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Competitive flotation and solvent sublation of Zn(II) and Mn(II) ions from diluted, model and experimental, aqueous solutions (after leaching of spent Zn-Mn battery) by proton-ionizable lariat ethers in the presence of octylphenylodecyl (ethylene glycol) ether (Triton X-100) as a nonionic foaming agent were investigated. The influence of ether crown size variations (from DB-16-C-5 through DB-19-C-6 to DB-22-C-7) on separation of zinc(II) and manganese(II) ions as well as influence of structural variation within the collectors (identity of the pendent acidic group and lipophilicity) and pH of the aqueous solutions were presented. It was found that among seven tested proton-ionizable lariat ethers, the most effective removal of Zn(II) and Mn(II) ions from diluted aqueous solutions may be achieved with the use of sodium 3-[sym-(Decyl)dibenzo-22-crown-7-oxy]propane-sulfonate).
Słowa kluczowe
Rocznik
Tom
Strony
1048--1060
Opis fizyczny
Bibliogr. 26 poz., rys. tab.
Twórcy
autor
- Wroclaw University of Technology, Wybrzeze Stanislawa Wyspianskiego 27, Wroclaw, Poland
autor
- Czestochowa University of Technology, ul. J. H. Dabrowskiego 69, Czestochowa, Poland
autor
- Wroclaw University of Technology, Wybrzeze Stanislawa Wyspianskiego 27, Wroclaw, Poland
Bibliografia
- AGUILAR J. C., RODRIGUEZ DE SAN MIGUEL E., DE GYVES J., BARTSCH R.A., KIM M., 2001, Design, synthesis and evaluation of diazadibenzocrown ethers as Pb2+ extractants and carriers in plasticized cellulose triacetate membranes, Talanta, 54, 1195-1204.
- BOND A.H., DIETZ M.L., ROGERS R.D., 1999, Metal ions separation and preconcentration, ACS Washington, DC.
- CHAREWICZ W., HOLOWIECKA B.A., WALKOWIAK W., 1999, Selective flotation of zinc(II) and silver(I) ions from dilute aqueous solutions, Sep. Sci. Technol., 34, 2447 - 2460.
- CHAREWICZ W., GRABOWSKA J., BARTSCH R.A., 2001, Flotation of Co(II), Sr(II), and Cs(I) cations with proton-ionizable lariat ethers, Sep. Sci. Technol., 31, 1479-1494.
- CHENG Q., DONG H., 2005, Solvent sublation using dithizone as a ligand for determination of trace elements in water samples, Microchimica Acta, 150, 59-65.
- HABASHI F., Textbook of Hydrometallurgy, Metallurgy Extractive Quebec, Quebec, 1999.
- JURKIEWICZ K., 1990, The removal of zinc from solutions by foam separation. I. Foam separation of complex zinc anions, Int. J. Miner. Process., 28, 173 - 187.
- KIM Y-S., CHOI Y-S., LEE W., LEE Y-I., 2001, Determination of zinc and lead in water samples by solvent sublation using ion pairing of metal-naphthoate complexes and tetra-n-butylammonium ion, Bulletin of the Korean Chemical Society., 22, 821-826.
- KIM Y-S., SHIN J-H., CHOI Y-S., LEE W., 2003, Studies on solvent sublation of trace heavy metals by continuous flow system as ternary complexes of 1,10-phenanthroline and thiocyanate ion, Bulletin of the Korean Chemical Society, 24, 1775-1780.
- KOIDE Y., OKA T., IMAMURA A., SHOSENJI H., YAMADA K., 1993, Studies of collectors. XIII. The flotation of cesium ion with resorcinol-type calix[4]arenes with alkyl side chains, Bull. Chem. Soc. Jpn., 66, 2137–2142.
- KOIDE Y., TERASAKI H., SATO H., SHOSENCJI H., YAMADA K., 1996,Flotation of uranium from seawater with phosphate esters of C-undecylcalix[4]resorcinarene, Bull. Chem. Soc. Jap., 69, 785–790. KOZLOWSKI C., ULEWICZ M., WALKOWIAK W.,2000, Separation of zinc and cadmium ions from aqueous chloride solutions by ion flotation and liquid membranes, Physicochem. Probl. Miner. Process., 34, 141-151.
- KOZLOWSKI C.A., ULEWICZ M., WALKOWIAK W., GIREK T., JABLONSKA J.,2002,The effect of tautomeric rearrangement on the separation of Zn(II) and Cd(II) in ion flotation process with 4-thiazolidinone derivatives, Minerals Engineering, 15, 677-682.
- LU Y., ZHU X., 2001, Solvent sublation: theory and application, Separation and Purification Methods., 30, 157-189.
- MACIEJEWSKI P., ULEWICZ M., ROBAK W., WALKOWIAK W., 2011, Lariat ethers with a novel proton-ionisable groups: new generation of collectors in ion flotation process, Int. J. Environment and Waste Management, 8, 305-324
- MACIEJEWSKI P., WALKOWIAK W., 2004, Selective removal of caesium(I), strontium(II) and bariom(II) ations with proton-ionizable lariat ethers in the ion flotation process, Physicochem. Probl. Miner. Process., 38, 139-146.
- WALKOWIAK W., KANG S.I., STEWARD L.E., NDIP G., BARTSCH R.A.,1990, Effect of ring size variation within lipophilic crown ether carboxylic acid on the selectivity and efficiency of competitive alkali-metal cation solvent extraction into chloroform, Anal. Chem., 62, 2022÷2026.
- SCHULZ J.C., WARR G.G.,1998, Selective flotation of ions by macrocyclic complexation, Ind. Eng. Chem. Res., 37, 2807-2811.
- SOBIANOWSKA K., 2012, The ion flotation Cs+, Sr2+, Ba2+ and Co2+ from aqueous solutions using macrocyclic compounds, Doctoral dissertation, Wroclaw University of Technology.
- SOBIANOWSKA K., WALKOWIAK W., KOZŁOWSKI C., 2009, Principles and applications of solvent sublation – a review, Ars Separatoria Acta. 7, 23-38.
- ULEICZ M., MACIEJEWSKI P., 2008, Proton- ionizable lariat ethers in ion flotation process – effect of alkali metal cations, Ars Separatoria Acta, 6, 244-245.
- ULEWICZ M., SADOWSKA K., BIERNAT J.F., 2007, Selective transport of Pb(II) across polymer inclusion membrane using imidazole azocrown ethers as carriers, Physicochem. Probl. Miner. Process., 41, 133-143.
- ULEWICZ M., WALKOWIAK W., JANG Y., KIM S. J.,BARTSCH R.A., 2003a, Ion flotation of cadmium(II) and zinc(II) in the presence of proton-ionizable lariat ethers, Anal. Chem., 75, 2276-2279.
- ULEWICZ M., WALKOWIAK W., BARTSCH R.A., 2006, Ion Flotation of Zinc(II) and Cadmium(II) with Proton-Ionizable LariatEthers – The effect of cavity size, Separ. Purif. Technol., 48, 264-269.
- ULEWICZ M., WALKOWIAK W., BRANDT K., PORWOLIC-CZOMBERLIKP I.,2003b, Ion flotation of zinc(II) and cadmium(II) in the presence of side-armed diphosphaza-16-crown-6ethers, Sep. Sci. Technol.,38, 633-645.
- WALKOWIAK W., ULEWICZ M.,1999, Kinetics studies of ion flotation, Physicochem. Probl. Miner. Process., 33, 201-214.
- WALKOWIAK W., NDIP G., BARTSCH R.A.,1999, Effect of structural variation within lipophilic lariat ether phosphonic acid monoesters on the selectivity and efficiency of competitive alkali metal cation extraction into chloroform, Anal. Chem., 71, 1021÷1026. ZOUBOULIS A.I., MATIS K.A., 1987, Ion flotation in environmental technology, Chemosphere, 16, 623÷631.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-ba3ec895-879d-4ae3-a23c-ff64fdeee0c0