Homochiral metal-organic framework [Zn2(d-Cam)2(4,4′-bpy)]n for high-resolution gas chromatographic separations

• Autorzy: Xue X. D , Zhang M. , Xie S. M , Yuan L. M
• Języki publikacji: EN

Abstrakty

EN

The metal-organic framework (MOF) is a kind of new type self-assembly porous coordination polymer, which possesses many characteristics such as homologic hole, controllable size of cave, high specific surface area, and good chemical stability. In this study, a three-dimensional framework [Zn2(d-Cam)2(4,4′-bpy)]n with large homochiral channel and the orderly arrangement of left- and right-handed helices was used as chiral stationary phases (CSPs) in gas chromatography (GC). [Zn2(d-Cam)2 (4,4′-bpy)]n-coated open tubular column was prepared by a dynamic coating method for high-resolution GC. Some racemates, isomers, linear alkanes, and alcohols are used as the targets for separation. The column coating properties efficiency, polarity, and selectivity were studied. The experimental results show that the stationary phase has outstanding selectivity and also possesses good recognition ability toward these compounds.

Słowa kluczowe

EN

metal-organic frameworks; chiral stationary phase; gas chromatography; enantioseparation

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2015
• Tom: Vol. 27, no. 1
• Strony: 15--26
• Opis fizyczny: Bibliogr. 49 poz., rys., tab.

Twórcy

autor

Xue X. D

• Yunnan Normal University Department of Chemistry Kunming 650092 P.R. China

autor

Zhang M.

• East China Normal University Department of Chemistry Shanghai 200241 P.R. China

autor

Xie S. M

• Yunnan Normal University Department of Chemistry Kunming 650092 P.R. China

autor

Yuan L. M

• Yunnan Normal University Department of Chemistry Kunming 650092 P.R. China

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