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Many countries use nontraditional methods to treat wastewater, especially those with water lacks. Among these methods, heterogeneous photocatalysis is more commonly widely used since it converts organic molecules into carbon dioxide and water. In this study, the photocatalytic degradation process of total organic carbon was investigated by TIO2/UV technique (TUT). This treatment is carried out in a batch recycle reactor using a UV light and catalyst TIO2. The optimum operating parameters were investigated regarding the best organic removal including, total organic carbon concentration, flow rate, pH, irradiation time, and photocatalysis dosage. The result showed that the TUT is affected by reducing total organic carbon (TOC) from synthetic wastewater (SW) by 61% at 50 ml/min of flow rate, 250 mg of catalyst concentration TIO2, and a concentration of TOC of 25 mg/l. Then the result of TUT was compared with a process of combining TIO2/UV and an oxidizing agent (Hydrogen peroxide H2O2). It was found that 73% of organic removal was obtained which is best than TUT when using an H2O2 dosage of 100 mg/l. Experimentally, Ozone was also added to the process of TUT and the result showed that the removal percentage increased to 80%.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
351--359
Opis fizyczny
Bibliogr. 36 poz., rys., tab.
Twórcy
autor
- Department of Chemical Engineering, College of Engineering, University of Basrah , Basra City, Iraq
autor
- Department of Chemical Engineering, College of Engineering, University of Basrah , Basra City, Iraq
Bibliografia
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- 2. Ahmad, R., Ahmad, Z., Khan, A.U., Mastoi, N.R., Aslam, M., Kim, J. 2016. Photocatalytic systems as an advanced environmental remediation: Recent developments, limitations and new avenues for applications. Journal of Environmental Chemical Engineering, 4(4), 4143–4164.
- 3. Akpan, U.G., Hameed, B.H. 2009. Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: a review. Journal of Hazardous Materials, 170(2–3), 520–529.
- 4. Ali, I., Asim,M., Khan, T.A. 2012. Low-cost adsorbents for the removal of organic pollutants from wastewater. Journal of Environmental Management, 113, 170–183.
- 5. Arar, Ö., Yüksel, Ü., Kabay, N., Yüksel, M. 2014. Various applications of electrodeionization (EDI) method for water treatment – A short review. Desalination, 342, 16–22.
- 6. Azimi, A., Azari, A., Rezakazemi, M., Ansarpour, M. 2017. Removal of heavy metals from industrial wastewaters: A review. ChemBioEng Reviews, 4(1), 37–59.
- 7. Baaloudj, O., Assadi, I., Nasrallah, N., El Jery, A., Khezami, L., Assadi, A.A. 2021. Simultaneous removal of antibiotics and inactivation of antibiotic-resistant bacteria by photocatalysis: A review. Journal of Water Process Engineering, 42, 102089
- 8. Baran, W., Makowski, A., Wardas, W. 2008. The effect of UV radiation absorption of cationic and anionic dye solutions on their photocatalytic degradation in the presence TiO2. Dyes and Pigments, 76(1), 226–230.
- 9. Mohamed, A.R. 2011. Roles of titanium dioxide and ion-doped titanium dioxide on photocatalytic degradation of organic pollutants (phenolic compounds and dyes) in aqueous solution: A review. Journal of Alloys and Compounds, 509(5), 1648–1660.
- 10. Chakrabarti, S., Dutta, B.K. 2004. Photocatalytic degradation of model textile dyes in wastewater using ZnO as semiconductor catalyst. Journal of Hazardous Materials, 112(3), 269–278.
- 11. Dhaka S., Kumar R., Lee S Hun, Kurade M.B., Jeon B.H. 2018. Degradation of ethyl paraben in aqueous medium using advanced oxidation process: Efficiency evaluation of UV-C – supported oxidation. J Clean Prod., 180, 505–13.
- 12. Doskaliyev, D., Poulopoulos, S.G., Yeshmuratov, A., Aldyngurova, F., Zorpas, A.A., Inglezakis, V.J. 2018. Effects of 2-chlorophenol and 2, 4, 6-trichlorophenol on an activated sludge sequencing batch reactor. Desalination and Water Treatment, 133, 283–291.
- 13. Hameed, F.M., Mousa, K.M. 2019. Study on Kinetic and Optimization of Continuous Advanced Oxidative Decolorization of Brilliant Reactive Red Dye. Iraqi Journal of Chemical and Petroleum Engineering, 20(1), 9–14.
- 14. Huang, Y., Liu, Y., Kong, M., Xu, E.G., Coffin, S., Schlenk, D., Dionysiou, D.D. 2018. Efficient degradation of cytotoxic contaminants of emerging concern by UV/H2O2. Environmental Science: Water Research & Technology, 4(9), 1272–1281.
- 15. Inglezakis, V.J., Amzebek, A., Kuspangaliyeva, B., Sarbassov, Y., Balbayeva, G., Yerkinova, A., Poulopoulos, S.G. 2018. Treatment of municipal solid waste landfill leachate by use of combined biological, physical and photochemical processes. Desalination and Water Treatment, 112, 218–231.
- 16. Kane, A., Assadi, A.A., El Jery, A., Badawi, A.K., Kenfoud, H., Baaloudj, O., Assadi, A.A. 2022. Advanced photocatalytic treatment of wastewater using immobilized titanium dioxide as a photocatalyst in a pilot-scale reactor: process intensification. Materials, 15(13), 4547.
- 17. Krishnan, S., Rawindran, H., Sinnathambi, C.M., Lim, J.W. 2017. Comparison of various advanced oxidation processes used in remediation of industrial wastewater laden with recalcitrant pollutants. In: IOP Conference Series: Materials Science and Engineering, 206(1), 012089. IOP Publishing
- 18. Kruithof, J.C., Kamp, P.C., Martijn, B.J. 2007. UV/H2O2 treatment: A practical solution for organic contaminant control and primary disinfection. Ozone: Science and Engineering, 29(4), 273–280.
- 19. Ledezma Estrada A., Li Y.Y., Wang A. Biodegradability enhancement of wastewater containing cephalexin by means of the electro-Fenton oxidation process. J Hazard Mater., 227–228, 41–8.
- 20. Mena, E., Rey, A., Beltrán, F.J. 2018. TiO2 photocatalytic oxidation of a mixture of emerging contaminants: A kinetic study independent of radiation absorption based on the direct-indirect model. Chemical Engineering Journal, 339, 369–380.
- 21. Mousset, E., Doudrick, K. 2020. A review of electrochemical reduction processes to treat oxidized contaminants in water. Curr. Opin. Electrochem. 2020, 22, 221–227.
- 22. Nasseh, N., Taghavi, L., Barikbin, B., Nasseri, M.A. 2018. Synthesis and characterizations of a novel FeNi3/SiO2/CuS magnetic nanocomposite for photocatalytic degradation of tetracycline in simulated wastewater. Journal of Cleaner Production, 179, 42–54.
- 23. Poulopoulos, S.G., Nikolaki, M., Karampetsos, D., Philippopoulos, C.J. 2008. Photochemical treatment of 2-chlorophenol aqueous solutions using ultraviolet radiation, hydrogen peroxide and photo-Fenton reaction. Journal of Hazardous Materials, 153(1–2), 582–587.
- 24. Preisner, M. 2020. Surface water pollution by untreated municipal wastewater discharge due to a sewer failure. Environmental Processes,7(3),767–780.
- 25. Ren, G., Han, H., Wang, Y., Liu, S., Zhao, J., Meng, X., Li, Z. 2021. Recent advances of photocatalytic application in water treatment: A review. Nanomaterials, 11(7), 1804.
- 26. Sacco, Vaiano V., Rizzo L., Sannino D. 2018. Photocatalytic activity of a visible light active structured photocatalyst developed for municipal wastewater treatment. J Clean Prod., 175, 38–49.
- 27. Sanchez, L., Peral, J., Domenech, X. 1998. Aniline degradation by combined photocatalysis and ozonation. Applied Catalysis B: Environmental, 19(1), 59–65.
- 28. Sharma, S., Chaturvedi, N., Chaturvedi, R.K., Sharma, M.K. 2010. Ammonium phosphomolybdate mediated photocatalytic degradation of janus green b dye in aqueous solution. I Control Pollution, 26(2), 165–169.
- 29. Tanaka, K., Abe, K., Hisanaga, T. 1996. Photocatalytic water treatment on immobilized TiO2 combined with ozonation. Journal of Photochemistry and Photobiology A: Chemistry, 101(1), 85–87.
- 30. Teh, C.M., Mohamed, A.R. 2011. Roles of titanium dioxide and ion-doped titanium dioxide on photocatalytic degradation of organic pollutants (phenolic compounds and dyes) in aqueous solutions: A review. Journal of Alloys and Compounds, 509(5), 1648–1660.
- 31. Wang, S., Shiraishi, F., Nakano, K. 2002. A synergistic effect of photocatalysis and ozonation on decomposition of formic acid in an aqueous solution. Chemical Engineering Journal, 87(2), 261–271.
- 32. Wilson, F., Lee, W.M. 1997. Rotating biological contactors for wastewater treatment in an equatorial climate. Water Science and Technology, 35(8), 177–184.
- 33. Yagub, M.T., Sen, T.K., Afroze, S., Ang, H.M. 2014. Dye and its removal from aqueous solution by adsorption: a review. Advances in Colloid and Interface science, 209, 172–184.
- 34. Zazouli, M.A., Kalankesh, L.R. 2017. Removal of precursors and disinfection by-products (DBPs) by membrane filtration from water; a review. Journal of Environmental Health Science and Engineering, 15, 1–10.
- 35. Zhang, H., Sun, C. 2021. Cost-effective iron-based aqueous redox flow batteries for large-scale energy storage application: A review. Journal of Power Sources, 493, 229445.
- 36. Zularisam, A.W., Ismail, A.F., Salim, R. 2006. Behaviours of natural organic matter in membrane filtration for surface water treatment – A review. Desalination, 194(1–3), 211–231.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c3232660-902e-4668-a233-81c65a7eea91