Gas chromatographic determination of parabens after in-situ derivatization and dispersive liquid-liquid microextraction

• Autorzy: Prichodko A , Janenaite E , Smitiene V , Vickackaite V.
• Języki publikacji: EN

Abstrakty

EN

Dispersive liquid-liquid microextraction in combination with an in situ derivatization is suggested for parabens sampling and preconcentration. The derivatization was carried out with acetic anhydride under alkaline conditions maintained using di-potassium hydrogen phosphate. The effects of an extraction solvent type, extraction and disperser solvents volume, extraction time, and ionic strength of the solution on the extraction efficiency were investigated. Chlorobenzene containing n-hexadecane as internal standard was used as an extracting solvent and acetone was used as a disperser solvent. The calibration graphs were linear up to 10 mg mL^-1, correlation coefficients were 0.997–0.999, enrichment factors were from 70 for methylparaben to 210 for butylparaben, and detection limits were 22, 4.2, 3.3, and 2.5 µg L−1 for methylparaben, ethylparaben, propylparaben, and butylparaben, respectively. Repeatabilities of the results were acceptable with relative standard deviations up to 11%. A possibility to apply the proposed method for parabens determination in water samples was demonstrated.

Słowa kluczowe

EN

dispersive liquid-liquid microextraction; gas chromatography; parabens; derivatization; water samples

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2012
• Tom: Vol. 24, no. 4
• Strony: 589--601
• Opis fizyczny: Bibliogr. 31 poz., rys., tab.

Twórcy

autor

Prichodko A

• Vilnius University Department of Analytical and Environmental Chemistry Naugarduko 24 LT-03225 Vilnius Lithuania

autor

Janenaite E

• Vilnius University Department of Analytical and Environmental Chemistry Naugarduko 24 LT-03225 Vilnius Lithuania

autor

Smitiene V

• Vilnius University Department of Analytical and Environmental Chemistry Naugarduko 24 LT-03225 Vilnius Lithuania

autor

Vickackaite V.

• Vilnius University Department of Analytical and Environmental Chemistry Naugarduko 24 LT-03225 Vilnius Lithuania

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