Silver(I) recovery on sulfur-containing polymeric sorbents from chloride solutions

• Autorzy: Pilśniak-Rabiega Magdalena , Wolska Joanna

Identyfikatory

DOI

10.37190/ppmp/130400

• Języki publikacji: EN

Abstrakty

EN

This work describes the preparation of functional polymers containing 2-mercapto-1-methylimidazole and guanylthiourea ligands from chemically modified vinylbenzyl chloride/divinylbenzene copolymer (VBC/DVB). The resins were used for the removal of Ag(I) from synthetic and real chloride solutions. The 2-mercapto-1-methylimidazole resin was highly selective towards Ag(I) in relation to Pb(II) from real chloride leaching solution. The resins were selective for Ag(I) from real chloride solution and they did not sorb chloride complexes of Co(II), Ni(II) and Zn(II). The sorption kinetic data were well fitted to the pseudo-first-order kinetic model. The degree of Ag(I) desorption was about 80% using 1% potassium cyanide solution in 0.5% hydrogen peroxide solution. Resins retain their capacity towards Ag(I) in five consecutive sorption/desorption cycles.

Słowa kluczowe

EN

functional polymers; synthesis; silver(I); sorption; selectivity

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2020
• Tom: Vol. 56, iss. 6
• Strony: 290--310
• Opis fizyczny: Bibliogr. 50 poz., tab., wykr., wz.

Twórcy

autor

Pilśniak-Rabiega Magdalena

• Department of Analytical Chemistry and Chemical Metallurgy, Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

autor

Wolska Joanna

• Department of Process Engineering and Technology of Polymeric and Carbon Materials, Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

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Uwagi

The work was financed by a statutory activity subsidy from the Polish Ministry of Science and Higher Education for the Faculty of Chemistry of Wrocław University of Science and Technology.