Synteza oraz badania spektroskopowe niesymetrycznych pochodnych soli diarylojodoniowych

• Autorzy: Kiklica E. , Kamińska I. , Ortyl J.

Warianty tytułu

EN

Synthesis and spectroscopic studies of unsymmetrical diaryliodonium salt

• Języki publikacji: PL

Abstrakty

EN

In the last years the interest in organic compounds hypervalent iodine (III) increased significantly due to the fact that there was a rapid development of applications for hypervalent iodine (III) derivatives, in both organic and polymer chemistry. These compounds have a high potential as efficient photoinitiators of cationic polymerization processes. Such a wide range of applications of hypervalent iodine(II) derivatives as diaryliodium salts encourages to search for new synthetic routes and extensive spectroscopic and photochemical developed derivatives. In order to obtain the diaryliodium salt the coupling reactions of [hydroxy(tosyloxy)iodo]arene (HTIA) derivatives with aryl derivatives activated electron electron-withdrawing substituens were carried out. The resulting diaryliodium salt derivatives analyzed with the use of spectroscopic methods including e.g.: NMR spectroscopy and UV-Vis. The diaryliodonium salt was also studied to be used as photoinitiators. To perform this study the research of photolysis was used.

Słowa kluczowe

PL

badania spektroskopowe; synteza; hiperwalencyjny jod(III); sole diarylojodoniowe

EN

diaryliodonium salts; hypervalent iodine(III) derivatives; cationic photoinitiators; photopolymerization

• Wydawca: ADVSEO sp. z o. o.
• Czasopismo: Technical Issues
• Rocznik: 2015
• Tom: nr 1
• Strony: 30--37
• Opis fizyczny: Bibliogr. 2 poz., rys., tab.

Twórcy

autor

Kiklica E.

• Politechnika Krakowska Wydział Inżynierii i Technologii Chemicznej Katedra Biotechnologii i Chemii Fizycznej ul. Warszawska 24 31-155 Kraków

autor

Kamińska I.

• Politechnika Krakowska Wydział Inżynierii i Technologii Chemicznej Katedra Biotechnologii i Chemii Fizycznej ul. Warszawska 24 31-155 Kraków

autor

Ortyl J.

• Politechnika Krakowska Wydział Inżynierii i Technologii Chemicznej Katedra Biotechnologii i Chemii Fizycznej ul. Warszawska 24 31-155 Kraków

Bibliografia

• 1. Meritt, E.A., Caineiro, V.M.T., Silva Jr. L.F. Olofsson, B., Facile Synthesis of Koser’s Reagent and Derivatives from Iodine or Aryl Iodides, J. Org. Chem., 2010, 75, pp. 7416-7419.
• 2. Menkissoglu-Spiroudi, M.. Karamanoli, K., Spyroudis, S., Constantidou, A., Hypervalent Iodine Compounds as Potent Antibacterial Agents against Ice Nucleaction Active (INA) Pseudomonas Syringae, J. Agris. Food Chem., 2001, 49, pp. 3746-3752.