Use of isoperibolic reaction calorimeter for the study of reaction kinetics of acetic anhydride hydrolysis reaction: Effect of acetic anhydride and water ratio

• Autorzy: Kumar Rajendra , Tiwari Anurag Kumar

Identyfikatory

DOI

10.24425/cpe.2022.140829

• Konferencja: The International Chemical Engineering Conference 2021 (ICHEEC): 100 Glorious Years of Chemical Engineering and Technology, September 16–19, 2021
• Języki publikacji: EN

Abstrakty

EN

Reaction kinetics of acetic anhydride hydrolysis reaction is being studied at a fixed reaction temperature and ambient pressure using an isoperibolic reaction calorimeter. Temperature versus time data along with heat and mass balance is used to determine the kinetics parameters i.e. activation energy and Arrhenius coefficient. It has been studied with the varying volumetric ratio of acetic anhydride and water; and kinetics parameters were compared and plotted for each ratio. Such a study has not been done previously to determine the kinetics dependency on varying the acetic anhydride water ratio. As the acetic anhydride hydrolysis reaction is exothermic in nature, the present study will help to decide the safe and suitable operating conditions such as concentration and temperature for conducting this reaction at plant scale. The kinetic data presented can be used further for the mathematical modeling and simulation of such exothermic hydrolysis reactions.

Słowa kluczowe

EN

acetic anhydride; water; reaction calorimeter; hydrolysis; kinetics

PL

bezwodnik octowy; woda; kalorymetr reakcyjny; hydroliza; kinetyka

• Wydawca: Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk
• Czasopismo: Chemical and Process Engineering
• Rocznik: 2022
• Tom: Vol. 43, nr 2
• Strony: 255--–264
• Opis fizyczny: Bibliogr. 11 poz., fot., wykr.

Twórcy

autor

Kumar Rajendra

• Scientific and Industrial Research – National Chemical Laboratory, Chemical Engineering and Process Development Division, Pune, India – 411008

autor

Tiwari Anurag Kumar

• Ambedkar National Institute of Technology, Department of Chemical Engineering, Jalandhar, Punjab, India – 144011

Bibliografia

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