Titanium(IV) Oxide Modified with Activated Carbon and Ultrasounds for Caffeine Photodegradation: Adsorption Isotherm and Kinetics Study

Zawadzki, Piotr; Kudlek, Edyta; Dudziak, Mariusz

doi:10.12911/22998993/126985

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Tytuł artykułu

Titanium(IV) Oxide Modified with Activated Carbon and Ultrasounds for Caffeine Photodegradation: Adsorption Isotherm and Kinetics Study

Autorzy

Zawadzki Piotr , Kudlek Edyta , Dudziak Mariusz

Treść / Zawartość

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DOI

10.12911/22998993/126985

Warianty tytułu

Języki publikacji

Abstrakty

In this paper the adsorption and photodegradation of caffeine (CAF) using modified photocatalysts were studied. The laboratory synthesis method of commercial titanium(IV) oxide, activated carbon and ultrasound was proposed. The adsorption effect of caffeine was described by the Langmuir and Freundlich isotherms. The effectiveness of CAF photocatalytic decomposition was evaluated as well as the parameters of the pseudo-first-order and pseudo-second-order reaction kinetics were estimated. It was determined that the caffeine adsorption fit both the Langmuir and Freundlich isotherms. The value of the experimental maximum adsorption capacity (q_e) was the highest for TiO₂ modified with activated carbon and ultrasounds (TiO₂/AC/Us). The highest removal degree (over 99.0%) of CAF was observed for titanium(IV) oxide modified with activated carbon. Both photodegradation kinetics models show good or very good fit; however, the pseudo-first-order model shows better fit to the experimental data (R² = 97–99%). After 20 minutes of the photodegradation process, the following efficiency order was determined: TiO₂ < TiO₂/AC < TiO₂/AC/US. The results indicate that the combination of TiO₂, activated carbon and ultrasound is an interesting alternative for the efficient degradation of caffeine, comparing to commercial TiO₂.

Słowa kluczowe

TiO2 caffeine photocatalysis modified photocatalysts activated carbon ultrasound kinetics adsorption

Wydawca

Polskie Towarzystwo Inżynierii Ekologicznej
Lublin University of Technology

Czasopismo

Journal of Ecological Engineering

Rocznik

2020

Tom

Vol. 21, nr 8

Strony

137--145

Opis fizyczny

Bibliogr. 30 poz., rys., tab.

Twórcy

autor

Zawadzki Piotr

pzawadzki@gig.eu

Department of Water Protection, Central Mining Institute, Plac Gwarków 1, 40-166 Katowice, Poland

autor

Kudlek Edyta

Institute of Water and Wastewater Engineering, Silesian University of Technology, Konarskiego 18, 44-100 Gliwice, Poland

autor

Dudziak Mariusz

Institute of Water and Wastewater Engineering, Silesian University of Technology, Konarskiego 18, 44-100 Gliwice, Poland

Bibliografia

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