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The origin and chemical composition of Carpathians chloride CO2-rich waters in the light of stable chlorine isotope studies (37Cl and 35Cl)

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Investigations into chloride CO2-rich water occurring in the Polish and Slovakian Carpathians were carried out to gain a better understanding of the Cl- sources. The primary Cl- concentration in sea water, processes accompanying diagenesis, together with water-rock-gas interactions, have undoubtedly influenced the present content of chlorides. The Cl-- concentrations in the waters analysed vary from 35.5 to 4148.3 mg/l, lower than in sea water, with a mean ~19000 mg/l. The measured δ37Cl values range from -1.15 to -0.26‰, below the typical sea water value of 0‰. It might be concluded that the chemical and isotopic composition of these waters are the result of reactions during diagenesis (e.g., ion exchange or diffusion through low-permeability clay layers) as well as meteoric water influx.
Rocznik
Strony
197--204
Opis fizyczny
Bibliogr. 36 poz., rys., tab., wykr.
Twórcy
  • AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. A. Mickiewicza 30, 30-059 Kraków, Poland
autor
  • Maria Curie-Sklodowska University, Mass Spectrometry Laboratory, 20-031 Lublin, Poland
  • AGH University of Science and Technology, Faculty of Geology, Geophysics and Environmental Protection, al. A. Mickiewicza 30, 30-059 Kraków, Poland
Bibliografia
  • 1. Alletti, M., Baker, D.R., Scaillet, B., Aiuppa, A., Moretti, R., Ottolini, L., 2009. Chlorine partitioning between a basaltic melt and H2O-CO2 fluids at Mount Etna. Chemical Geology, 263: 37-50.
  • 2. Bačová, N., Bačo, P., Komoň, J., 2009. Hydrogeological conditions of discharge area, chemical composition and origin of natural curative water Cigel’ka (in Slovak with English summary). Podzemná Voda, 15: 216-229.
  • 3. Birkenmajer, K., 1986. Stages of structural evolution of the Pieniny Klippen Belt, Carpathians. Studia Geologica Polonica, 88: 7-32.
  • 4. Bojdys, G., Lemberger, M., 1986. Three-dimensional gravity modelling of Earth’s crust and upper mantle in the Polish Carpatthians. Annales Societatis Geologorum Poloniae, 56: 349-373.
  • 5. Chowaniec, J., 1991. Region karpacki (in Polish). In: Budowa geologiczna Polski, 7, Hydrogeologia (ed. J. Malinowski): 204-215. Wyd. Geol., Warszawa.
  • 6. Desaulniers, D.E., Kaufmann, R.S., Cherry, J.A., Bentley, H.W., 1986. 37Cl-35Cl variations in a diffusion-controlled groundwater system. Geochimica et Cosmochimica Acta, 50: 1757-1764.
  • 7. Dowgiałło, J., 1980. Poligenetyczny model karpackich wód chlorkowych i niektóre jego konsekwencje (in Polish). In: Współczesne problemy hydrogeologii regionalnej, Jachranka: 275-290. Wyd. Geol., Warszawa.
  • 8. Edmunds, W.M., 1996. Bromine geochemistry of British groundwaters. Mineralogical Magazine, 60: 275-284.
  • 9. Eggenkamp, H.G.M., 2004. Summary of methods for determining the stable isotope composition of chlorine and bromine in natural materials. In: Handbook of Stable Isotope Analytical Techniques (ed. P.A. de Groot). Elsevier, Amsterdam.
  • 10. Eggenkamp, H.G.M., Kreulen, R., Koster van Groos, A.F., 1995. Chlorine stable isotope fractionation in evaporites. Geochimica et Cosmochimica Acta, 59: 5169-5175.
  • 11. Godon, A.R., Jendrzejewski, N., Eggenkamp, H.G.M., Banks, D.A., Ader, M., Coleman, M.L., Pineau, F., 2004. A cross-calibration of chlorine isotopic measurements and suitability of seawater as the international reference material. Chemical Geology, 207: 1-12.
  • 12. Golonka, J., Krobicki, M., Waśkowska, A., Cieszkowski, M., Ślączka, A., 2015. Olistostromes of the Pieniny Klippen Belt, northern Carpathians. Geological Magazine, 152: 269-286.
  • 13. Hałas, S., Pelc, A., 2009. New isotope ratio mass spectrometfic method of precise δ37Cl determinations. Rapid Communications in Mass Spectrometry, 23: 1061-1064.
  • 14. Hoefs, J., 2009. Stable Isotope Geochemistry. Springer, Berlin.
  • 15. Lavastre, V., Jenderzejewski, N., Agrinier, P., Javoy, M., Evrard, M., 2005. Chlorine transfer out of a very low permeabillty clay sequence (Paris Basin, France): 35Cl and 37Cl evidence. Geochimica et Cosmochimica Acta, 69: 4949-4961.
  • 16. Leśniak, P.M., 1980. The origin of chloride waters in Wysowa, West Carpathians. Chemical and isotopic approach. Acta Geologica Polonica, 30: 519-550.
  • 17. Long, A., Eastoe, C.J., Kaufmann, R.S., Martin, J.G., Wirt, L., Finley, J.B., 1993. High-precision measurement of chlorine stable isotope ratios. Geochimica et Cosmochimica Acta, 57: 2907-2912.
  • 18. Macioszczyk, A., 1987. Hydrogeochemia (in Polish). Wyd. Geol., Warszawa.
  • 19. Małecka, D., Chowaniec, J., Małecki, J.J., 2007. Region górnej Wisły (in Polish). In: Hydrogeologia regionalna Polski, I. Wody słodkie (eds. B. Paczyński and A. Sadurski): 108-159. Państwowy Instytut Geologiczny, Warszawa.
  • 20. Manning, C.E., 2004. The chemistry of subduction-zone fluids. Earth and Planetary Science Letters, 223: 1-16.
  • 21. Marcin, D., 1999. Mineral water-bearing hydrogeological structures in the Magura Unit of The Flysch Belt, Eastern Slovakia. In: Proceedings IAH Congress XXIX - Hydrogeology and Land Use Management (eds. M. Fendekova and M. Fendek): 701-706. Bratysława.
  • 22. Marcin, D., 2002. Hydrogeological structures Šarišský Štiavnik and Radoma (in Slovak with English summary). Podzemná Voda, 8: 116-122.
  • 23. Ney, R., 1975. Tectogenesis of the Carpathians in the light of new tectonics of the Earth’s globe. Publications of the Institute of Geophysics, Polish Academy of Sciences, 82: 95-110.
  • 24. Oszczypko, N., 1992. Late Cretaceous evolution of the Magura Basin. Abstracts of 6th Annual Meeting of IGCP 262 Cretaceous facies in Orogenic Belts, Athens: 14-15.
  • 25. Oszczypko, N., 1997. The Early-Middle Miocene Carpathian petripheral foreland basin (Western Carpathian, Poland). Przegląd Geologiczny, 45: 1054-1063.
  • 26. Oszczypko, N., 1999. From remnant oceanic basin to collision-related foreland basin - a tentative history of the Outer Carpatthians. Geologica Carpathica, 50: 161-163.
  • 27. Oszczypko, N., Zuber, A., 2002. Geological and isotopic evidence of diagenetic waters in the Polish Flysch Carpathians. Geologica Carpathica, 53: 257-268.
  • 28. Oszczypko, N., Ślączka, A., Żytko, K., 2008. Tectonic subdivision of Poland: Polish Outer Carpathian and their foredeep (in Polish with English summary). Przegląd Geologiczny, 56: 927-935.
  • 29. Paczyński, B., Płochniewski, Z., 1996. Wody mineralne i lecznicze Polski (in Polish). Państwowy Instytut Geologiczny , Warszawa.
  • 30. Pelc, A., Hałas, S., 2008. Negative ion source for chlorine isotope ratio measurements. Rapid Communications in Mass Spectrometry, 22: 3977-3982.
  • 31. Rajchel, L., 2012. Szczawy i wody kwasowęglowe Karpat polskich (in Polish). Wydawnictwa Naukowe AGH, Kraków.
  • 32. Ransom, B., Spivack, A.J., Kastner, M., 1995. Stable Cl isotopes in subduction-zone pore waters; implications for fluid-rock reactions and the cycling of chlorine. Geology, 23: 715-718.
  • 33. Ransom, B., Kastner, M., Spivack, A.J., 1998. Chlorine/fluid cycling in subduction zones: evidence from chloride concentrations and chlorine stable isotopes. Mineralogical Magazine, 62a: 1233-1234.
  • 34. Spivack, A.J., Kastner, M., Ransom, B., 2002. Elemental and isotopic chloride geochemistry and fluid flow in the Nankai Trough. Geophysical Research Letters, 29: 1661.
  • 35. Świdziński, H., 1972. Geology and mineral waters of Krynica (in Polish with English summary). Prace Geologiczne, 70: 5-105.
  • 36. White, D.E., Barnes, J., O'Neil, J.R., 1973. Thermal and mineral waters of nonmeteoric origin, California Coast Ranges. GSA Bulletin, 84: 547-560.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-bba8955f-e499-414c-828d-96f293f0d37b
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