Sorption of Cd(II), Ni(II) and Zn(II) on natural, sodium-, and acid-modified clinoptilolite-rich tuff

• Autorzy: Abatal M. , Olguin M. T. , Abdellaoui Y. , El Bouari A.

Identyfikatory

DOI

10.5277/epe180104

• Języki publikacji: EN

Abstrakty

EN

Sorption of Cd²⁺, Ni²⁺and Zn²⁺ions on natural (ZPCli), sodium modified (ZPCliNa) and acid modified (ZPCliH) zeolites have been investigated in function of the contact time, pH, and metal concentration by the batch technique. The characterization of ZPCIi, ZPCliNa, and ZPCliH materials was performed using X-ray powder diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy techniques. The surface area (BET) and the pHpzcwere also determined. The pH in the point of the zero charge of ZPCli, ZPCliNa, and ZPCliH zeolites was 8.25, 8.00, and 2.05, respectively. The kinetic sorption data for ZPCli, ZPCliNa and ZPCliH were well fitted to the pseudo-second order model (R2> 0.99). The linear model described the Cd, Ni and Zn sorption isotherms for ZPCliH, while for ZPCliNa and ZPCliH it was the Freundlich model. The unmodified and modified zeolitic materials showed the highest sorption capacity for Cd²⁺, lower for Zn²⁺ and Ni²⁺.

Słowa kluczowe

EN

heavy metals; clinoptilolite; cadmium removal

PL

metale ciężkie; klinoptylolit; usuwanie kadmu

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2018
• Tom: Vol. 44, nr 1
• Strony: 41--59
• Opis fizyczny: Bibliogr. 27 poz., tab., rys.

Twórcy

autor

Abatal M.

• Facultad de Ingeniería, Universidad Autónoma del Carmen, C.P. 24180, Cd. del Carmen, Campeche, México

autor

Olguin M. T.

• Departamento de Química, ININ, A.P. 18-1027, Col. Escandón Miguel Hidalgo, C.P. 11801, México

autor

Abdellaoui Y.

• Centre for Advanced Materials, University Mohamed VI Polytechnic, Lot 660 Hay Moulay Rachid 43150, Benguerir – Morocco.

autor

El Bouari A.

• LRCPGM, Department of Chemistry, Faculty of Sciences, Ben M’Sik-Casablanca, Morocco.

Bibliografia

• [1] WILLIAMS C.J., ADERHOLD D., EDYVEAN G.J., Comparison between biosorbents for the removal of metal ions from aqueous solutions, Water Res., 1998, 32, 216.
• [2] KADIRVELU K., THAMARAISELVI K., NAMASIVAYAM C., Removal of heavy metals from industrial wastewaters by adsorption onto activated carbon prepared from an agricultural solid waste, Bioresour. Technol., 2001, 76, 63.
• [3] SPRYNSKYY M., BUSZEWSKI B., TERZYK A., P., NAMIESNIK J., Study of the selection mechanism of heavy metal (Pb2+,Cu2+, Ni2+ and Cd2+) adsorption on clinoptilolite, J. Coll. Interf. Sci., 2006, 304, 21.
• [4] NAZIR R., KHAN M., MASAB M., REHMAN H., U., RAUF N., U., SHAHAB S., AMEER N., SAJED M., ULLAH M., RAFEEQ M., SHAHEEN Z., Accumulation of heavy metals (Ni, Cu, Cd, Cr, Pb, Zn, Fe) in the soil, water and plants and analysis of physicochemical parameters of soil and water collected from Tanda Dam Kohat, J. Pharm. Sci. Res., 2015, 7 (3), 89.
• [5] RAZEK M.A., Biosorption of chromium(VI) from single ion solutions on cotton stalks and rice straw wastes, J. App. Chem., 2015, 8 (4), 36.
• [6] BABEL S., KURNIAWAN T.A., Low-cost adsorbents for heavy metals uptake from contaminated water. A review, J. Hazard. Mater. B., 2003, 97, 219.
• [7] SHAHEEN S.M., DERBALAH A.S., MOGHANM F.S., Removal of heavy metals from aqueous solution by zeolite in competitive sorption system, I.J.E.D., 2012, 3 (4), 362.
• [8] WINGENFELDER U., HANSEN C., FURRER G., RSCHULIN R., Removal of heavy metals from mine waters by natural zeolites, Environ. Sci. Technol., 2005, 39, 4606.
• [9] KESRAOUI-OUKI S., CHEESEMAN C., PERRY R., Natural zeolite utilization in pollution control. A review of applications to metals effluents, J. Chem. Technol. Biotechnol., 1994 59, 121.
• [10] ZAMZOW M.J., EICHBAUM B.R., SANDGREN K.R., SHANKS D.E., Removal of heavy metals and other cations from wastewater using zeolites, Separ. Sci. Technol., 1990, 25 (13–15), 1555.
• [11] SHAHEEN S.M., DERBALAH A.S., MOGHANM F.S., Removal of heavy metals from aqueous solution by zeolite in competitive sorption system, Int. J. Environ. Sci. Dev., 2012, 3 (4), 362.
• [12] ZAINI M.A.A., OKAYAMA R., MACHIDA M., Adsorption of aqueous metal ions on cattle-manure-compost based activated carbons, J. Hazard. Mater., 2009, 170 (2–3), 1119.
• [13] MA W., ZHAO N., YANG G., TIAN L., WANG R., Removal of fluoride ions from aqueous solution by the calcination product of Mg-Al-Fe hydrotalcite-like compound, Desalination, 2011, 268 (1–3), 20.
• [14] LOPEZ-RAMON M.V., STOECKLI F., MORENO-CASTILLA C., CARRASCO-MARIN F., On the characterization of acidic and basic surface sites on carbons by various techniques, Carbon, 1999, 37, 1215.
• [15] AUROUX A., Acidity and basicity. Determination by adsorption microcalorimetry, Mol. Sieves, 2008, 6, 45.
• [16] WAZINGWA M.M., KABWADZA-CORNER P.,, JOHAN E., MATSUE N., Decrease in cation exchange capacity of zeolites at neutral Ph. Examples and proposals of determination method, J. Mater. Sci. Chem. Eng., 2014, 2, 1.
• [17] WAZINGWA M.M., JOHAN E., MATSUE N., Proton adsorption selectivity of zeolites in aqueous media. Effect of exchangeable cation species of zeolites, Environments, 2015, 2, 91.
• [18] MATHIALAGAN T., VIRARAGHAVAN T., Adsorption of cadmium from aqueous solutions by vermiculite, Sep. Sci. Technol., 2003, 38 (1), 57.
• [19] HO Y.S., MCKAY G., Pseudo-second order model for sorption processes, Process. Biochem., 1999, 34 (5), 461.
• [20] MIHALY C.L., MIHALY C.A., PETER A., NICULA C., BAKATULA N.E., TUTU H., The influence of pH on the adsorption of lead by Na-clinoptilolite: Kinetic and equilibrium studies, Water SA, 2012, 38 (2), 269.
• [21] YANG X., YANG S., YANG S., HU J., TAN X., WANG X., Effect of pH, ionic strength and temperature on sorption of Pb(II) on NKF-6 zeolite studied by batch technique, Chem. Eng J., 2011, 168, 86.
• [22] INGLEZAKIS V.J., LOIZIDOU M.D., GRIGOROPOULOU H.P., Ion exchange of Pb2+, Cu2+, Fe3+, and Cr3+ on natural clinoptilolite. selectivity determination and influence of acidity on metal uptake, Colloid. Interf. Sci., 2003, 261, 49.
• [23] ARÁMBULA-VILLAZANA V., SOLACHE-RÍOS M., OLGUÍN M. T., Sorption of cadmium from aqueous solutions at different temperatures by Mexican HEU-type zeolite rich tuff, J. Incl. Phenom. Macro., 2006, 55, 237.
• [24] SPRYNSKYY M., BUSZEWSKI B., TERZYK A.P., NAMIESNIK J., Study of the selection mechanism of heavy metal (Pb2+, Cu2+, Ni2+, and Cd2+) adsorption on clinoptilolite, J. Colloid Interf. Sci., 2006, 304, 21.
• [25] HAMIDPOUR M., KALBASI M., AFYUNI M., SHARIATMADARI H., HOLM P.E., HANSEN H. C.B., Sorption hysteresis of Cd(II) and Pb(II) on natural zeolite and bentonite, J. Hazard. Mater., 2010, 181,686.
• [26] ARGUN M.E., Use of clinoptilolite for the removal of nickel ions from water. Kinetics and thermodynamics, J. Hazard. Mater., 2008, 150, 587.
• [27] CORUH S., The removal of zinc ions by natural and conditioned clinoptilolites, Desalination, 2008, 225, 41.

Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).