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Synthesis and characterization of the aluminum phosphates modified with ammonium, calcium and molybdenum were conducted. The influence of process parameters (reactive pressure and molar ratios) in the reaction mixture were studied. The contents of the individual components in the products were in the range of: 10.97–17.31 wt% Al, 2.65–13.32 wt% Ca, 0.70–3.11 wt% Mo, 4.36–8.38 wt% NH3, and 35.12–50.54 wt% P2O5. The materials obtained in the experiments were characterized by various physicochemical parameters. The absorption oil number was in the range from 67 to 89 of oil/100 g of product, the surface area was within the range of 4–76 m2/g, whereas the average particle size of products reached 282–370 nm. The Tafel tests revealed comparable anticorrosive properties of aluminum phosphates modified with ammonium, calcium, molybdenum in comparison with commercial phosphate.
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131--139
Opis fizyczny
Bibliogr. 17 poz., rys., tab.
Twórcy
autor
- West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, ul. Pułaskiego 10, 70-322 Szczecin, Poland
autor
- West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, ul. Pułaskiego 10, 70-322 Szczecin, Poland
autor
- West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, ul. Pułaskiego 10, 70-322 Szczecin, Poland
autor
- West Pomeranian University of Technology, Szczecin, Polymer Institute, ul. Pułaskiego 10, 70-322 Szczecin, Poland
Bibliografia
- 1. Benda, P. & Kalendová, A. (2013). Anticorrosion Properties of Pigments based on Ferrite Coated Zinc Particles. Phys. Procedia. 44, 185–194. DOI: 10.1016/j.phpro.2013.04.023.
- 2. Directive 2004/42/CE of the European Parliament and of the Council of 21 April 2004 on the limitation of emissions of volatile organic compounds due to the use of organic solvents in certain paints and varnishes and vehicle refi nishing products and amending Directive 1999, 13/EC.
- 3. United States Environmental Protection Agency. Retrieved Decmember 1, 2014, from http://www.epa.gov/iaq/voc.html
- 4. Mousavifard, S.M., MalekMohammadi Nouri, P., Attar, M.M. & Ramezanzadeh, B. (2013). The effects of zinc aluminum phosphate (ZPA) and zinc aluminum polyphosphate (ZAPP) mixtures on corrosion inhibition performance of epoxy/polyamide coating. Ind. Eng. Chem. Res. 19, 1031–1039. DOI: 10.1016/j.jiec.2012.11.027.
- 5. Kołodziejski, R., Zieliński, J. & Grudzińska, E. (2009). Effect of microwaves on properties of desulfurized vacuum residue of crude oil. Przem. Chem. 88(11), 1188–1190.
- 6. Deyab, M.A. & Keera, S.T. (2014). Effect of nano-TiO2 particles size on the corrosion resistance of alkyd coating. Mater. Chem. Phys. 146, 406–411. DOI: 10.1016/j.matchemphys. 2014.03.045.
- 7. Grzmil, B., Kic, B. & Lubkowski, K. (2007). Studies on obtaining of zinc phosphate nanomaterials. Rev. Adv. Mater. Sci. 14, 46–48.
- 8. Łuczka, K., Grzmil, B., Srenscek-Nazzal, J. & Kowalczyk, K. (2013) Studies on obtaining of aluminium ammonium calcium phosphates. J. Ind. Eng. Chem. 19, 1000–1007. DOI: 10.1016/j.jiec.2012.11.023.
- 9. Łuczka, K., Sibera, D., Smorowska, A. & Grzmil, B. (2013) Preparation of aluminium ammonium calcium phosphates using microwave radiation. Chem. Pap. 67(9), 1210–1217. DOI: 10.2478/s11696-013-0326-8.
- 10. Varnaite – Żuravliova, S., Jankauskaite, V., Guobiene, A. & Prosycevas, I. (2014). Investigation of optical and morphological properties of metalized nanocomposites. Appl. Surf. Sci. 317, 639–647. DOI: 10.1016/j.apsusc.2014.08.149.
- 11. Huang, H., Zhang, S., Qi, L., Yu, X. & Chen, Y. (2006). Microwave-assisted deposition of uniform thin gold film on glass surface. Surf. Coat. Technol. 200, 4389–4396. DOI: 10.1016/j.surfcoat.2005.02.203.
- 12. Gaina, L., Torje, I., Gal, E., Lupan, A., Bischin, C., Silaghi-Dumitrescu, R., Damian, G., Lönnecke, P., Cristea, C. & Silaghi-Dumitrescu, L. (2014). Microwave assisted synthesis, photophysical and redox properties of (phenothiazinyl)vinylpyridinium dyes. Dyes Pigm. 102, 315–325. DOI: /10.1016/j.dyepig.2013.10.044.
- 13. Beall, G.W., Duraia, E.M., El-Tantawy, F., Al-Hazmi, F. & Al-Ghamdi, A.A. (2013). Rapid fabrication of nanostructured magnesium hydroxide and hydromagnesite via microwaveassisted technique. Powder Technol. 234, 26–31. DOI: 10.1016/j.powtec.2012.09.029.
- 14. Box, G.E.P., Hunter, J.S. & Hunter, W.G. (2005). Statistics for Experimenters. Hoboken, NJ: Wiley – Interscience.
- 15. Minczewski, J. & Marczenko, Z. (2005). Chemia analityczna. Warszawa, PWN.
- 16. Orion Ammonia Electrode. (2003). Instruction manual, Thermo Electron Corporation. Texas, USA.
- 17. Polish Committee for Standardization. (1999). General methods of test for pigments and extenders – Part 5: Determination of oil absorption value. PN EN ISO 787-5:1995, Warsaw.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-bc85c37b-fba0-4f5b-9219-57ab52732522