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Hydrometallurgical treatment of non-sulfide zinc ore for precipitation of zinc oxide nanoparticles

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Acid leaching of Egyptian zinc ore from the Um Gheig area was carried out with sulfuric acid. This study determines the optimum conditions for dissolution of non-sulfide zinc ore. The optimum conditions are 25% -74m particle size, 45 °C temperature, 2 h leaching time, 1.1 stoichiometric molar ratio of H2SO4 to Zn, 1:3 solid/liquid ratio. The maximum filtration rate is 1.6 Mg Zn•m-2•day-1at pressure difference of 0.80 bar. The zinc recovery is about 90%. As the zinc ore contains zinc silicate, some additives were tested to enhance filtration and prevent formation of silica gel. To increase the added value of the product, zinc oxide was precipitated by a co-precipitation method in a nanosize powder with average particle size ~ 20 nm. Photocatalytic degradation of methylene blue dye under UV light using ZnO nanopowders produced at different conditions was investigated. Photocatalytic efficiency with methylene blue (MB) concentration was reduced as much as 85% in 240 min with the produced nanoparticles.
Rocznik
Strony
729--737
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
  • Central Metallurgical Research and Development Institute, P.O. Box 87, Helwan, Cairo, Egypt
autor
  • Central Metallurgical Research and Development Institute, P.O. Box 87, Helwan, Cairo, Egypt
  • Central Metallurgical Research and Development Institute, P.O. Box 87, Helwan, Cairo, Egypt
  • Central Metallurgical Research and Development Institute, P.O. Box 87, Helwan, Cairo, Egypt
  • Ain Shams University, Faculty of Science, Cairo, Egypt,
Bibliografia
  • ABDEL-AAL E.A., IBRAHIM I.A., RASHAD M.M., ISMAIL A.K., 1994, Hydrometallurgical processing of Egyptian magnesite ore for production of magnesium sulfate, Physicochemical Problems of Mineral Processing Journal, 28, 165–175.
  • ABDEL-AAL E.A., 1995, Possibility of utilizing Egyptian dolomite ores for production of magnesium oxide by acid leaching, Physicochemical Problems of Mineral Processing Journal, 29, 55–65.
  • ABDEL-AAL E.A., IBRAHIM I.A., RASHAD M.M., ISMAIL A.K., 1996, Hydrometallurgical processing of Egyptian magnesite ore, Physicochemical Problems of Mineral Processing Journal, 30, 207–216.
  • ABDEL-AAL E.A., RASHAD M.M. 1997, Hydrometallurgical processing of Egyptian magnesite ore with nitric acid, Physicochemical Problems of Mineral Processing Journal, 31, 7–17.
  • ABDEL-AAL E.A., SHOUKRY Z.E. 1997, Application of quick leaching method to an Egyptian zinc silicate ore, Transactions-Institution of mining and metallurgy. Section C. Mineral processing & extractive metallurgy, 106.
  • ABDEL-AAL E.A., 1997, Direct leaching of oxidized zinc ore, The Institution of Engineers India, Journal-MM 78, 25–29.
  • ABDEL-AAL E.A., 2000, Kinetics of sulfuric acid leaching of low-grade zinc silicate ore, Hydrometallurgy 55, 247–254.
  • BODAS M.G., 1996, Hydrometallurgical treatment of zinc silicate ore from Thailand, Hydrometallurgy 40, 37−49.
  • CORRIOU, J.P., GELY, R., VIERS, P., 1988, Thermodynamic and kinetic study of the pressure leaching of zinc sulfide in aqueous sulfuric acid, Hydrometallurgy, 21, 85–102.
  • DE WET K., SINGLETON J.D., 2008, Development of a viable process for the recovery of zinc from oxide ores. The Southern African Institute of Mining and Metallurgy, Proceedings of LEAD and ZINC '08, Durban, 177–192.
  • DUFRESNE R., 1976, Quick leach of siliceous zinc ores, JOM 28, 8–12.
  • FARAG M.Z., ABDEL-KHALEK N.A., HASSAN M.S., El AREF M.M., El MANAWI A.W., 2012, Upgrading of Egyptian nonsulfide zinc ore by gravity separation techniques, Journal of Metallurgical Engineering, 1, 6–13.
  • HONGSHENG X., CHANG W., CUNXIONG L., GANG F., ZHIGAN D., MINTING L., XINGBIN L., 2010, Sulfuric acid leaching of zinc silicate ore under pressure, Hydrometallurgy 105, 186–190.
  • HUAA Y., LINA Z., YAN Z., 2002, Application of microwave irradiation to quick leach of zinc silicate ore, Minerals Engineering 15, 451–456.
  • IBRAHIM I.A., ABDEL-AAL E.A., El-SAFTY N.A., ISMAIL A.K., 1995, Hydrometallurgical beneficiation of manganese ore from Sinai, Physicochemical Problems of Mineral Processing Journal, 29, 73–79.
  • ISMAIL A.A., EL-MIDANY A., ABDEL-AAL E.A., EL-SHALL H., 2005, Application of statistical design to optimize the preparation of ZnO nanoparticles via hydrothermal technique, Materials Letters 59, 1924–1928.
  • KUMAR R., BISWAS A.K., 1986, Zinc recovery from Zawar ancient siliceous slag, Hydrometallurgy 15, 267−280.
  • LICUN-X., XU H., DENG Z., LI X., LI M., WEI C., 2010, Pressure leaching of zinc silicate ore in sulfuric acid medium. Transactions of Nonferrous Metals Society of China, 20, 918–923.
  • NOUNEH K., AJJAMMOURI T., LAGHFOUR Z., MAAROUFI A., ABD-LEFDIL M., CHAUMONT D., SEKAT Z., 2015, Structural and spectral properties of ZnO nanorods by wet chemical method for hybrid solar cells applications, Materials Letters 139, 26–30.
  • PERRY W., 1966, Refining zinc silicate ore by special leaching technique, Chemical Engineering, 73, 182−184.
  • SCIACCA F., 1963, Brazilian patent 65, 790.
  • WOOD J.T., KEM P.L., ASHDOWN N.C., 1977, Electrolytic recovery of zinc from oxidized ores, Journal of Metals, 29, 7–11.
  • WOOLLETT, A., 2005, The processing of non-sulfide zinc deposits. In: Boni, M., Gilg, H.A. (Eds.), European Science Foundation (ESF) Workshop on Nonsulfide Zn–Pb Deposits, Iglesias.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-bf7d1725-62fe-438b-ac25-818c483f14fd
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