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This study focused on the leaching of uranium and thorium from a high grade Ethiopian tantalite ore using sulfuric acid. The effects of variables such as acid concentration, temperature and leaching time were studied. In general, the leaching efficiency of uranium increases with increasing temperature from 100 to 300°C whereas the opposite trend was observed for thorium. The amount of uranium leached increased from 69.1% at contact time of 1 hr to 88.6% when the tantalite ore was leached for 3 hrs. On the other hand, for the experiments conditions considered in this study, the leaching behavior of uranium and thorium did not change significantly with varying sulphuric acid concentration from 70 to 90 wt%. Overall, the highest dissolution of uranium and thorium were achieved at 100°C, 70 wt% H2SO4 concentration and 1 hr contact time.
Rocznik
Tom
Strony
448--457
Opis fizyczny
Bibliogr. 21 poz., rys., tab.
Twórcy
autor
- School of Materials Science and Engineering, Jimma Institute of Technology, Jimma University, PO Box 378, Jimma, Ethiopia
- Federal Technical Vocational and Education Training Institute, FTVETI, Department of Manufacturing Technology, Addis Ababa, Ethiopia
autor
- School of Chemical and Bio Engineering, AAiT, Addis Ababa University, PO Box 1176, Addis Ababa, Ethiopia
autor
- Department of Mining Engineering and Metallurgical Engineering, Western Australia School of Mines, Curtin University, Egan St, Kalgoorlie, WA 6430, Australia
- Department of Chemistry, College of Natural and Computational Science, Mekelle University, PO Box 823, Mekelle, Ethiopia
Bibliografia
- BERHE, G.G., ALBERTO, V.R., TADESSE, B., YIMAM, A., WOLDETINSAE, G., 2018. Decomposition of the Kenticha mangano-tantalite ore by HF/H2SO4 and KOH fusion. Physicochem. Probl. Miner. Process. 54, 406-414.
- BERHE, G.G., ALBERTO, V.R., YIMAM, A., WOLDETINSAE, G., TADESSE, B., 2017, Alternative beneficiation of tantalite and removal of radioactive oxides from Ethiopian Kenticha pegmatite–spodumene ores. Int. J. Min. Met. Mater. 24, 727–735.
- BHARGAVA, S.K., RAM, R., POWNCEBY, M., GROCOTT, S., RING, B., TARDIO, J., JONES, L., 2015. Review A review of acid leaching of uraninite. Hydrometall. 151, 10–24.
- BOSE, D.K., GUPTA, C.K., 2001. Extractive metallurgy of tantalum, Min. Pro. Ext. Rev. 22, 389–412.
- DAMPARE, S.B., NYARKO, B.J.B., OSAE, S., AKAHO, E.H.K., ASIEDU, D.K., SERFORE-ARMAH, Y., NUDE, P., 2005. Simultaneous determination of tantalum, niobium, thorium and uranium in placer columbite-tantalite deposits from the Akim Oda District of Ghana by epithermal instrumental neutron activation analysis. J. Radioanal. Nucl. Chem. 265, 53–59.
- EL-HAZEK, M.N., AMER, T.E., ABU EL-AZM, M.G., ISSA, R.M., EL-HADY, S.M., 2012, Liquid–liquid extraction of tantalum and niobium by octanol from sulfate leach liquor. Arabian J. Chem. 5, 31-39.
- EL-HUSSAINI, O.M., MAHDY, M.A., 2002. Sulfuric acid leaching of Kab Amiri niobium–Tantalum bearing minerals, Central Eastern Desert, Egypt. Hydrometall. 64, 219–229.
- GUPTA, C.K., 1990. Hydrometallurgy in Extraction Processes, Wiley-VCH.
- HABASHI, F., 1997. Handbook of Extractive Metallurgy, Wiley-VCH.
- HU, Z., QI, L., 2014. Sample Digestion Methods, Elsevier, pp. 87–109.
- KIM, E., KIM, S., MOON, D., KOH, S., 2013, Fractionation and rare-element mineralization of Kenticha pegmatite, Southern Ethiopia. Econ. Environ. Geol. 46, 375-390.
- KUSTER, D., ROMER, R.L., TOLESSA, D., ZERIHUN, D., BHEEMALINGESWARA, K., MELCHER, F., OBERTHÜR, T., 2009, The Kenticha rare-element pegmatite, Ethiopia: internal differentiation, U-Pb age and Ta mineralization. Miner. Deposita. 44, 723-750.
- MADAKKARUPPAN, V., PIUS, A., SREENIVAS, T., SARBAJNA, C., 2016. Gangue minerals reactivity in oxidative leaching of uraninite with dilute sulfuric acid from low-grade ores: an approach for better leach liquor purity. J. Radioanal. Nucl. Chem. 309, 493–501.
- MERRITT, R.C., 1971, The Extractive Metallurgy of Uranium, Golden, Colorado, pp. 59-61.
- NETE, M., KOKO, F., THERON, T., PURCELL, W., NEL, J.T., 2014. Primary beneficiation of tantalite using magnetic separation and acid leaching. Int. J. Miner. Metall. Mater. 21, 1153–1159.
- NETE, M., PURCELL, W., 2018. In: Ramasami, P., Gupta, B.M., Jhaumeer, L.S., Li, K.W.H. (eds) Emerging Trends in Chemical Sciences, Springer International Publishing, Basel.
- NETTLETON, K.C.A., NIKOLOSKI, A.N., DA COSTA, M., 2015. The leaching of Uranium from betafite. Hydrometall. 157, 270–279.
- PANDA, R., KUMARI, A., KUMAR, J.M., HAIT, J., Kumar V, KUMAR, J.R., LEE, J.Y., 2014. Leaching of rare earth metals from Korean monazite concentrate. J. Ind. Eng. Chem. 20, 2035–2042.
- SADRI, F., RASHCHI, F., AMINI, A., 2017. Hydrometallurgical digestion and leaching of Iranian monazite concentrate containing rare earth elements Th, Ce, La and Nd. Int. J. Min. Process. 159, 7–15.
- SIMANDL, G.J., 2001. Tantalum Market and Resources: An Overview. British Columbia Geological Survey, 313–318.
- TADESSE, S., ZERIHUN, D., 1996, Composition, fractionation trend and zoning accretion of the columbite-tantalite group of minerals in the Kenticha rare metal field (Adola, Southern Ethiopia). J. Afr. Earth Sci., 23, 411-431.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c07fa919-91fd-4137-a781-626408658e36