Modeling of Ozonation of C.I. Reactive Black 5 through a Kinetic Approach

• Autorzy: Bilińska L. , Żyłła R. , Smółka K. , Gmurek M. , Ledakowicz S.

Identyfikatory

DOI

10.5604/01.3001.0010.4628

Warianty tytułu

PL

Modelowanie kinetyki procesu ozonowania Reactive Black 5

• Języki publikacji: EN

Abstrakty

EN

C.I. Reactive Black 5 (RB5) is the most commonly used dye in the textile industry. Ozone is a strong oxidan that can decompose many barely degradable pollutants, including dyes. Although there are many literature reports devoted to the treatment of textile wastewater and dye solutions by ozone, the ozonation mechanism and modeling of the kinetics is still not well covered. In this work a kinetic model of the process of RB5 decolourisation by ozone has been proposed and validated on the basis of experimental data. The experiments were carried out in a liquid-liquid system to avoid mass transfer limitation. A model was established for acid reaction medium. The main RB5 reaction was direct oxidation of the dye with molecular ozone. The self-decomposition of ozone in liquid phase was taken into account and described by an empirical equation. The reaction rate constants of RB5 with ozone were estimated from the experimental data in the range of (1.88 ± 0.08) × 10⁴ – (2.53 ± 0.10) × 10⁵ M^-1s^-1 (invariant with initial dye concentration). An empirical equation k′ ₂ = 1.06 × 10⁸(C_OH−)^0.31 was built for the constant to make it dependent on the pH value. A solution of the non-linear inverse problem allowed for identification of the kinetic constants on the basis of the experimental data obtained. The model gave a good match between the prediction and experimental data for pH between 1.88 and 4.0.

PL

Reactive Black 5 (RB5) jest powszechnie stosowanym barwnikiem w przemyśle włókienniczym. Ozon, będący silnym utleniaczem, jest w stanie rozłożyć wiele trudno degradowalnych substancji w tym barwniki. Pomimo, iż oczyszczanie ścieków włókienniczych i roztworów barwników ozonem było tematem wielu pozycji literaturowych, niewiele pośród nich dotyczyło badań nad poznaniem mechanizmu utleniania oraz modelowania kinetyki tego procesu. W niniejszej pracy zaproponowano matematyczny model opisujący kinetykę procesu odbarwiania barwnika RB5 za pomocą ozonu. Walidacji dokonano poprzez porównanie wyników modelowania do danych eksperymentalnych. Eksperymenty prowadzono w układzie homogenicznym ciecz-ciecz, aby uniknąć limitacji transferu masy między fazami układu. Model został opracowany dla procesu przebiegającego w środowisku kwaśnym, gdzie główną reakcją było bezpośrednie utlenianie barwnika cząsteczkowym ozonem z jednoczesnym uwzględnieniem rozkładu ozonu w fazie ciekłej. Model opisano równaniem empirycznym. Wartości stałych szybkości reakcji RB5 z ozonem oszacowane na podstawie danych eksperymentalnych znajdowały się w zakresie od do M^-1s^-1 i były niezależne od początkowego stężenia substratu. W celu uzależnienia stałych szybkości od wartości pH, wyznaczono zależność empiryczną w postaci. Rozwiązanie nieliniowego problemu odwrotnego pozwoliło na identyfikację stałych kinetycznych na podstawie danych eksperymentalnych. Otrzymano dobrą zgodność pomiędzy wynikami modelowania a danymi doświadczalnymi dla wartości pH w zakresie 1,88-4,0.

Słowa kluczowe

EN

ozonation; C.I. Reactive Black 5; kinetic model; second-order kinetic constant with ozone; second-order kinetic constant with hydroxyl radical

PL

ozonowanie; Reactive Black 5; model kinetyczny

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2017
• Tom: Vol. 25, no. 5 (125)
• Strony: 54--60
• Opis fizyczny: Bibliogr. 39 poz., rys., tab.

Twórcy

autor

Bilińska L.

• Lodz University of Technology, Faculty of Process & Environmental Engineering, Wolczanska 213, 90-924 Lodz, Poland
• Textile Company Bilinski, Mickiewicza 29, 95-050 Konstantynow Lodzki, Poland

autor

Żyłła R.

• Textile Research Institute, Brzezinska 5/15,92-103 Lodz, Poland

autor

Smółka K.

• Lodz University of Technology, Institute of Mechatronics and Information Systems, Stefanowskiego 18/22, 90-924 Lodz, Poland

autor

Gmurek M.

• Lodz University of Technology, Faculty of Process & Environmental Engineering, Wolczanska 213, 90-924 Lodz, Poland

autor

Ledakowicz S.

• Lodz University of Technology, Faculty of Process & Environmental Engineering, Wolczanska 213, 90-924 Lodz, Poland

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