The adsorption and kinetics studies of nitrate ions from bioethanol wastewater by ammonium-based ion exchange polymer

Rahayu, Aster; Hakika, Dhias Cahya; Amrillah, Nafira Alfi Zaini; Sisca, Vivi; Veranica; Chusna, Firda Mahira Alfiata; Anggresani, Lia; Lim, Lee Wah

doi:10.12912/27197050/199560

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The adsorption and kinetics studies of nitrate ions from bioethanol wastewater by ammonium-based ion exchange polymer

Autorzy

Rahayu Aster , Hakika Dhias Cahya , Amrillah Nafira Alfi Zaini , Sisca Vivi , Veranica , Chusna Firda Mahira Alfiata , Anggresani Lia , Lim Lee Wah

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5_rahayu_the_adsorption_and_eeet_3_2025.pdf

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DOI

10.12912/27197050/199560

Warianty tytułu

Języki publikacji

Abstrakty

Bioethanol wastewater contains complex inorganic and organic ions, posing a severe environmental problem. In this research, the removal of nitrate ion (NO₃) from bioethanol wastewater was conducted using ammonium polymers as adsorbents. Ammonium polymer was synthesized using the one-pot approach method using functional monomer with single thermal. This study aimed to analyze the performance of an ammonium polymer for removing nitrate ions (NO3-) from bioethanol waste, considering operational parameters (polymer mass, temperature, and contact time) by advanced characterization technique and determine the isotherm model for predicting adsorption behavior. The results of FTIR revealed significant functional groups, including N-H and C-N. SEM-EDX confirmed the effectiveness of adsorption by identifying each component, and elemental analysis confirmed the percentages of C, H, and N in the adsorbent. The optimal conditions for the adsorption process were achieved when 0.1 g of ammonium polymer was in contact with bioethanol wastewater for 60 minutes at 40 °C with a removal efficiency of 96.32% and an adsorption capacity of 0.58 mg/g. The adsorption isotherm analysis followed the Temkin model.

Słowa kluczowe

isotherm adsorbent removal characterization performance

Wydawca

Lubelski Oddział Polskiego Towarzystwo Inżynierii Ekologicznej
Lublin University of Technology
WNGB Wydawnictwo Naukowe

Czasopismo

Ecological Engineering & Environmental Technology

Rocznik

2025

Tom

Vol. 26, iss. 3

Strony

54--69

Opis fizyczny

Bibliogr. 48 poz., rys., tab.

Twórcy

autor

Rahayu Aster

aster.rahayu@che.uad.ac.id

Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Ahmad Dahlan,Tamanan, Bantul, D.I. Yogyakarta, 55191, Indonesia

https://orcid.org/0000-0003-4995-5249

autor

Hakika Dhias Cahya

Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Ahmad Dahlan,Tamanan, Bantul, D.I. Yogyakarta, 55191, Indonesia

https://orcid.org/0000-0002-7185-6805

autor

Amrillah Nafira Alfi Zaini

Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, Japan

https://orcid.org/0009-0001-4716-7364

autor

Sisca Vivi

Research Center for Chemistry, National Research and Innovation Agency B.J. Habibie Science and Techno Park, Serpong, South Tangerang, Banten, 15314, Indonesia

https://orcid.org/0000-0001-9325-5990

autor

Veranica

Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Ahmad Dahlan,Tamanan, Bantul, D.I. Yogyakarta, 55191, Indonesia

https://orcid.org/0009-0000-2365-7230

autor

Chusna Firda Mahira Alfiata

Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Ahmad Dahlan,Tamanan, Bantul, D.I. Yogyakarta, 55191, Indonesia

https://orcid.org/0000-0002-1621-2193

autor

Anggresani Lia

Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, Japan

https://orcid.org/0000-0002-4491-8484

autor

Lim Lee Wah

Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, Japan

https://orcid.org/0000-0002-6897-531X

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