Możliwości usuwania środków cieniujących ze ścieków

Węgrzyn, A.; Machura, M.; Żabczyński, S.

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Tytuł artykułu

Możliwości usuwania środków cieniujących ze ścieków

Autorzy

Węgrzyn A. , Machura M. , Żabczyński S.

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Warianty tytułu

Possibilities for removal of contrast agents from wastewater

Języki publikacji

Abstrakty

Badania naukowe wskazują na obecność w ściekach związków cieniujących, które w diagnostyce medycznej wykorzystywane są do wizualizacji zmian w tkankach miękkich. Wykazano, że niezmetabolizowane leki, a także produkty ich przemian metabolicznych, trafiają do miejskiej sieci kanalizacyjnej, a następnie do oczyszczalni ścieków. W konwencjonalnych procesach oczyszczania środki cieniujące nie ulegają pełnej mineralizacji i wraz ze ściekami oczyszczonymi przedostają się do wód powierzchniowych. Wykazano, że największą skuteczność usuwania substancji cieniujących (powyżej 80%) uzyskuje się w zaawansowanych procesach utleniania (O3/H2O2, reakcja Fentona, TiO2/H2O2). Skuteczność usuwania tych substancji w procesie osadu czynnego jest mniejsza niż w przypadku zaawansowanego utleniania i wynosi 40÷80%. Ponieważ żadna z obecnie wykorzystywanych technik oczyszczania ścieków nie jest w stanie usunąć wszystkich zanieczyszczeń farmaceutycznych, dlatego poszukuje się nowych rozwiązań (biologicznie produkowane tlenki manganu BioMnOx czy nanocząstki palladu Bio-Pd) oraz łączy się metody fizyczno-chemiczne i biologiczne w celu skuteczniejszego usuwania farmaceutyków ze ścieków.

Scientific studies indicate presence of contrast agents, used for X-ray imaging of soft tissues, in wastewater. Unmetabolized drugs as well as their metabolites enter municipal sewage system and then are discharged into the wastewater treatment plant. Contrast agents are not fully mineralized in conventional treatment processes and enter surface waters with treated wastewater. It was demonstrated that the highest efficacy of contrast media removal (above 80%) was obtained in advanced oxidation processes (AOPs: O3/H2O2, Fenton’s reaction, TiO2/H2O2). The efficacy of contrast media removal using the activated sludge process is lower than in AOPs and ranges from 40 to 80%. As none of the treatment techniques currently used is sufficient to eliminate all the pharmaceutical contaminants, new solutions are tested (biologically produced nanoparticles of manganese oxide, BioMnOx or palladium, Bio-Pd) and a combined approach of physicochemical and biological methods for the effective removal of pharmaceuticals from wastewater is taken into consideration.

Słowa kluczowe

farmaceutyki oczyszczanie ścieków fotoliza zaawansowane metody utleniania reakcja Fentona

pharmaceuticals sewage treatment biodegradation photolysis AOPs

Wydawca

Polskie Zrzeszenie Inżynierów i Techników Sanitarnych, Oddział Dolnośląski

Czasopismo

Ochrona Środowiska

Rocznik

2015

Tom

Vol. 37, nr 1

Strony

55--63

Opis fizyczny

Bibliogr. 80 poz., tab., wykr.

Twórcy

autor

Węgrzyn A.

Politechnika Śląska, Wydział Inżynierii Środowiska i Energetyki, ul. Akademicka 2, 44-100 Gliwice

autor

Machura M.

Politechnika Śląska, Wydział Inżynierii Środowiska i Energetyki, ul. Akademicka 2, 44-100 Gliwice

autor

Żabczyński S.

sebastian.zabczynski@polsl.pl

Politechnika Śląska, Wydział Inżynierii Środowiska i Energetyki, ul. Akademicka 2, 44-100 Gliwice

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