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Dodecyl amine adsorption at different interfaces during bubble attachment/detachment at a silica surface

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Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The reverse flotation of quartz and other gangue silicate minerals with alkyl amines is an important and well known strategy for the processing of iron ore, low grade bauxite ore, and phosphate rock. Some details of amine adsorption by quartz have been described in the literature, but little is known about the disposition of amine during bubble attachment. Now, a new experimental procedure involving vibrational sum frequency spectroscopy (VSFS) has been developed to provide, for the first time, a more detailed analysis of the state of dodecyl amine (DDA) adsorption at different interfaces during bubble attachment/detachment at a silica surface. The results show that the hydrophobic surface state at the silica surface is created by the transfer of a well-organized monolayer of DDA from the bubble surface to the silica surface during bubble contact and attachment.
Rocznik
Strony
81--88
Opis fizyczny
Bibliogr. 17 poz., rys., tab.
Twórcy
autor
  • University of Utah, College of Mines and Earth Sciences, Department of Metallurgical Engineering, 135 South 1460 East, Rm 412, Salt Lake City, UT 84112
autor
  • University of Utah, College of Mines and Earth Sciences, Department of Metallurgical Engineering, 135 South 1460 East, Rm 412, Salt Lake City, UT 84112
Bibliografia
  • ALBIJANIC, B., BRADSHAW, D. J., NGUYEN, A. V., 2012. The relationships between the bubble-particle attachment time, collector dosage and the mineralogy of a copper sulfide ore. Minerals Engineering, 36–38, 309–313.
  • CHERNYSHOVA, I. V., HANUMANTHA Rao, K., VIDYADHAR, A., 2001. Mechanism of adsorption of long-chain alkylamines on silicates: A spectroscopic study. 2. Albite. Langmuir, 17, 775-785.
  • DIGRE, M., SANDVIK, K.L., 1968. Adsorption of amine on quartz through bubble interaction. IMM Transactions, Section C, 77, C61-64.
  • DE BRUYN, P.L., AGA, G.E., 1962. Surface chemistry of flotation. In: Froth flotation-50th anniversary. Fuerstenau, D.W. (ed.), American Institute of Mining, Metallurgical, and Petroleum Engineers, New York, NY, USA, 91-138.
  • FUERSTENAU, D.W., 1957. Correlation of contact angle, adsorption density, zeta potentials and flotation rate. AIME Transactions, 208, 1365-1367.
  • GUYOT-SIONNEST, P., HUNT, J.H., SHEN, Y.R., 1987. Sum-frequency vibrational spectroscop of a Langmuir film: Study of molecular orientation of a two-dimensional system. Physical Review Letters, 59(14), 1597-1600.
  • KRASOWSKA, M., MALYSA, K., 2007. Wetting films in attachment of the colliding bubble. Advances in Colloid and Interface Science, 134–135, 138–150.
  • KOUA, J. Ko, TAO, D., XUA, G., 2010. A study of adsorption of dodecylamine on quartz surface using quartz crystal microbalance with dissipation. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 368, 75–83.
  • LASKOWSKI, J. S., 2013. From amine molecules adsorption to amine precipitate transport by bubbles: A potash ore flotation mechanism. Minerals Engineering, 45, 170–179.
  • LI, H., 1958. Adsorption of organic and inorganic ions on quartz. Doctoral Thesis, Massachusetts Institute of Technology, Cambridge, MA, USA.
  • NGUYEN, A. V., SCHULZE, H. J., RALSTON, J., 1997. Elementary steps in particle-bubble attachment. International Journal of Mineral Processing, 51, 183–195.
  • NGUYEN, A. V., STECHEMESSER, H., 2004. Influence of dewetting kinetics on bubble-particle interaction. Physical Chemistry Chemical Physics, 6, 429–433.
  • PARKINSON, L., and RALSTON, J., 2011. Dynamic aspects of small bubble and hydrophilic solid encounters. Advances in Colloid and Interface Science, 168, 198–209.
  • SCHROEDLE, S., MOORE, F.G., RICHMOND, G.L., 2007. Surface speciation at solid/liquid interfaces: A vibrational sum-frequency study of acetate at the fluorite/water interface. Journal of Physical Chemistry C, 111, 10088-10094.
  • SHEN, Y.R., 1984. The principles of nonlinear optics. Wiley, New York, NY, USA.
  • SMITH, R.W., 1962. Contact angles in a quartz dodecylammonium acetate solution-nitrogen system. Proceedings South Dakota Academy of Science, XLI, 150.
  • WANG, X., LIU, J., DU, H., and MILLER, J.D., 2010. States of adsorbed dodecyl amine and water at a silica surface as revealed by vibrational spectroscopy. Langmuir, 26(5), 3407–3414.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-bf9e64be-4eb8-4bcd-acc0-5b9167c238bd
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