VO2(B) conversion to VO2(A) and VO2(M) and their oxidation resistance and optical switching properties

Zhang, Y.

doi:10.1515/msp-2016-0023

Artykuł - szczegóły

Tytuł artykułu

VO2(B) conversion to VO2(A) and VO2(M) and their oxidation resistance and optical switching properties

Autorzy

Zhang Y.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

DOI

10.1515/msp-2016-0023

Warianty tytułu

Języki publikacji

Abstrakty

Vanadium dioxide VO₂ has been paid in recent years increasing attention because of its various applications, however, its oxidation resistance properties in air atmosphere have rarely been reported. Herein, VO₂ (B) nanobelts were transformed into VO₂ (A) and VO₂ (M) nanobelts by hydrothermal route and calcination treatment, respectively. Then, we comparatively studied the oxidation resistance properties of VO₂ (B), VO₂ (A) and VO₂ (M) nanobelts in air atmosphere by thermo-gravimetric analysis and differential thermal analysis (TGA/DTA). It was found that the nanobelts had good thermal stability and oxidation resistance below 341 degrees C, 408 degrees C and 465 degrees C in air, respectively, indicating that they were stable in air at room temperature. The fierce oxidation of the nanobelts occurred at 426, 507 and 645 degrees C, respectively. The results showed that the VO₂ (M) nanobelts had the best thermal stability and oxidation resistance among the others. Furthermore, the phase transition temperatures and optical switching properties of VO₂ (A) and VO₂ (M) were studied by differential scanning calorimetry (DSC) and variable-temperature infrared spectra. It was found that the VO₂ (A) and VO₂ (M) nanobelts had outstanding thermochromic character and optical switching properties.

Słowa kluczowe

VO2 polymorphs thermal properties oxidation resistance phase transition optical properties

Wydawca

De Gruyter

Czasopismo

Materials Science Poland

Rocznik

2016

Tom

Vol. 34, No. 1

Strony

169--176

Opis fizyczny

Bibliogr. 40 poz., rys., tab.

Twórcy

autor

Zhang Y.

yfzhang@dlut.edu.cn

School of Chemistry, Dalian University of Technology, Dalian 116024, PR China

Bibliografia

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-be3f28fe-a169-42ad-b188-1ee0b5fd23f0