Synthesis and characterization of new polymer sorbents based on EGDMA and cellulose

• Autorzy: Podkościelna Beata , Wawrzkiewicz Monika , Goliszek Marta , Lipke Agnieszka , Chabros Artur

Identyfikatory

DOI

10.37190/ppmp/147466

• Konferencja: Physicochemistry of interfaces - instrumental methods (22-26.08.2021 ; Lublin, Poland)
• Języki publikacji: EN

Abstrakty

EN

In this article bio-based and cheap microcrystalline cellulose was used as a modificator for the synthesis of polymeric sorbents based on ethylene glycol dimethacrylate (EGDMA) and styrene (St). Cellulose was previously modified with methacrylic anhydride. The polymerization reaction was carried out in an aqueous medium with the addition of polyvinyl alcohol using the suspension polymerization technique. The chemical structure of the obtained sorbents was confirmed by ATR-FTIR analysis. In the next stage of the research, the materials were tested for their sorption capacity to remove organic dyes of acidic and basic type from aqueous solutions.

Słowa kluczowe

EN

cellulose; EGDMA; polymer; sorption; bio-filler

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2022
• Tom: Vol. 58, iss. 2
• Strony: art. no. 147466
• Opis fizyczny: Bibliogr. 31 poz., fot., rys., tab., wykr.

Twórcy

autor

Podkościelna Beata

• Department of Polymer Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University; M. Curie-Skłodowska Sq. 3, 20-031 Lublin, Poland

• https://orcid.org/0000-0002-0267-5402

autor

Wawrzkiewicz Monika

• Department of Inorganic Chemistry, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University; M. Curie-Skłodowska Sq. 3, 20-031 Lublin, Poland

autor

Goliszek Marta

• Analytical Laboratory, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University; M. Curie-Skłodowska Sq. 3, 20-031 Lublin, Poland

autor

Lipke Agnieszka

• Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University; M. Curie-Skłodowska Sq. 3, 20-031 Lublin, Poland

autor

Chabros Artur

• Analytical Laboratory, Institute of Chemical Sciences, Faculty of Chemistry, Maria Curie-Skłodowska University; M. Curie-Skłodowska Sq. 3, 20-031 Lublin, Poland

Bibliografia

• ANIRUDHAN, T.S., JALAJAMONY, S., DIVYA, L., 2009. Efficiency of Amine-Modified Poly(glycidyl methacrylate)- Grafted Cellulose in the Removal and Recovery of Vanadium(V) from Aqueous Solutions. Ind. Eng. Chem. Res. 48, 2118–2124.
• BAI, Y-X., LI, Y-F., 2006. Preparation and characterization of crosslinked porous cellulose beads. Carbohydr. Polym. 64, 402-407.
• BAI, Q., XIONG, Q., LI, C., SHEN, Y., UYAMA, H., 2017. Hierarchical porous cellulose/activated carbon composite monolith for efficient adsorption of dyes. Cellulose 24, 4275–4289.
• BATMAZ, R., MOHAMMED, N., ZAMAN, M., MINHAS, G., BERRY, R.M., TAM, K.C., 2014. Cellulose nanocrystals as promising adsorbents for the removal of cationic dyes. Cellulose 21, 1655-1665.
• BIDGOLI, H., MORTAZAVI, Y., KHODADADI, A.A., 2019. A functionalized nano-structured cellulosic sorbent aerogel for oil spill cleanup: Synthesis and characterization. J. Hazard. Mater. 366, 229-239.
• CHABROS, A., GAWDZIK, B., PODKOŚCIELNA, B., GOLISZEK. M., PĄCZKOWSKI, P., 2020. Composites of unsaturated polyester resins with microcrystalline cellulose and its derivatives. Materials 13, 62.
• DING, Y., SONG, C., GONG, W., LIU, L., WU, M., LI, L., YAO, J., 2021. Robust, sustainable, hierarchical multi-porous cellulose beads via pre-crosslinking strategy for efficient dye adsorption. Cellulose 28, 7227–7241.
• DURAN, A., SOYLAK, M., TUNCEL, A., 2008. Poly(vinyl pyridine-poly ethylene glycol methacrylate-ethylene glycol dimethacrylate) beads for heavy metal removal. J. Hazard. Mater. 155, 114-120.
• FOO, K., HAMEED, B., 2010. Insights into the modeling of adsorption isotherm systems. Chem. Eng. J. 156, 2–10.
• GARBA, Z.N., LAWAN, I., ZHOU, W., ZHANG, M., WANG, L., YUAN, Z., 2020. Microcrystalline cellulose (MCC) based materials as emerging adsorbents for the removal of dyes and heavy metals – A review. Sci. Total Environ. 717, 135070.
• GERICKE, M., TRYGG, J., FARDIM, P., 2013. Functional Cellulose Beads: Preparation, Characterization, and Applications. Chem. Rev. 113, 4812–4836.
• GOLISZEK, M., PODKOŚCIELNA, B., FILA, K., RIAZANOVA, A.V., AMINZADEH, S., SEVASTYANOVA, O., GUN’KO, V.M., 2018. Synthesis and structure characterization of polymeric nanoporous microspheres with lignin. Cellulose 25, 5843-5862.
• GOLISZEK, M., PODKOŚCIELNA, B., SEVASTYNOVA, O., GAWDZIK, B., CHABROS, A., 2019a. The influence of lignin diversity on the structural and thermal properties of polymeric microspheres derived from lignin, styrene and/Or divinylbenzene. Materials 12, 2847.
• GOLISZEK, M., SOBIESIAK, M., FILA, K., PODKOŚCIELNA, B., 2019b. Evaluation of sorption capabilities of biopolymeric microspheres by the solid-phase extraction. Adsorption 25, 289-300.
• HALYSH, H., SEVASTYANOVA, O., PIKUS, S., DOBELE, G., PASALSKIY, B., GUN’KO, V.M., KARTEL, M., 2020. Sugarcane bagasse and straw as low-cost lignocellulosic sorbents for the removal of dyes and metal ions from water. Cellulose 27, 8181-8197.
• KOBAYASHI, S., SAKAMOTO, J., KIMURA, S., 2001. In vitro synthesis of cellulose and related polysaccharides. Prog. KONG, Q., WANG, X., LOU, T., 2020. Preparation of millimeter-sized chitosan/carboxymethyl cellulose hollow kapsule and its dye adsorption properties. Carbohydr. Polym. 244, 116481.
• KUMAR, R., SHARMA, R.K., 2019. Functionalized cellulose with hydroxyethyl methacrylate and glycidyl methacrylate for metal ions and dye adsorption applications. Int. J. Biol. Macromol. 134, 704-721.
• LUO, X., ZHANG, L., 2009. High effective adsorption or organic dyes on magnetic cellulose beads entrapping activated carbon. J. Hazard. Mater. 171, 340-347.
• MALL, I. D., SRIVASTAVA, V. C., AGARWAL, N. K., 2007. Adsorptive removal of Auramine-O: Kinetic and equilibrium study. J. Hazard. Mater. 143(1-2), 386–395.
• NAMASIVAYAM, C., YAMUNA, R., ARASI, D.J.S.E., 2001. Removal of acid violet from wastewater by adsorption on waste red mud. Environ. Geol. 41, 269-273.
• OLGUN, A., ATAR, N., 2009. Equilibrium and kinetic adsorption study of Basic Yellow 28 and Basic Red 46 by a boron industry waste. J. Hazard. Mater. 161(1), 148–156.
• QIAO, L., CHEN, K., ZHAO, D., ZHAN, Y., MIN, W., HUANG, Q., SHEN, G., ZHOU, J., 2017. The application of poly(methyl methacrylate-co-butyl acrylate-co-styrene) in reinforcing fragile papers: experiments and computer simulations. Cellulose 24, 5157–5171.
• RAMOS, R.R.F., SIQUEIRA, D.D., WELLEN, R.M.R., LEITE, I.F., GLENN, G.M., MEDEIROS, E.S., 2019. Development of green composites based on polypropylene and corncob agricultural residue. J. Polym. Environ. 27, 1677–1685.
• VARGHESE, A.G., PAUL, S.A., LATHA, M.S., 2019. Remediation of heavy metals and dyes from wastewater Rusing cellulose-based adsorbents. Environ. Chem. Lett. 17, 867-877.
• WAWRZKIEWICZ, M., KOTOWSKA, U., SOKÓŁ, A., 2021. Purification of textile effluents containing C.I. Acid Violet 1: adsorptive removal versus hydrogen peroxide and peracetic acid based advanced oxidation. Processes 9, 1911.
• WIŚNIEWSKA, M., WAWRZKIEWICZ, M., ONYSZKO, M., MEDYKOWSKA, M., NOSAL-WIERCIŃSKA, A., BOGATYROV, V., 2021. Carbon-silica composite as adsorbent for removal of hazardous C.I. Basic Yellow 2 and C.I. Basic Blue 3 dyes. Materials 14(12), 3245.
• WNUCZEK, K., PODKOŚCIELNA, B., SOBIESIAK, M., SZAJNECKI, Ł., GOLISZEK M., 2020. Synthesis and modification by carbonization of styrene-ethylene glycol dimethacrylate-lignin sorbents and their sorption of acetylsalicylic acid. Materials 13, 1761.
• WU, S., GONG, Y., LIU, S., PEI, Y., LUO, X., 2021. Functionalized phosphorylated cellulose microspheres: Design, characterization and ciprofloxacin loading and releasing properties. Carbohydr. Polym. 254, 117421.
• YU, H.Y., ZHANG, D.Z., LU, F.F., YAO, J., 2016. New approach for single-step extraction of carboxylated cellulose nanocrystals for their use as adsorbents and flocculants. ACS Sustain. Chem. Eng. 4, 2632–2643.
• YANG, X., ZHU, W., SONG, Y., ZHUANG, H., TANG, H., 2021. Removal of cationic dye BR46 by biochar prepared from Chrysanthemum morifolium Ramat straw: A study on adsorption equilibrium, kinetics and isotherm. J. Mol. Liq. 340, 116617.
• ZHU, W., LIU, L., LIAO, Q., CHEN, X., QIAN, Z., SHEN, J., LIANG, J., YAO, J., 2016. Functionalization of cellulose with hyperbranched polyethylenimine for selective dye adsorption and separation. Cellulose 23, 3785–3797.

Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).