Plasticizing properties improvement of poly (4-vinylpyridine)/clay composites: effect of composition and clay nature

• Autorzy: Dergal Fayçal , Lerari Djahida , Khaldoun Bachari

Identyfikatory

DOI

10.2478/adms-2021-0014

• Języki publikacji: EN

Abstrakty

EN

A significant number of investigations have been reported on the elaboration and characterization of Polymer/Clays composites, via different methods. In our work, new composites materials were successfully prepared by in-situ polymerization of 4-vinylpyridine (4VP), in presence of two different types of Algerian modified clays (Maghnia and Mostaganem), noted (BC) and (MC), respectively. Different percentage clays (1 wt%, 3 wt% and 5 wt%) have been used. The differential scanning calorimetry analysis reveals the variation of glass transition temperature (Tg) of the copolymer in the composite materials. We show a decrease glass transition temperature (Tg) from 147°C to 131°C for P4VP-BC and from 147°C to 124°C for P4VP-MC according to the increase percentage of clays. Thermogravimetric analysis (TGA) shows good stability of composite materials at high temperature. Fourier Transformed Infrared (FTIR), Scanning Electron Microscopy coupled with Energy dispersive X-Ray Spectroscopy (SEM-EDX) and 1H NMR spectroscopy are used to show the presence of the clays in the materials.

Słowa kluczowe

EN

composite; P4VP; clays; in-situ polymerization

PL

kompozyt; P4VP; glina; polimeryzacja in situ

• Wydawca: Politechnika Gdańska
• Czasopismo: Advances in Materials Science
• Rocznik: 2021
• Tom: Vol. 21, nr 3(69)
• Strony: 5--16
• Opis fizyczny: Bibliogr. 25 poz., tab., wykr., zdj.

Twórcy

autor

Dergal Fayçal

• Centre de Recherche Scientifique et Technique en Analyses Physico-chimiques (CRAPC), Bp 384 Bousmail Tipaza, Algeria
• University of Tlemcen, Laboratoire de Catalyse et Synthèse en Chimie Organique (LCSCO) Department of Chemistry, Tlemcen, 13000, Algeria

autor

Lerari Djahida

• Centre de Recherche Scientifique et Technique en Analyses Physico-chimiques (CRAPC), Bp 384 Bousmail Tipaza, Algeria

autor

Khaldoun Bachari

• Centre de Recherche Scientifique et Technique en Analyses Physico-chimiques (CRAPC), Bp 384 Bousmail Tipaza, Algeria

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).