PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Observations on the effect of proximity to rhyolitic intrusions on Kübler index

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The Upper Ordovician sedimentary succession of southeast Ireland is riddled with almost synsedimentary igneous intrusions. A study was required to determine any effects of these intrusions on Kübler Index (KI) so that further sampling for a regional study could be undertaken and the results would be unbiased. Sampling was carried out on the low-grade metapelites (Southeast Ireland) around the rhyolitic and doleritic intrusions, which were intruded into the still soft sediment. Clay mineralogy was determined using X-ray diffractometry and KI values were measured; SEM and whole rock elemental analyses were applied to complement the results of the XRD work. KIs immediately around rhyolitic intrusions were observed in all cases to be lower than the regional KI, however this was not seen around doleritic intrusions. SEM work shows illite grain sizes following the KI trend and K2O were noted to be highest where KI was lowest. Rare earth elements (REEs) show some mobilization which also follows the KI trend. This is considered to be a residual effect of hydrothermal fluids / volatiles hosted by the rhyolites but not encountered in the dolerites. Chlorite crystallinity is not affected as it most likely crystallized after the hydrothermal event. The KI is often used as a proxy for illite crystallinity in studies of low grade metamorphism but is influenced by many parameters and care should be taken when applying this technique to studies of regional metamorphism.
Słowa kluczowe
Czasopismo
Rocznik
Strony
75--94
Opis fizyczny
Bibliogr. 33 poz., rys., tab., wykr.
Twórcy
autor
  • Okavango Research Institute, University of Botswana, Private Bag 285 Maun, Botswana
  • Electron Microscope Unit, University of Botswana, Private Bag 704 Gaborone, Botswana
Bibliografia
  • Àrkai, P. (1991). Chlorite crystallinity: an empirical approach and correlation with illite crystallinity, coal rank and mineral facies as exemplified by Palaeozoic and Mesozoic rocks of northwest Hungary. Journal of Metamorphic Geology, 9, 723-734.
  • Àrkai, P., & Sadek Ghabrial, D. (1997). Chlorite Crystallinity as an indicator of metamorphic grade of low temperature meta-igneous rocks: a case study from the Bukk Mountains, Northeast Hungary. Clay Minerals, 32, 205-222.
  • Battaglia, S., Leoni, L., & Sartori, F. (2004). The Kubler Index in Late Diagenetic to low-grade metamorphic pelites: a critical comparison of data from 10Å and 5Å peaks. Clays and Clay Minerals, 56, 85-105.
  • Bisevac, V., Balen, D., Tibljas, D., & Spanic, D. (2009). Preliminary results on degree of thermal alteration recorded in the eastern part of Mt. Papuk, Slavonia, Croatia. Geologia Croatia, 62, 63-72.
  • Blackmore, R.H. (1995). Low-grade metamorphism in the Upper Palaeozoic Munster Basin, southern Ireland. Irish Journal of Earth Sciences, 14, 115-133.
  • Breitschmid, A. (1982). Diagenese und schwache Metamorphose in den sedimentaren Abfolgen der Zentralschweizer Alpen Vierwaldstatter See, Urirotstock). Ecolgae geologica Helvetica, 75, 331-380.
  • Crouzet , C., Dunkl, I., Árkai, P., Balogh, K., & Appel, E. (2007). Temperature and age constraints on the metamorphism of the Tethyan Himalaya in Central Nepal: A multidisciplinary approach. Journal of Asian Earth Sciences, 30, 113–130.
  • Diskin, S. (1996). Low grade metamorphism of the Upper Ordovician Rocks of Southeast Waterford. Unpublished MSc Thesis, University of Dublin, Trinity College.
  • Downes, K. (1974). The geology and geochemistry of the Ordovician volcanics of Co. Waterford. Unpublished PhD Thesis, University of Dublin, Trinity College.
  • Dunoyer de Segonzac, G., Ferrero, J., & Kubler, B. (1968). Sur la cristallinite de L’illite dans la diagenese et l’anchimetamorphisme. Sedimentology, 10, 137-143.
  • Eberl, D.D., & Velde, B. (1989). Beyond the Kubler Index. Clay Minerals, 24, 571-577.
  • Fleet A.J. (1984). Aqueous and sedimentary geochemistry of the rare earth elements. In P. Henderson (Ed.), Rare Earth Element Geochemistry (pp. 343-373). Amsterdam: Elsevier.
  • Frey, M. (1987). Low Temperature Metamorphism. Glasgow: Blackie and Son.
  • Fritz, W.J., & Stillman, C.J. (1996). A subaqueous welded tuff from the Ordovician of County Waterford, Ireland. Journal of Volcanology and Geothermal Research, 70, 91-106.
  • Gardiner, P.R.R. (1974). The Duncannon Group: An upper Ordovician unit in southwest County Waterford. Geological Survey of Ireland Bulletin, 1, 47-52.
  • Gibbs, R.J. (1965). Error due to segregation in quantitative clay-mineral X-ray diffraction mounting techniques. American Mineralogist, 50, 741-751.
  • Guggenheim, S., Bain, D.C., Bergaya, F., Brigatti, M.F., Drits, V.A., Eberl, D.D., Formoso, M.L.L., Galan, E., Merriman, R.J., Peacor, D.R., Stanjek, H., & Watanabe, T. (2002). Report of the Association Internationale pour l’Etude des Argiles (AIPEA) Nomenclature committee for 2001: Order, disorder and crystallinity in phyllosilicates and the use of the ‘Crystallinity Index’. Clay Minerals, 37, 389-393
  • Jaboyedoff, M ., Bussy, F., Kubler, B., & Thelin, Ph. (2001) Illite "Crystallinity" Revisited. Clays and Clay Minerals, 49(2), 156-167.
  • Kim, J.C., Lee, Y.I., & Hisada, K. (2007). Depositional and compositional controls on sandstone diagenesis, the Tetori Group (Middle Jurassic–Early Cretaceous), central Japan. Sedimentary Geology, 195, 183-202.
  • Kisch, H.J. (1987). Correlation between indicators of very low-grade metamorphism. In M. Frey (Ed.), Low Temperature Metamorphism (pp. 227-300). Glasow: Blackie and Son.
  • Kisch, H.J. (1991). Illite crystallinity: recommendations on sample preparation, X-ray diffraction settings and interlaboratory samples. Journal of Metamorphic Geology, 9, 665-670.
  • Kübler, B. (1967). La cristallinité de l’illite et zones tout a fait superieures du metamorphisme. In: Etages tectonique, Colloque de Neuchatel 1966 (pp. 105-121). A la Baconniere, Neuchatel, Suisse.
  • Kübler, B. (1968). Evaluation quantitative du metamorphisme par la cristallinité de l’illite. Bulletin Centre Recherche Pau-SNPA, 2, 385-397.
  • Liu, K.W. (2003). Deep-burial diagenesis of the siliciclastic Ordovician Natal Group, South Africa. Sedimentary Geology, 154, 177-189.
  • Merriman, R.J., Roberts, B., & Peacor, D.R. (1990). A transmission electron microscope study of white-mica crystallite size distribution in a mudstone to slate transitional sequence, North Wales, UK. Contributions to Mineralogy and Petrology, 106, 27-40.
  • Milodowski, A.E., & Zalasiewicz, J.A. (1991). Redistribution of rare earth elements during diagenesis of turbidite/hemipelagite mudrock sequences of Llandovery age from central Wales. In A.C. Morton, S.P. Todd, & P.D.W. Haughton, (Eds.), Developments in Sedimentary Provenance Studies (pp. 101-124). Geological Society, London, Special Publication, 57.
  • Nadeau, P.H., & Reynolds, R.C. (1981). Burial and Contact Metamorphism in the Mancos Shale. Clays and Clay Minerals, 29, 249-259.
  • Roberts, B., & Merriman, R.J. (1985). The distinction between Caledonian Burial and regional metamorphism in pelites from North Wale: an analysis of isocryst patterns. Journal of the Geological Society, London, 142, 615-624.
  • Ruiz Cruz, M.D. (2008). Na-bearing white micas from Triassic rocks of the transition between the Malaguide and Alpujarride Complexes (Beltic Cordillera, Spain). Clays and Clay Minerals, 56, 344-358.
  • Sleeman, A.G., & McConnell. B. (1995). Geology of East Cork-Waterford: A geological description of East Cork, Waterford and adjoining parts of Tipperary and Limerick to accompany the bedrock geology 1:100,000 scale map series, Sheet 22, Geology of East Cork-Waterford.
  • Środoń J. (1984). X-ray powder diffraction identification of illitic materials. Clays & Clay Minerals 32, 337-349.
  • Środoń J., & Eberl D. D. (1984). Illite. In S.W.Bailey (Ed.) Micas. Reviews in Mineralogy 13, (pp. 495-544). Washington, DC: Mineralogical Society of America.
  • Warr, L.N., & Rice, A.H.N. (1994). Interlaboratory standardisation and calibration of clay mineral crystallinity and crystallite size data. Journal of Metamorphic Geology, 12, 141-152.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c28937ce-dff4-4fa5-bde2-d3671fd69674
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.