Temperature study of magnetic resonance spectra of co-modified (Co,N)-TiO2 nanocomposites

• Autorzy: Guskos N. , Typek J. , Zolnierkiewicz G. , Guskos A. , Berczynski P. , Dolat D. , Mozia S. , Aidinis K. , Kruk K. , Morawski A. W.

Identyfikatory

DOI

10.1515/msp-2016-0042

• Języki publikacji: EN

Abstrakty

EN

The (nCo,N)-TiO₂ (n = 1, 5 and 10 wt.% of Co) nanocomposites were investigated by magnetic resonance spectroscopy in 4 K to 290 K range. Analyses of ferromagnetic/electron paramagnetic resonance (FMR/EPR) spectra in terms of four Callen lineshape components revealed the existence of two types of magnetic centers, one derived from metallic cobalt nanoparticles in superparamagnetic (SPM) phase and the other from cobalt clusters in the TiO2 lattice. Additionally, at low temperature the EPR spectrum arising from Ti³⁺ ions was also registered. Both relaxations of the Landau-Lifshitz type and the Bloch-Bloembergen type played an important role at high temperature in determining the linewidths and the latter relaxation was prevailing at low temperature. Analysis of the integrated intensity showed that the SPM signal is due to small size FM cobalt nanoparticles while the paramagnetic signal from Co clusters originates from those nanoparticles in which the concentration of magnetic polarons is below the percolation threshold.

Słowa kluczowe

EN

nano titanium dioxide; electron paramagnetic resonance; photocatalyst

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2016
• Tom: Vol. 34, No. 2
• Strony: 242--250
• Opis fizyczny: Bibliogr. 42 poz., rys., tab.

Twórcy

autor

Guskos N.

• Department of Solid State Physics, Faculty of Physics, University of Athens, Panepistimioupolis, GR-157 84 Athens, Greece
• Department of Physics, West Pomeranian University of Technology, al. Piastow 48, 70-311 Szczecin, Poland

autor

Typek J.

• Department of Physics, West Pomeranian University of Technology, al. Piastow 48, 70-311 Szczecin, Poland

autor

Zolnierkiewicz G.

• Department of Physics, West Pomeranian University of Technology, al. Piastow 48, 70-311 Szczecin, Poland

autor

Guskos A.

• Department of Physics, West Pomeranian University of Technology, al. Piastow 48, 70-311 Szczecin, Poland

autor

Berczynski P.

• Department of Physics, West Pomeranian University of Technology, al. Piastow 48, 70-311 Szczecin, Poland

autor

Dolat D.

• Department of Chemical and Environmental Engineering, West Pomeranian University of Technology, al. Piastow 17, 70-310 Szczecin, Poland

autor

Mozia S.

• Department of Chemical and Environmental Engineering, West Pomeranian University of Technology, al. Piastow 17, 70-310 Szczecin, Poland

autor

Aidinis K.

• Department of Electronic, Faculty of Physics, University of Athens, Panepistimioupolis, GR-157 84 Athens, Greece

autor

Kruk K.

• Faculty of Electrical Engineering, West Pomeranian University of Technology, ul. Sikorskiego 37, 70-313 Szczecin, Poland

autor

Morawski A. W.

• Department of Chemical and Environmental Engineering, West Pomeranian University of Technology, al. Piastow 17, 70-310 Szczecin, Poland

Bibliografia

• [1] Schneider J., Matsuoka M., Takeuchi M., Zhang J., Horiuchi Y., Anpo M., Bahnemann D.W., Chem. Rev., 114 (2014), 9919.
• [2] Yates H.M., Nolan M.G., Sheel D.W., Pemble M.E., J. Photochem. Photobiol. A, 179 (2006), 213.
• [3] Thompson T.L., Yates Jr. J.T., Chem. Rev., 106 (2006), 4428.
• [4] Hashimoto K., Irie H., Fujishima A, Jpn. J. Appl. Phys., 44 (2005), 8269.
• [5] Stepanov A.L., Rev. Adv. Mater. Sci., 30 (2012), 150.
• [6] Zaleska A., Recent Pat. Eng., 2 (2008), 157.
• [7] Matsumoto Y., Murakami M., Shono T., Hasegawa T., Fukumura T., Kawasaki M., Ahmet P., Chikyow T., Koshihara S., Koinuma H., Science, 291 (2001), 854.
• [8] Dietl T., Ohno H., Matsukura F., Cibert J., Ferrand D., Science, 287 (2000), 1019.
• [9] Sato K., Katayama-Yoshida H., Jpn. J. Appl. Phys., 39 (2000), L555.
• [10] Coey J.M.D., Venkatesan M., Fitzgerald C.B., Nat. Mater., 4 (2005), 173.
• [11] Janisch R., Gopal P., Spaldin N.A., J. Phys.: Condens. Mater., 17 (2005), R657.
• [12] Li X.L., Qi S.F., Jiang F.X., Quan Z.Y., Xu X.H., Sci. China-Phys. Mech. Astron., 56 (2013), 111.
• [13] Griffin Roberts K., Varela M., Rashkeev S., Pantelides S.T., Pennycook S.J., Krishnan K.M., Phys. Rev. B, 78 (2008), 014409.
• [14] Yamada Y., Fukumura T., Ueno K., Kawasaki M., Appl. Phys Lett., 99 (2011), 242502.
• [15] Mohanty P., Mishra N.C., Choudhary R.J., Banerjee A., Shripathi T., Lalla N.P., Annapoorni S., Chandana R, J. Phys. D Appl. Phys., 45 (2012), 32530.
• [16] Tian J., Gao H., Kong H., Yang P., Zhan W., Chu J., Nanoscale Res. Lett., 8 (2013), 533.
• [17] Santara B., Pal B., Giri P.K., J. Appl. Phys., 110 (2011), 114322.
• [18] Nakai I., Sasano M., Inui K., Korekawa T., Ishijima H., Katoh H., J. Korean Phys. Soc., 63 (2013), 532.
• [19] Kaushik A., Dalela B., Kumar S., Alvi P.A., Dalela S., J. Alloy. Compd., 552 (2013), 274.
• [20] Kim J.Y., Park J.H., Park B.G., Noh H.J., Oh S.J., Yang J.S., Kim D.H., Bu S.D., Noh T.W., Lin H.J., Hsieh H.H., Chen C.T., Phys. Rev. Lett., 90 (2003), 017401.
• [21] Shinde S.R., Ogale S.B., Sarma S.D., Simpson J.R., Drew H.D., Lofland S.E., Lanci C., Buban J.P., Browning N.D., Kulkarni V.N., Higgins J., Sharma R.P., Greene R.L., Venkatesan T., Phys. Rev. B, 67 (2003), 115211.
• [22] Kaspar T.C., Droubay T., McCready D.E., Nachimuthu P., Heald S.M., Wang C.M., Lea A.S., Shutthanandan V., Chamber S.A., Toney M.F., J. Vac. Sci. Technol. B, 24 (2006), 2012.
• [23] Xu J., Shi S., Li L., Zhang X., Wang Y., Chen X., Wang J., Lv L., Zhang F., Zhong W., J. Appl. Phys., 107 (2010), 053910.
• [24] Rashad M.M., Elsayed E.M., Al-Kotb M.S., Shalan A.E., J. Alloy. Compd., 581 (2013), 71.
• [25] Huang C., Liu X., Kong L., Lan W., Su Q., Wang Y., Appl. Phys. A, 87 (2007), 781.
• [26] Sadanandam G., Lalitha K., Kumari V.D., Shankar M.V., Subrahmanyam M., Int. J. Hydrogen Energ., 38 (2013), 9655.
• [27] Guskos N., Zolnierkiewicz G., Guskos A., Typek j., Berczynski P., Dolat D., Mozia S., Aidinis K., Morawski A.W., Nukleonika, 60 (2015), 411.
• [28] Dolat D., Mozia S., Wrobel R. j., Moszynski D., Ohtani, B., Guskos N., Morawski A.W., Appl. Catal. B-Environ., 162 (2015), 310.
• [29] Guskos N., Zolnierkiewicz G., Guskos A., Typek J., Berczynski P., Dolat D., Mozia S., Morawski A.W., Magnetic Resonance Study of Nickel and Nitrogen Co-modified Titanium Dioxide Nanocomposites, in: Bonca J., Kruchinin S. (Eds.), NATO Science for Peace and Security Series C: Environmental Security, Nanotechnology in the Security Systems, Springer, Dordrecht, 2015, p. 33.
• [30] Guskos N., Typek J., Maryniak M., Narkiewicz U., Kucharewicz I., Wrobel R., Mater. Sci.-Poland, 23 (2005), 1001.
• [31] Bodziony T., Guskos N., Typek j., Roslaniec Z., Narkiewicz U., Maryniak M., Mater. Sci.-Poland, 23 (2005), 1055.
• [32] Narkiewicz U., Arabczyk W., Pełech I., Guskos N., Typek J., Maryniak M., Wozniak M.J., Matysiak H., Kurzydlowski K.J., Mater. Sci.-Poland, 24 (2006), 1067.
• [3] Hurum D.C., Agrios A.G., Gray K.A., Rajh T., Thurnauer M.C., J. Phys. Chem. B, 107 (2003), 4545.
• [34] Kumar C.P., Gopal N. O., Wang T. C., Wong M.S., Ke S.C., J. Phys. Chem. B, 110 (2006), 5223.
• [35] Ribbens S., Caretti I., Beyers E., Zamani S., Vinck E., Van Doorslaer S., Cool P., J. Phys. Chem. C, 115 (2011), 2302.
• [36] Dolat D., Moszynski D., Guskos N., Ohtani B., Morawski A.W., Appl. Surf. Sci., 266 (2013), 410.
• [37] Kliava J., Electron Magnetic Resonance of Nanoparticles: Superparamagnetic Resonance, in: Gubin S.P (Ed.), Magnetic nanoparticles, Wiley-VCH, Weinheim, 2009, p. 255.
• [38] Helminiak A., Arabczyk W., Zolnierkiewicz G., Guskos N., Typek J., Rev. Adv. Mat. Sci., 29 (2011), 166.
• [39] Guskos N., Likodimos V., Glenis S., Maryniak M., Baran M., Szymczak R., Roslaniec Z., Kwiatkowska M., Petridis D., J. Nanosci. Nanotech., 8 (2008), 2127.
• [40] Guskos N., Glenis S., Zolnierkiewicz G., Guskos A., Typek J., Berczynski P., Dolat D., Grzmil B., Ohtani B., Morawski. A.W., J. Alloy. Compd., 606 (2014), 32.
• [41] Guskos N., Typek J., Zolnierkiewicz G., Diamantopoulou A., Mozia S., Morawski A.W., Magnetic Properties of Cobalt and Nitrogen Co-modified Titanium Dioxide Nanocomposites, in: Bonca j., Kruchinin S. (Eds.), NATO Science for Peace and Security Series C: Environmental Security, Nanotechnology in the Security Systems, to be published in 2016.
• [42] Knobel M., Nunes W.C., Socolovsky L.M., De Biasi E., Vargas J.M., Denardin J.C., J. Nanosci. Nanotech., 8 (2008), 2836.

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.