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Oxidation activation energy of titanium alloy based on TiAl(γ) intermetalic phase

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The present paper deals with the analysis of the course of oxidation of the cyclic Ti-46Al-7Nb-0.7Cr-0.1Si-0.2Ni alloy in a hot air atmosphere in the temperature range of 875-975°C. The constant rates of the oxidation were determined (separately for the first and second stages of oxidation) and the energy of oxidation activation of the tested alloy was established. It was discovered that the oxidation process of the Ti-46Al-7Nb-0,7Cr-0.1Si-0.2Ni alloy develops according to the parabolic correlation, and it is only possible to determine the apparent energy of oxidation activation.
Rocznik
Strony
5--14
Opis fizyczny
Bibliogr. 29 poz., rys., wykr., tab.
Twórcy
autor
  • Opole University of Technology, Faculty of Mechanical Engineering, Department of Materials Engineering, Poland
Bibliografia
  • 1. Appel F., Paul J. D. H., Oehring M., Gamma titanium aluminide alloys, Wiley-VCH Verlag GmbH (2011).
  • 2. Loria A.: Gamma titanium aluminides as prospective structural materials, Intermetallics 8 (2000) 1339–1345.
  • 3. Szkliniarz W., The alloys from the binary system of Ti-Al, Z. Bojar, W. Przetakiewicz, (Eds.), Metallic materials with the participation of intermetallic phases, Technical Military Academy, Warsaw (2006) 66–88 (Chapter 2.2, in Polish).
  • 4. Kumpfert J., Leyens C.: Titanium and Titanium Alloys, Fundamentals and Applications. Edited by Christoph Leyens, Manfred Peters, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (2003).
  • 5. Mrowec S., Werber T.: Gas Corrosion of Metals, Katowice (1975) (in Polish).
  • 6. Mrowec S., Werber T.: Gas Corrosion, WNT, Katowice (1965) (in Polish).
  • 7. Kakare S.A., Toney J.B., Aswath P.B., Oxidation of Ductile Particie Reinforced Ti-48Al Composite, Metallurgical and Materials Transactions, 26A (1995) 1835-1845.
  • 8. Woo J.C., Varmas.K., Mahapatra R.N., Effect of Ta and Zr additions on the oxidation characteristics of Ti-44Al-xNb alloy, Gamma Titanium Aluminides, (2003) 585-589.
  • 9. Singheiser L., Quadakkers W.J., Shemet V., Isothermal and cyclic oxidation behavior of titanium aluminides, Gamma Titanium Aluminides, (1999) 743-752.
  • 10. Reddy R.G., Wen X., Okafor I.C.I., Interdiffusion in the TiO2 oxidation product of Ti3Al, Metallurgical and Materials Transactions A, 32A (2001) 491-495.
  • 11. Król S., Mechanism and kinetics of oxidation titanium and selected titanium alloys, ??? 82, Opole (1994) (in Polish)
  • 12. Pilling N., Bedworth B., The oxidation of metals at high temperatures, Journal of the Institute of Metals, 29 (1923) 529-534.
  • 13. Evans U.: Transaction Electrochemical Society, 46 (1924) 267.
  • 14. Tammann G., Koster W.: Die Geschwindigkeit der Einwirkung von Sauerstoff, Schwefelwasserstoff und Halogenen auf Metalle, Zeitschrift für anorganische und allgemeine Chemie, 123 (1922) 196-224.
  • 15. Kubaschewski O., Hopkins B.E., Oxidation of Metals and Alloys, London: Butterworths (1962).
  • 16. Kofstad P., Nonstoichiometry, diffusion and electric conductivity in binary metal oxides (1983), Malaba, Florida: R. E. Krieger Publishing Company.
  • 17. Kofstad P., High Temperature Corrosion, Elsevier Applied Science, London, New York (1988).
  • 18. Kofstad P., Fundamental aspects of corrosion by hot gases, Materials Science and Engineering A120 (1989) 25–29.
  • 19. Kofstad P.: Defects and Transport Properties of Metal Oxides, Oxidation of Metals 1/2, 44 (1995) 3–27.
  • 20. Rahmel A., ed. Auifbau von Oxidschichten auf Hochtemperaturwerkstoffen und ihre technische Bedeutung, Deutsche Gesellschaft für Materialskunde e.V.: Oberursel (1983).
  • 21. Wagner C., Formation of composite scales consisting of oxides of different metals, Journal of the Electrochemical Society 103(11) (1956) 627–633.
  • 22. Wagner C., Reaktionstypen bei der oxydation von legierungen, Elektrochemie 63 (1959) 772–782.
  • 23. Gulbransen E.A., Andrew K.F., Kinetics of the reactiona of titanium with O2, N2 and H2, Metals Transactions 185 (1949) 741-748.
  • 24. Morton P.H., Boldwin W.M., The scale of titanium in air, Transactions of the American Society for Metals 44 (1952) 1004-1029
  • 25. Kinna W., Knorr W., Uber die oxidation von Tittan, Z. Metallkunde 47 (1956) 594-598.
  • 26. Jenkins A.E., The oxidation of titanium at high temperatures in an atmosphere of pure oxygen, Journal of the Institute of Metals 82 (1954) 213-221.
  • 27. Mrowec S., Werber T., Kinetics and mechanism oxidation of metal, Katowice (1982) (in Polish)
  • 28. Kubaschewski O., Evans E., Alcock C.B., Metallurgical thermochemistry, Pergamon Press, London (1968).
  • 29. Krupkowski A., Laws of thermodynamics, PWN, Cracow (1958) (in Polish).
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-bcd4c8e3-2759-4153-b796-a6c6eafa1a9e
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