NMR study of microstructure of n-butyl methacrylate and methyl methacrylate comopolymer

• Autorzy: Matlengiewicz M. , Pasich M. , Rygielska A. , Majcher D.
• Języki publikacji: EN

Abstrakty

EN

Microstructure of copolymers of two methacrylate monomers are difficult to analyze by ¹³C NMR spectroscopy since the region of the carbonyl signals, usually utilized for this purpose, is relatively narrow and the lines split due to different sequences are strongly superimposed. The spectra of the two respective homopolymers indicate that both monomers introduce configurational effects, hence the copolymer microstructure should be described in terms of distribution of configurational-compositional sequences. It was shown that for the investigated copolymer of n-butyl methacrylate and methyl methacrylate such analysis can be performed at the triad level.

Słowa kluczowe

EN

copolymer; methacrylate copolymers; microstructure

PL

kopolimer; kopolimer metylu; mikrostruktura

• Wydawca: Sieć Badawcza Łukasiewicz – Instytut Inżynierii Materiałów Polimerowych i Barwników
• Czasopismo: Farby i Lakiery
• Rocznik: 2013
• Tom: nr 2
• Strony: 17--21
• Opis fizyczny: Bibliogr. 7 poz., rys.

Twórcy

autor

Matlengiewicz M.

• Institute of Chemistry, Department of Environmental Chemistry and Technology, Silesian University, ul. Szkolna 9, 40-006 Katowice, Poland

autor

Pasich M.

• Institute of Chemistry, Department of Environmental Chemistry and Technology, Silesian University, ul. Szkolna 9, 40-006 Katowice, Poland; Institute for Engineering of Polymer Materials and Dyes, Paint and Plastics Department, ul. Chorzowska 50A, 44-100 Gliwice, Poland

autor

Rygielska A.

• Institute of Chemistry, Department of Environmental Chemistry and Technology, Silesian University, ul. Szkolna 9, 40-006 Katowice, Poland

autor

Majcher D.

• Institute of Chemistry, Department of Environmental Chemistry and Technology, Silesian University, ul. Szkolna 9, 40-006 Katowice, Poland

Bibliografia

• 1. G. Nguyen, D. Nicole, M. Swistek, M. Matlengiewicz, B. Wiegert, Polymer, 38, 3455 (1997)
• 2. H. Momose, K. Hattori, T. Hirano, K. Ute, Polymer, 50, 3819 (2009)
• 3. A. S. Brar, A. K. J. Saini, Appl. Polym. Sci., 32, 4607 (1986)
• 4. B. Sannigrahi, B. Garnaik, Polym. /., 30, 340 (1988)
• 5. D.J.T. Hill, N.G. Moss, P.J. Pomerya, A.K. Whittaker, Polymer, 41, 1287 (2000)
• 6. A. S. Brar, G. S. Kapur, Polym. }., 20, 811 (1988)
• 7. R. Quinting, R. Cai, Macromolecules, 27, 6301 (1994)