Chemical modification of cellulose for boron sorption from water solutions

• Autorzy: Sarsenov A. , Bishimbaev V. K. , Kapsalamov B. A. , Lepesov K. K. , Gapparova K. M. , Grzesiak P.

Identyfikatory

DOI

10.2478/pjct-2018-0064

• Języki publikacji: EN

Abstrakty

EN

It is shown that natural cellulose obtained from the walnut shell (Juglans regia) can be used for chemical modification of the selective boron sorbent. The modification was carried out by the coupling technique of chlorine derivatives of the polyhydric alcohols or polyols (mannitol, xylitol, sorbitol or glycerol). In this case new hybrid substances (sorbents) were obtained and they are represented by the formula: R-O-(CHOH)_n -CH₃ , where R is a residue of the cellulose backbone, n is the number of functional (OH) groups of the polyhydric alcohols. The pulp mercerization was carried out by processing the ground walnut shell (WS) with hot solution of sodium hydroxide. Chlorination of polyhydric alcohols was carried out by gaseous hydrochloric acid sparging through the polyhydric alcohol aqueous solution. The coupling process proceeds according to the mechanism of substitution of the cellulose hydroxyl groups with chlorine atoms.

Słowa kluczowe

EN

cellulose chemistry; natural hybrid sorbents; modified cellulose

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2018
• Tom: Vol. 20, nr 4
• Strony: 123--128
• Opis fizyczny: Bibliogr. 26 poz., rys., tab.

Twórcy

autor

Sarsenov A.

• Social Fund “Research Centre of Salt Technology”, BC Ansar, 25 Syganak, 010000 Astana, Republic of Kazakhstan

autor

Bishimbaev V. K.

• Social Fund “Research Centre of Salt Technology”, BC Ansar, 25 Syganak, 010000 Astana, Republic of Kazakhstan

autor

Kapsalamov B. A.

• Social Fund “Research Centre of Salt Technology”, BC Ansar, 25 Syganak, 010000 Astana, Republic of Kazakhstan

autor

Lepesov K. K.

• Social Fund “Research Centre of Salt Technology”, BC Ansar, 25 Syganak, 010000 Astana, Republic of Kazakhstan

autor

Gapparova K. M.

• Fund “Research Centre of Salt Technology”, BC Ansar, 25 Syganak, 010000 Astana, Republic of Kazakhstan

autor

Grzesiak P.

• Institute of Plant Protection – National Research Institute, Władysława Węgorka 20, 60-318 Poznań, Poland

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).