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The paper presents the results of the investigation on the efficiency of the potassium ferrate application in water conditioning processes: oxidation of pollutants of different composition by ferrate compounds; clarification of model solutions by coagulation; reduction of corrosive aggressiveness of aqueous solutions. The optimal conditions for the water clarification process using potassium ferrate were: reagent dose 1 mg∙dm-3, pH close to neutral, and temperature 20°C. The oxidation rate of organic substances by the potassium ferrate solutions was 50% when applied in concentrations of 15-20 mg∙dm-3. The studies on the possible application of the reagent as a steel corrosion inhibitor in neutral aqueous media were conducted. The degree of corrosion protection reached 60%, which indicated the prospect of using iron (VI) compounds as inhibitory additives.
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134--140
Opis fizyczny
Bibliogr. 9 poz., rys., tab.
Twórcy
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu 37/4, 03056 Kyiv, Ukraine
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu 37/4, 03056 Kyiv, Ukraine
autor
- Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu 37/4, 03056 Kyiv, Ukraine
Bibliografia
- 1. Graham N., Jiang C.C., Li X.Z., Jiang J.Q., Ma J. The influence of pH on the degradation of phenol and chlorophenols by potassium ferrate. 2004. Chemosphere, 56(10), 949-956.
- 2. Jia-Qian Jiang, Hari Babu Prithiviraj Durai, Winzenbacher R., Petri M. 2013. Drinking water treatment by in-situ generated ferrate (VI). Proceedings of the 13th International Conference on Environmental Science and Technology. Athens, Greece.
- 3. Kulskij L.А., Goronowskij I.Т., Koganowskij А.М., Szewczenko М.А. 1980. Справочник по свойствам, методам анализа и очистке воды. Naukowa dumka. Kijev.
- 4. Lurie J.J., Rybnikova А.I. 1974. Chimiczeskij analiz proizwodstwiennych stocznych wod. Chimja. Моskwa.
- 5. Perfilyev U.D., Kulykov L.A., Dedushenko S.K. 2004. Advanced ferrate water treatment technology. Moscow. Russia.
- 6. Shabliy T., Nosachova J., Radovenchik Y., Vember V. 2017. Study of effectiveness of heavy metals ions as the inhibitors of steel corrosion. Eastern-European Journal of Enterprise Technologies, 4/12(88), 10-16.
- 7. Sharma V.K. 2010. Oxidation of nitrogen-containing pollutants by novel ferrate (VI) technology. Journal of Environmental Science and Health, Part A – Toxic/Hazardous Substances & Environmental Engineering, 45(6), 645-667.
- 8. Sharma V.K. Oxidation of inorganic contaminants by ferrates (VI, V, and IV)-kinetics and mechanisms. 2011. Journal of Environmental Management, 92(4), 1051-1073.
- 9. Sharma V.K., Jiang J.Q., Bouzek K. 2004. Innovative ferrate (VI) technology in water and wastewater treatment. Thesis. Proceedings of Internat. Symp. Prague, Czech Republic.
Typ dokumentu
Bibliografia
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