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pH effect on the aggregation of silver nanoparticles synthesized by chemical reduction

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Silver colloidal nanoparticles were prepared according to the chemical reduction method in which the ascorbic acid was used as a reducing agent and sodium citrate as a stabilizing agent. The absorption spectra of all prepared samples obtained using the UV-Vis spectrophotometer showed a surface plasmon peak at a wavelength of about 420 nm. The size of the silver nanoparticles was controlled by changing the pH values of the reaction system. At high pH, smaller size silver nanoparticles were obtained compared to low pH values. This difference can be attributed to the difference in the reduction rate of the precursor. In addition to the inverse proportionality between the size and the pH value it is clear that increasing the pH value enables us to obtain spherical nanoparticles while at low pH, rods and triangular particle shapes were formed. Poor balance between nucleation and growth processes could be the cause of this result.
Słowa kluczowe
Wydawca
Rocznik
Strony
107--111
Opis fizyczny
Bibliogr. 10 poz., rys., wyk., tab.
Twórcy
autor
  • Physics Department, Jordan University of Science and Technology, Irbid, Jordan
autor
  • Physics Department, Jordan University of Science and Technology, Irbid, Jordan
autor
  • Al-Huson University College, Al-Balqa applied University, Huson-Irbid
  • silver nanoparticles; pH; chemical synthesis
autor
  • Al-Huson University College, Al-Balqa applied University, Huson-Irbid
autor
  • Physics Department, Jordan University of Science and Technology, Irbid, Jordan
Bibliografia
  • [1] MYERS D., Surfaces, Interfaces, and Colloids: Principles and Applications, 2nd Ed., Wiley VCH, New York,1999.
  • [2] PILLAI Z.S., P.V. KAMAT, J. Phys. Chem. B, 108(2004), 945.
  • [3] LIU Y., CHEN S., ZHONG L., WU G., Radiat. Phys.Chem., 78 (2009), 251.
  • [4] TSUJI T., IRYO K., WATANABE N., TSUJI M., Appl.Surf. Sci., 202 (2002), 80.
  • [5] MA H.Y., YIN B.S., WANG S.Y., JIAO Y.L., PAN W.,HUANG S.X., CHEN S.H., MENG F.J., Chem. Phys.Chem., 5 (2004), 68.
  • [6] QU J., CHANG Y., MA Y., ZHENG J., LI H., QU Q., REN C., CHEN X., Sensor. Actuat. B-Chem., 174 (2012)133.
  • [7] DONG X. et al., J. Phys. Chem. C, 113 (2009), 6573.
  • [8] MAZUMDAR H., AHMED G., Int. J. Chem. Tech. Res.,3 (2011), 1494.
  • [9] QIN Y., JI X., JING J., LIU H., WU H., YANG W.,Colloid. Surface. A, 375 (2010), 172.
  • [10] LEE P.C., MEISEL D., J. Phys. Chem. B, 86 (1982), 3391.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c0837741-c699-4291-a3d4-3fd9cfe903a0
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