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Improving spodumene flotation using a mixed cationic and anionic collector

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Lithium, a rare-earth element, has been in increasing demand. Spodumene flotation is an important and challenging step for lithium extraction and production from lithium ore. In the present work, flotation tests for three pure minerals (i.e., spodumene, quartz and feldspar) and a real spodumene ore were carried out at laboratory scale. The results showed that YOA, a mixture of oleic acid and dodecylamine with the molar ration of 10:1, could be used as collector to produce a spodumene concentrate with grade of 5.59% Li2O from the feed ore with grade of 1.48% Li2O where 85.24% of Li2O was recovered to the concentrate. The measured zeta potential, contact angle and adsorption capacity indicated that YOA was preferentially adsorbed on spodumene instead of on quartz or feldspar, with the spodumene surface being more hydrophobic than that of feldspar or quartz. The adsorption energies of YOA on spodumene were calculated and the results provided insights into the superior flotation performance obtained in the present work.
Rocznik
Strony
567--577
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
autor
  • School of Minerals Processing & Bioengineering, Central South University, Changsha 410083, China
autor
  • School of Minerals Processing & Bioengineering, Central South University, Changsha 410083, China
autor
  • School of Resources and Environmental Engineering, Shandong University of Technology, Zibo 255049, China
autor
  • School of Minerals Processing & Bioengineering, Central South University, Changsha 410083, China
autor
  • School of Chemical Engineering, The University of Queensland, Brisbane Qld 4072, Australia
autor
  • School of Minerals Processing & Bioengineering, Central South University, Changsha 410083, China
autor
  • School of Minerals Processing & Bioengineering, Central South University, Changsha 410083, China
Bibliografia
  • AMARANTE M. M.,BOTELHO DE SOUSA A.,MACHADO LEITE M., 1999. Processing a spodumene ore to obtain lithium concentrates for addition to glass and ceramic bodies.Miner. Eng., 12(4), 433-436.
  • BAYAT O., ARSLAN V., CEBECI Y., 2006. Combined application of different collectors in the floatation concentration of Turkish feldspars. Miner. Eng., 19 (1), 98–101.
  • DE SOUSA B.A., AMARANTE M.M., LEITE M.M., 2000. Beneficiation studies on a spodumene ore from Portugal. Dev. Miner. Process., 13, C11-40-C11-46.
  • FELIX B., REINER H., 2010. New concepts for lithium minerals processing. Miner. Eng., 23(8), 659-661.
  • CAO Q., CHENG J., WEN S., LI C., BAI S., LIU D., 2015, A mixed collector system for phosphate flotation. Miner. Eng., 78,114-121.
  • HE J., 2009. Application of a new collector in the flotation of lithium and beryl minerals. J. Xinjiang Nonferrous Met. (In Chinese), 2, 37-38.
  • LABIDI N. S.,DJEBAILI A., 2008, Studies of the mechanism of polyvinyl alcohol adsorption on the calcite/water interface in the presence of sodium oleat. J. Miner. Mater. Charact. Eng., 7(2), 421-435.
  • LEE K., ARCHIBALD D., MCLEAN J., REUTER M.A., 2009. Flotation of mixed copper oxide and sulphide minerals with xanthate and hydroxamate collectors. Miner. Eng., 22(4), 395–401.
  • LIU N. 2008. Experiments on the flotation of V26 and V38 spodumene ore body in Koktokay, J. of Xinjiang Nonferrous Met. (In Chinese), 5, 48-49.
  • LOTTER N.O.,BRADSHAW D.J., 2010. The formulation and use of mixed collectors in sulphide flotation, Miner. Eng., 23(11),945-951.
  • LUO X., LV L.,CHEN X., 2012. Direct flotation of a low grade and refractory spodumene ore, Nonferrous Met. Eng. (In Chinese), 5, 36-39.
  • LU D., HU Y., LI Q., YU S., JIANG T., SUN W., WANG Y., 2016. Improving the recovery of fine auriferous pyrite using iso-amylxanthate and its isomeride. Miner. Eng., 92, 57-62.
  • LU Y., SUN S., 2007. Development and rule of combined reagents. Min. Eng. (In Chinese), 5(6), 42-44.
  • EJTEMAEI M., IRANNAJAD M., GHARABAGHI M., 2011. Influence of important factors on flotation of zinc oxide mineral using cationic, anionic and mixed (cationic/anionic) collectors, Miner. Eng., 24 (13), 1402-1408.
  • MCFADZEAN B., CASTELYN D.G., O’CONNOR C.T., 2012. The effect of mixed thiol collectors on the flotation of galena, Miner. Eng., 36–38(10), 211–218.
  • MENÉNDEZ M., VIDAL A., TORAÑO J., GENT M., 2004. Optimisation of spodumene flotation. Eur. J. Miner. Process. Environ. Prot., 4(2), 130-135.
  • MOON K.S., FUERSTENAU W.D., 2003. Surface crystal chemistry in selective flotation of spodumene (LiAl[SiO3]2) from other aluminosilicates. Int. J. Miner. Process., 72(1~4),11-24.
  • VIDYADHAR A., RAO K.H.,CHERNYSHOVA I., 2003. Mechanisms of Amine-Quartz Interaction in the Absence and Presence of Alcohols Studied by Spectroscopic Methods. J. Colloid Interface Sci., 214(1–3), 127-142.
  • VIDYADHAR A., RAO K.H., 2007. Adsorption mechanism of mixed cationic/anionic collectors in feldspar-quartz flotation system. J. Colloid Interface Sci., 306, 195–204.
  • VIDYADHAR A., KUMARI N., BHAGAT R.P., 2012. Adsorption mechanism of mixed collector systems on hematite flotation, Miner. Eng., 26(1), 102-104.
  • WANG Y., YU F., 2005. New collector for the flotation of spodumene and beryl. J. Cent. S. Univ. (In Chinese), 36(5), 807-811.
  • XU L., HU Y., TIAN J., WU H., YANG Y., ZENG X., WANG J., 2016. Selective flotation separation of spodumene from feldspar using new mixed anionic/cationic collectors. Miner. Eng., 89, 84-92.
  • YU F., WANG Y., ZHANG L., ZHU G., 2015. Role of oleic acid ionic molecule complexes in the flotation of spodumene. Miner. Eng., 71, 7-12.
  • ZHU G., WANG Y., LIU X., YU F., LU D., 2015. The cleavage and surface properties of wet and dry ground spodumene and their flotation behavior. Appl. Surf. Sci., 357 (part A), 333-339.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-ba14a203-829c-4cfd-b3fa-09d21a6dbd9e
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