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Tytuł artykułu

REE-bearing minerals in sediment-hosted stratiform pyrite mineralization zones of the Wiśniówka area (Holy Cross Mts., Poland)

Autorzy
Migaszewski Zdzisław M. , Gałuszka Agnieszka , Zielińśki Grzegorz
Treść / Zawartość
Pełne teksty:
Migaszewski_Z_REE-bearing_GQ_Vol. 67_No. 2_2023.pdf
Identyfikatory
DOI
10.7306/gq.1687
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
There are two arsenical pyrite (As-FeS2mineralization zones cropping out in the Podwiśniówka and Wiśniówka Duża quarries where quartzites and quartzitic sandstones have been extracted for over a century. A large amount of pyrite in the Wiśniówka siliciclastics is unusual in the hard rock mining throughout the world. The pyritiferous beds contain a variety of REE-bearing minerals, including a crandallite series of aluminum-phosphate-sulfate (APS) minerals, e.g., predominant goyazite SrHAl3[(PO4)2(OH)6] with subordinate gorceixite BaHAl3[(PO4)2(OH)6] and very occasional crandallite CaHAl3[(PO4)2(OH)6]. By contrast, the other REE-phosphate minerals, e.g., xenotime YPO4, bur particularly monazite CePO4 occur in a lesser amount. Goyazite prevails somewhat in the Podwiśniówka beds whereas xenotime in the Wiśniówka Duża beds. Of the other REE-bearing minerals, bastnäsite REECO3(F,OH), florencite (REE)Al3(PO4)2(OH)6 and synchysite CaCe[CO3]2F occur in trace amounts. Interestingly, the quite common phosphate minerals, i.e., wavellite (Al.3[(OH,F)3|(PO4)2]×5H2O and variscite Al[PO4]×2H2O) are depleted in REEs with only Ce attaining 0.09 wt.% as documented by an electron-probe microanalysis. In contrast to quartzites/quartzitic sandstones, carbonaceous clayey-silty shales and bentonites/tuffites are distinctly enriched in REE-bearing minerals. This diversity is also mirrored in the mean total REE concentrations varying from 204 to 314 mg/kg, in clayey-silty shales and bentonites, attaining 457 mg/kg in some Podwiśniówka shale beds. Results of this and the previous petrographic, mineralogical and geochemical studies have indicated that REE-bearing minerals formed generally along with As-rich pyrite, nacrite/dickite and probably TiO2 polymorphs as a result of multiphase hydrothermal vent activity that took place in the Wiśniówka Late Cambrian sedimentary basin. This evidence is also backed up by the values of LREENASC/HREENASC (1.44–1.75) and Eu/EuNASC (1.24–1.30) coefficients in the clayey-silty shales. This positive Eu anomaly (31.20) points to the formation of REE-bearing minerals in a reducing environment.
Słowa kluczowe
EN
Wydawca
Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy
Czasopismo
Geological Quarterly
Rocznik
2023
Tom
Vol. 67, No. 2
Strony
art. no. 17
Opis fizyczny
Bibliogr. 67 poz., fot., tab., wykr.
Twórcy
autor
Migaszewski Zdzisław M.
zmig@ujk.edu.pl
  • Jan Kochanowski University, Świętokrzyska 7, 25-406 Kielce, Poland
autor
Gałuszka Agnieszka
  • Jan Kochanowski University, Świętokrzyska 7, 25-406 Kielce, Poland
autor
Zielińśki Grzegorz
  • Polish Geological Institute – National Research Institute, Rakowiecka 4, 00-975 Warszawa, Poland
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c130a89c-cce5-41cc-8414-bb0aabad11f6
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