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Chemical recycling of polyesters

Autorzy
Dębowski Maciej , Iuliano Anna , Plichta Andrzej , Kowalczyk Sebastian , Florjańczyk Zbigniew
Treść / Zawartość
Pełne teksty:
05_Debowski_11-12_2019.pdf
Identyfikatory
DOI
10.14314/polimery.2019.11.5
Warianty tytułu
PL
Recykling chemiczny poliestrów
Języki publikacji
EN
Abstrakty
EN
In the presented paper, two basic strategies that can be used in the processes of chemical recycling of polyester material were described. The first of them involves increasing the molar mass of recycled materials in the solid-state polycondensation (SSP) process and/or joining their chains with various types of substances easily reacting with the end groups of polyesters (so-called extending agents). The essence of the second strategy is the degradation of the material under the influence of various protogenic agents (such as water, alcohols, glycols and amines) to obtain low-molecular products or oligomers that can be used as raw materials in the synthesis of many classes of polymers. The methods that are already used in PET [poly(ethylene terephthalate)] recycling and the possibility of their extension to other types of polyesters are both shown.
PL
W pracy przedstawiono dwie podstawowe strategie możliwe do wykorzystania w procesach chemicznego recyklingu tworzyw poliestrowych. Pierwsza z nich polega na zwiększeniu masy molowej utylizowanych tworzyw polimerowych w procesie polikondensacji w ciele stałym (SSP) i/lub łączeniu ich łańcuchów za pomocą różnego typu substancji łatwo reagujących z grupami końcowymi poliestrów (tzw. czynników przedłużających). Istotą drugiej strategii jest degradacja tworzywa pod wpływem różnych czynników protogennych (takich jak: woda, alkohole, glikole i aminy) w celu uzyskania produktów małocząsteczkowych lub oligomerów, które można wykorzystać jako surowce w syntezie wielu klas materiałów polimerowych. Omówiono metody stosowane już w recyklingu PET [poli(tereftalanu etylenu)], a także możliwość ich rozszerzenia na inne gatunki poliestrów.
Słowa kluczowe
EN
PL
Wydawca
Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej
Czasopismo
Polimery
Rocznik
2019
Tom
T. 64, nr 11-12
Strony
764--776
Opis fizyczny
Bibliogr. 174 poz., rys. kolor.
Twórcy
autor
Dębowski Maciej
debowski@ch.pw.edu.pl
  • Warsaw University of Technology, Faculty of Chemistry, Noakowskiego 3, 00-664 Warsaw, Poland
autor
Iuliano Anna
  • Warsaw University of Technology, Faculty of Chemistry, Noakowskiego 3, 00-664 Warsaw, Poland
autor
Plichta Andrzej
  • Warsaw University of Technology, Faculty of Chemistry, Noakowskiego 3, 00-664 Warsaw, Poland
autor
Kowalczyk Sebastian
  • Warsaw University of Technology, Faculty of Chemistry, Noakowskiego 3, 00-664 Warsaw, Poland
autor
Florjańczyk Zbigniew
  • Warsaw University of Technology, Faculty of Chemistry, Noakowskiego 3, 00-664 Warsaw, Poland
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Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c119406a-c449-4ebc-9840-b7c9a8fa7a2b
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