Identyfikatory
Warianty tytułu
Ocena występowania leków sulfonamidowych w biosferze
Języki publikacji
Abstrakty
Emissions from road traffic play a key role for the impact on entering several types of pollutants into the air, causing that the troposphere (not only in the vicinity of roads) depends on the intensity and type of the transport. Due to exploitation of vehicles and road surfaces, gaseous pollutants and particulates are released into the atmosphere. The paper presents results of research studies on the concentration of PM10 dust, and the concentration of heavy metals (Al, Cd, Cu, Cr, Ni, Pb and Zn), which it contains. The PM10 concentration measurements were performed using MicroPNS HVS16 sets of dust collectors with control modules. Qualitative and quantitative indications of heavy metals were performed using AAS. The presented approach differs from the previous ones with the method of obtaining results for the reference state, which previously were set out in the same sites, in which later were investigated the effect of motor traffic on the qualities of the air. Samples of the airborne particulate matter and surface dust were collected twice in the same area for a period of 28 days in April 2004 (an area without human intervention) and 2012 (an area of operation). The study was conducted on the area of the current section of the northern ring road of Opole (PL). It was shown that the land-use change, which is the exploitation of new road, causes PM10 concentration increase and raise of the designated heavy metals in the air. Based on the estimated EF and Wilcoxon test it was stated that transport significantly affects the level of Pb, Cd, Zn and Cu. It was indicated that the speed of vehicles is one of the key factors influencing the degree of air degradation. It was also concluded that the former approach applied in the assessment of the air quality being based on the comparison of its quality at source and the quality in areas away from human activity, is justified.
Emisja z ruchu drogowego jest istotnym źródłem wprowadzania szeregu rodzajów zanieczyszczeń do powietrza, co powoduje, że jakość troposfery (nie tylko w sąsiedztwie dróg) uwarunkowana jest intensywnością i rodzajem transportu. W wyniku eksploatacji pojazdów i nawierzchni jezdnych do atmosfery uwalniane są zanieczyszczenia gazowe oraz pyłowe. Praca przedstawia wyniki badań dotyczących koncentracji pyłu PM10 i zawartych w nim metali ciężkich (Al, Cd, Cu, Cr, Ni, Pb i Zn). Pomiary stężenia PM10 wykonano przy użyciu zautomatyzowanych zestawów pobierania pyłów MicroPNS HVS16. Oznaczenia jakościowe i ilościowe metali ciężkich wykonano przy użyciu spektrometrii AAS. Zaprezentowane podejście różni się od dotychczasowych sposobem uzyskania wyników dla stanu odniesienia. Koncentracje analizowanych związków określono w tych samych miejscach, w których później badano wpływ ruchu pojazdów silnikowych na jakość powietrza. Próbki pyłu zawieszonego pobierano dwukrotnie na tym samym terenie przez okres 28 dni w miesiącu kwietniu, w 2004 (teren pozbawiony ingerencji ludzkiej) i 2012 r. (teren eksploatowany). Badania prowadzono na obszarze obecnego odcinka północnej obwodnicy Opola (PL). Wykazano, że zmiana sposobu użytkowania terenu, jakim jest eksploatacja nowej drogi, powoduje wzrost stężeń PM10 i oznaczanych metali ciężkich w powietrzu. Na podstawie wyznaczonej wartości współczynnika wzbogacania (EF) i analizy testem Wilcoxona stwierdzono, że transport wydatnie wpływa na poziom Pb, Cd, Zn i Cu. Wykazano, że prędkość pojazdów jest jednym z kluczowych czynników wpływających na stopień degradacji powietrza. Ponadto stwierdzono, że dotychczasowa metoda wykorzystywana przy ocenie jakości powietrza polegająca na porównaniu jego jakości u źródła z jego jakością na terenach oddalonych od działalności człowieka jest uzasadniona.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
1173--1184
Opis fizyczny
Bibliogr. 34 poz., rys., tab., wykr.
Twórcy
autor
- Department of Thermal Engineering nd Industrial Facilities, Opole University of Technology, ul. Mikołajczyka 5, 45–271 Opole, Poland
Bibliografia
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- [3] Thorpe A, Harrison R. Sources and properties of non-exhaust particulate matter from road traffic: A review. Sci Total Environ. 2008;400:270-282. DOI: 10.1016/j.scitotenv.2008.06.007.
- [4] Healy D, Silvari V, Whitaker A, Lopez J, Pere-Trepat E, Heffron E, et al. Linking urban field measurements of ambient air particulate matter to their chemical analysis and effects on health. Proc of the 6th Int Conf on Urban Air Quality. Cyprus: Limassol; 2007.
- [5] Yang W, Omaye ST. Air pollutants, oxidative stress and human health. Mutat Res. 2009;674:45-54. DOI: 0.1016/j.mrgentox.2008.10.005.
- [6] Council Directive 1999/30/EC relating to limit values for sulphur dioxide, nitrogen dioxide and oxides of nitrogen, particulate matter and lead in ambient air. Official Journal L 163, 29 June 1999:41-60.
- [7] Directive 2004/107/EC of the European Parliament and of the Council of 15 December 2004 relating to arsenic, cadmium, mercury, nickel and polycyclic aromatic hydrocarbons in ambient air. Official Journal L 023, 26/01/2005;0003-0016.
- [8] Abu-Allaban M, Gillies JA, Gertler AW, Clayton R, Proffitt D. Tailpipe, resuspended dust, and brake-wear emission factors from on-road vehicles. Atmosph Environ. 2003:37:5283-93. DOI: 10.1016/j.atmosenv.2003.05.005.
- [9] Samara C, Kouimtzis T, Tsitouridou R, Kanias G, Simeonov V. Chemical mass balance source apportionment of PM10 in an industrialized urban area of Northern Greece. Atmos Environ. 2003;37:41-54. PII: S 1352-2310(02)00772-0.
- [10] Kennedy P, Gadd J. Preliminary examination of trace elements in tyres, brake pads, and road bitumen in New Zealand. Prepared for Ministry of Transport. New Zealand: Infrastructure Auckland; 2003.
- [11] Pakkanen TA, Kerminen V-M, Loukkola K, Hillamo RE, Aarnio P, Koskentalo T, et al. Size distributions of mass and chemical components in street-level and rooftop PM1 particles in Helsinki. Atmos Environ. 2003;37:1673-90. DOI: 10.1016/S1352-2310(03)00011-6.
- [12] Salma I, Maenhaut W. Changes in elemental composition and mass of atmospheric aerosol pollution between 1996 and 2002 in a Central European city. Environ Pollut. 2006;143:479-488. DOI: 10.1016/j.envpol.2005.11.042.
- [13] Furusjö E, Sternbeck J, Cousins AP. PM10 source characterization at urban and highway roadside locations. Sci Total Environ. 2007;387:206-219. DOI: 10.1016/j.scitotenv.2007.07.021.
- [14] Gunawardana Ch, Goonetilleke A, Egodawatta P, Dawes L, Kokot S. Source characterisation of road dust based on chemical and mineralogical composition. Chemosphere. 2012;87:163-170. DOI: 10.1016/j.chemosphere.2011.12.012.
- [15] Fuller GW, Green D. Evidence for increasing concentrations of primary PM10 in London. Atmosph Environ. 2006;40:6134-6145. DOI: 10.1016/j.atmosenv. 2006.05.031.
- [16] Mossetti S, Angius SP, Angelino E. Assessing the impact of particulate matter sources in the Milan urban area. Int J Environ Pollut. 2005;24:247-259. DOI: 10.1504/IJEP.2005.007396.
- [17] Kunzli N, Kaiser R, Medina S, Studnicka M, Chanel O, Filliger P, et al. Public-health impact of outdoor and traffic-related air pollution: A European assessment. Lancet. 2000;356:795-801.
- [18] Progiou AG, Ziomas IC. Road traffic emissions impact on air quality of the Greater Athens Area based on a 20 year emissions inventory. Sci Total Environ. 2011;410-411:1-7. DOI: 10.1016/j.scitotenv.2011.09.050.
- [19] Rönkkö T, Virtanen A, Vaaraslahti K, Keskinen J, Pirjola L, Lappi M. Effect of dilution conditions and driving parameters on nucleation mode particles in diesel exhaust: Laboratory and on-road study. Atmosph Environ. 2006;40:2893-2901. DOI: 10.1016/j.atmosenv.2006.01.002.
- [20] Hjortenkrans DST, Bergbäck BG, Häggerud AV. Metal emissions from brake linings and tires: Case studies of Stockholm, Sweden 1995/1998 and 2005. Environ Sci Technol. 2007;41:5224-5230. DOI: 10.1021/es070198o.
- [21] Canepari S, Perrino C, Olivieri F, Astolfi ML. Characterisation of the traffic sources of PM through size-segregated sampling, sequential leaching and ICP analysis. Atmosph Environ. 2008;42:8161-8817. DOI: 10.1016/j.atmosenv.2008.07.052.
- [22] Sörme L, Bergbäck B, Lohm U. Goods in the anthroposphere as a metal emission source. Water Air Soil Pollut. 2001;1:213-227.
- [23] Sternbeck J, Sjodin A, Andreasson K. Metal emissions from road traffic and the influence of resuspension a results from two tunnel studies. Atmosph Environ. 2002;36:4735-4744. PII: S 1352-2310(02)00561-7.
- [24] EN 12341:1998. Air quality. Determination of the PM10 fraction of suspended particulate matter. Reference method and field test procedure to demonstrate reference equivalence of measurement methods.
- [25] Pastuszka JS, Rogula-Kozłowska W, Zajusz-Zubek E. Characterization of PM10 and PM2.5 and associated heavy metals at the crossroads and urban background site in Zabrze, Upper Silesia, Poland, during the smog episodes. Environ Monit Assess. 2010;168:613-627. DOI: 0.1007/s10661-009-1138-8.
- [26] Wang X, Bi X, Sheng G, Fu J. Chemical composition and sources of PM10 and PM2.5 aerosols in Guangzhou, China. Environ Monit Assess. 2006;119:425-439. DOI: 10.1007/s10661-005-9034-3.
- [27] Yang K-L. Spatial and seasonal variation of PM10 mass concentrations in Taiwan. Atmosph Environ. 2002;36:3403-3411. PII: S 1352-2310(02)00312-6.
- [28] Katragkou E, Kazadzis S, Amiridis V, Papaioannou V, Karathanasis S, Melas D. PM10 regional transport pathways in Thessaloniki, Greece. Atmosph Environ. 2009;43:1079-1085. DOI: 10.1016/j.atmosenv.2008.11.021.
- [29] Querol X, Alastuey A, Rodrýguez S, Viana MM, Artýnano B, Salvador P, et al. Levels of particulate matter in rural, urban and industrial sites in Spain. Sci Total Environ. 2004;334-335:359-376. DOI: 0.1016/j.scitotenv.2004.04.036.
- [30] Slezakova K, Pereira MC, Reis MA, Alvim-Ferraz MC. Influence of traffic emissions on the composition of atmospheric particles of different sizes – Part 1: Concentrations and elemental characterization. J Atmosph Chem. 2007;58:55-68. DOI: 10.1007/s10874-007-9078-6.
- [31] Gaudry A, Moskura M, Mariet C, Ayrault S, Denayer F, Bernard N. Inorganic Pollution in PM10 Particles Collected Over Three French Sites Under Various Influences: Rural Conditions, Traffic and Industry. Water Air Soil Pollut. 2008;193:91-106. DOI: 10.1007/s11270-008-9670-7.
- [32] Baldasano JM, Gonçalves M, Soret A, Jiménez-Guerrero P. Air pollution impacts of speed limitation measures in large cities: The need for improving traffic data in a metropolitan area. Atmosph Environ. 2010;44:2997-3006. DOI: 10.1016/j.atmosenv.2010.05.013.
- [33] Kłos A, Rajfur M, Wacławek M. Application of enrichment factor (EF) to the interpretation of results from the biomonitoring studies. Ecol Chem Eng S. 2011;18(2):172-183.
- [34] Taylor SR, McLennan SM. The continental crust: Its composition and evolution. Oxford: Blacwell; 1985.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-bc9af006-4066-47a8-805b-bf43a5872ee5
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