Designing of membrane contactors with cross-counter current flow

• Autorzy: Kołtuniewicz A.B. , Modelski S. , Witek A.
• Języki publikacji: EN

Abstrakty

EN

The knowledge about membrane contactors is growing rapidly but is still insufficient for a reliable designing. This paper presents a new type of membrane contactors that are integrated with one of the following ways of separation by using absorbents, micelles, flocculants, functionalized polymers, molecular imprints, or other methods that are based on aggregation. The article discusses methods for designing multi-stage cascade, usually counter-current. At every stage of this cascade, relevant aggregates are retained by the membrane, while the permeate passes freely through membrane. The process takes place in the membrane boundary layer with a local cross-flow of the permeate and the retentate. So the whole system can be called a cross-counter-current. The process kinetics “k” must be coordinated with the permeate flux “J” and the rate of surface renewal of the sorbent on the membrane surface, s. This can be done by using ordinary back-flushing or relevant hydrodynamic method of sweeping, such as: turbulences, shear stresses or lifting forces. A surface renewal model has been applied to adjust the optimal process conditions to sorbent kinetics. The experimental results confirmed the correctness of the model and its suitability for design of the new type of contactors.

Słowa kluczowe

EN

membrane contactor; sorption process; integrated processes of separation; designing; surface renewal theory

PL

stycznik membranowy; proces sorpcji; zintegrowany proces separacji; projektowanie; teoria odnowienie powierzchni

• Wydawca: Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk
• Czasopismo: Chemical and Process Engineering
• Rocznik: 2012
• Tom: Vol. 33, nr 4
• Strony: 573--583
• Opis fizyczny: Bibliogr. 18 poz., rys., tab.

Twórcy

autor

Kołtuniewicz A.B.

• Warsaw University of Technology, Faculty of Chemical and Process Engineering, Waryńskiego 1, 00-645 Warszawa, Poland

autor

Modelski S.

• Wroclaw University of Technology, Faculty of Chemistry, Norwida 4/6, 50-373, Wroclaw, Poland

autor

Witek A.

• Wroclaw University of Technology, Faculty of Chemistry, Norwida 4/6, 50-373, Wroclaw, Poland

Bibliografia

• 1. Ding H.B., Carr P.W., Cussler E.L., 1992. Racemic leucine separation by hollow-fiber extraction. AIChE J., 38, 1493-1498. DOI: DOI: 10.1002/aic.690381002.
• 2. Drioli E., Giorno L., 2005. Membrane Contactors: Fundamentals, 1st edition, ELSEVIER. Commercial Brochure of Liqui Cel®, Membrana, 2012. North Carolina, USA.
• 3. Einstein H.A., Li H., 1956. The viscous sublayer along a smooth boundary. J. Eng. Mech. Div. ASCE, 82, EM2. Koltuniewicz A.B., 1992. Predicting permeate flux in ultrafiltration on the basis of surface renewal concept. J. Membrane Sci., 68, 107-118. DOI: 10.1016/0376-7388(92)80153-B.
• 4. Koltuniewicz A.B., Field R.W., 1996. Process factors during removal of oil-in-water emulsions with cross-flow microfiltration. Desalination, 105, 79- 89. DOI: 10.1016/0011-9164(96)00063-X.
• 5. Koltuniewicz A.B., Bezak K., 2002. Engineering of membrane biosorption. Desalination, 144, 219-226. DOI: 10.1016/S0011-9164(02)00315-6.
• 6. Koltuniewicz A.B., Witek A., Bezak K., 2004. Efficiency of membrane-sorption integrated processes. J. Membrane Sci., 239, 129–141. DOI: 10.1016/j.memsci.2004.02.037.
• 7. Koltuniewicz A.B., Drioli E., 2008. Membranes in clean technologies, theory and practice. Wiley-VCH.
• 8. Koltuniewicz A.B., 2010. Integrated membrane operations in various industrial sectors, In: Drioli E., Giorno L. (Eds.), Comprehensive membrane science and engineering. ELSEVIER, chapter 4.05.1.
• 9. Koltuniewicz A.B., 2011. Process engineering for sustainability, In: Encyclopedia of Life Support Systems. UNESCO EOLSS, chapter 6.34.7.1.
• 10. Modelski Sz., Kołtuniewicz A.B., Witek-Krowiak A., 2011. Kinetics of VOC absorption using capillary membrane contactor. Chem. Eng. J., 168, 1016–1023. DOI: 10.1016/j.cej.2011.01.075.
• 11. Kumar P.S., Hogendorn J.A., Feron P.H.M., Versteeg G.F., 2002. New absorption liquids for the removal of CO2 from diluted gas streams using membrane contactors. Chem. Eng. Sci., 57, 1639-1651. DOI: 10.1016/S00092509(02)00041-6.
• 12. Pagnanelli A.F., Beolchini F., Di Biase A., Veglio V., 2003. Effect of equilibrium models in the simulation of heavy metals biosorption in single and two-stage UF/MF membrane reactor systems. Biochem. Eng. J., 15, 27– 35. DOI: 10.1016/S1369-703X(02)00179-1.
• 13. Reed B.W., Siemens M.J., Cussler E.L., 1995. Membrane contactors, In: Noble R.D., Sern S.A. (Eds.), Membrane Separations Technology, Principles and Applications. ELSEVIER SCIENCE, Amsterdam, the Netherlands, Chapter 10.
• 14. Stankiewicz A., Moulin J.A., 2004. Re-engineering the chemical processing plant. Process intensification. Marcel Dekker, Inc., New York.
• 15. Witek A., Koltuniewicz A.B., Kurczewski B., Radziejowska M., Hatalski M., 2006. Simultaneous removal of phenols and Cr3+ using micellar-enhanced ultrafiltration process. Desalination, 191, 111–116. DOI: 10.1016/j.desal.2005.05.024.
• 16. Witek A., Szafran R.G., Koltuniewicz A.B., 2006. p-Cresol removal using a membrane contactor enhanced by the micellar solubilization, Desalination, 200, 575–577. DOI: 10.1016/j.desal.2006.03.453.
• 17. Witek-Krowiak A., Szafran R.G., Koltuniewicz A., 2009. Application of a membrane contactor for a simultaneous removal of p-cresol and Cr(III) ions from water solution, Desalination, 241, 91-96. DOI: 10.1016/j.desal.2007.11.083.
• 18. Yilmaza I., Kabay N., Bryjak M., Yüksela M., Wolska J., Koltuniewicz A.B., 2006. Submerged membrane–ionexchange hybrid process for boron removal. Desalination, 198, 310–315. DOI:10.1016/j.desal.2006.01.031.