xanthate and dithiocarbamate collectors in flotation of heazlewoodite, Trans. Inst. Min. Metall., 100, C55-C57.
- Deng T., Yu S., Lotter N.O., Di Feo A., 2010, Laboratory testwork of mixed xanthates for the Raglan ore, In: Proceedings of Canadian Mineral Processors, Ottawa, January 2010, 16, 253-268.
- FILIPPOV L.O., FILIPPOVA I.V., SEVEROV V.V., 2010, The use of collectors mixture in the reverse cationic flotation of magnetite ore: The role of Fe-bearing silicates, Miner. Eng., 23, 91-98.
- FILIPPOV L.O., SEVEROVA V.V., FILIPPOVA I.V., 2014, An overview of the beneficiation of iron ores via reverse cationic flotation, Int. J. Miner. Process., 127, 62-69.
- HANUMANTHA R.K., ANTTI B.M., FORSSBERG K.S.E., 1990, Flotation of mica minerals and selectivity between muscovite and biotite while using mixed anionic/cationic collectors, Miner. Metall. Process., 7,127-132.
- HANUMANTHA R.K., FORSSBERG K.S.E., 1993, Solution chemistry of mixed cationic/anionic collectors and flotation separation of feldspar from quartz, Proceedings of the XVIII International Mineral Processing Congress, Sydney, Australia.
- HANUMANTHA R.K., FORSSBERG K.S.E., 1997, Mixed collector system in flotation, Int. J. Miner. Process., 51 (1-4), 67-79.
- HOUOT R., 1983, Beneficiation of iron ore by flotation-review of industrial and potential applications, Int. J. Miner. Process., 10, 183-204.
- LI L., LIU J.T., WANG Y.T., CAO Y.J., ZHANG H.J., YU H.S., 2009, Experimental research on anionic reverse flotation of hematite with a flotation column. Procedia Earth and Planetary Science, 1, 791-798.
- LU D.F., HU Y.H., LI Q., YU S.L., JIANG T., SUN W., WANG Y.H., 2016, Improving the recovery of fine auriferous pyrite using iso-amylxanthate and its isomeride, Miner. Eng., 92,57-62.
- MA X., MARQUES M., GONTIJO C., 2011, Comparative studies of reverse cationic/anionic flotation of Vale iron ore. Int. J. Miner. Process., 100, 179-183.
- MINGIONE P.A., 1984, Use of dialkyl and diaryl dithiophosphate promoters as mineral flotation agents, Institution of Mining and Metallurgy, London, 19-24.
- NEYMAYER P.L., GEORGE E.S., ANTONIO E.C., 2013, Effect of amine and starch dosages on the reverse cationic flotation of an iron ore, Miner. Eng., 45, 180-184.
- RAO K.H., FORSSBERG K., 1997, Mixed collector systems in flotation, Int. J. Miner. Process., 51,67-79.
- SHEN H., HUANG X., 2005, A review of the development in iron ore processing from 2000 to 2004 . Min. Met. Eng., 25, 26-30 (In Chinese).
- SUN W., HAN H., TAO H., LIU R., 2015, Study on the flotation technology and adsorption mechanism of galena-jamesonite separation, International Journal of Mining Science and Technology, 25, 53-57.
- SUN Z., BAO S.C., WANG J., YIN W., 2014, Optimization and mechanism of gold-bearing sulfide flotation. Rare Metals, 33, 363-368.
- VALDIVIEZO E., OLIVEIRA J.F., 1993, Synergism in aqueous solutions of surfactant mixtures and its effect on the hydrophobicity of mineral surfaces, Miner. Eng., 6, 655-661.
- ZHANG G., LI W., BAI X., 2006, A study of the practice at Diaojuntai mineral processing plant, Met. Min., 357, 37-41 (In Chinese).
Typ dokumentu
Bibliografia
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