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The microstructures of in-situ synthesized TiC by Ti-CNTs reaction in Cu melts

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In order to study the influence of the carbon nanotubes (CNTs) as a source of carbon on the microstructure of in-situ synthesized TiC in Cu melts, CNTs and Ti powders were introduced into melted Cu to prepare TiC-reinforced Cu matrix composites. The influence of Ti/C ratio and Si on the microstructures and properties of the composites were also examined. It is found that CNTs can be effectively wetted through the Ti-C reaction and successfully introduced into Cu melt to synthesize TiC. In examining the changes in Ti/C ratio, it was found that an increase in the Ti content may result in the decrease of TiC agglomeration and improvement of TiC dispersion, while simultaneously causing an increase in the TiC particle size. Besides, while the addition of Si into Ti-CNTs mixture can also improve the distribution of TiC, the effect is weak compared with that of increasing the content of Ti. It was also found that the highest hardness (238.8 HV) is achieved by the Cu-Ti-C composite with the highest Ti/C ratio, while the electrical conductivities of all the prepared composites are relatively low, which should be due to the insufficient reaction between Ti and CNTs.
Słowa kluczowe
Wydawca
Rocznik
Strony
145--158
Opis fizyczny
Bibliogr. 23 poz., rys.
Twórcy
autor
  • State Grid Hebei Electric Power Research Institute, Shijiazhuang 050021, PR China
  • State Grid Hebei Energy Technology Service Co., Ltd, Shijiazhuang 050021, PR China
autor
  • State Grid Hebei Electric Power Research Institute, Shijiazhuang 050021, PR China
  • State Grid Hebei Energy Technology Service Co., Ltd, Shijiazhuang 050021, PR China
autor
  • State Grid Hebei Electric Power Research Institute, Shijiazhuang 050021, PR China
  • State Grid Hebei Energy Technology Service Co., Ltd, Shijiazhuang 050021, PR China
autor
  • State Grid Hebei Electric Power Research Institute, Shijiazhuang 050021, PR China
  • State Grid Hebei Energy Technology Service Co., Ltd, Shijiazhuang 050021, PR China
autor
  • State Grid Hebei Electric Power Research Institute, Shijiazhuang 050021, PR China
  • State Grid Hebei Energy Technology Service Co., Ltd, Shijiazhuang 050021, PR China
autor
  • State Grid Hebei Electric Power Research Institute, Shijiazhuang 050021, PR China
  • State Grid Hebei Energy Technology Service Co., Ltd, Shijiazhuang 050021, PR China
autor
  • State Grid Hebei Electric Power Research Institute, Shijiazhuang 050021, PR China
  • State Grid Hebei Energy Technology Service Co., Ltd, Shijiazhuang 050021, PR China
autor
  • School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding 071003, PR China
autor
  • School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding 071003, PR China
Bibliografia
  • [1] Zhang JF, Jia T, Zhu HG, Xie ZH. Microstructure and mechanical properties of in-situ TiC reinforced FeCoNiCu2.0 high entropy alloy matrix composites. Mater Sci Eng A. 2021;822:141671. https://doi.org/10.1016/j.msea.2021.141671
  • [2] Radhakrishnan M, Hassan MM, Long BE, Otazu D, Lienert TJ, Anderoglu O. Microstructures and properties of Ti/TiC composites fabricated by laser-directed energy deposition. Addit Manuf. 2021;46:102198. https://doi.org/10.1016/j.addma.2021.102198
  • [3] Lu Y, Watanabe M, Miyata R, Nakamura J, Yamada J, Kato H, et al. Microstructures and mechanical properties of TiC-particulate-reinforced Ti-Mo-Al intermetallic matrix composites. Mater Sci Eng A. 2020;790:139523. https://doi.org/10.1016/j.msea.2020.139523
  • [4] Dudina DV, Vidyuk TM, Gavrilov AI, Ukhina AV, Bokhonov BB, Legan MA, et al. Separating the reaction and spark plasma sintering effects during the formation of TiC-Cu composites from mechanically milled Ti-C-3Cu mixtures. Ceram Int. 2021;47:12494–504. https://doi.org/10.1016/j.ceramint.2021.01.107
  • [5] Wang LH, Li JW, Catalano M, Bai GZ, Li N, Dai JJ, et al. Enhanced thermal conductivity in Cu/diamond composites by tailoring the thickness of interfacial TiC layer. Compos Part A Appl Sci Manuf. 2018;113:76–82. https://doi.org/10.1016/j.compositesa.2018.07.023
  • [6] Shen BL, Itoi T, Yamasaki T, Ogino Y. Indentation creep of nanocrystalline Cu-TiC alloys prepared by mechanical alloying. Scr Mater. 2000;42:893–8. https://doi.org/10.1016/S1359-6462(00)00309-2
  • [7] Besterci M, Ivan J, Kovac L, Weissgaerber T, Sauer C. Strain and fracture mechanism of Cu-TiC. Mater Lett. 1999;38:270–4. https://doi.org/10.1016/S0167-577X(98)00171-2
  • [8] Palma RH, Sepulveda AO. Creep behavior of two Cu-2 vol% TiC alloys obtained by reaction milling and extrusion. Mater Sci Eng A. 2013;588:82–5. https://doi.org/10.1016/j.msea.2013.09.024
  • [9] Palma RH, Sepulveda AH, Espinoza RA, Montiglio RC. Performance of Cu-TiC alloy electrodes developed by reaction milling for electrical-resistance welding. J Mater Process Technol. 2005;169:62–6. https://doi.org/10.1016/j.jmatprotec.2005.02.260
  • [10] Rathod S, Modi OP, Prasad BK, Chrysanthou A, Vallauri D, Deshmukh VP, et al. Cast in situ Cu-TiC composites: Synthesis by SHS route and characterization. Mater Sci Eng A. 2009;502:91–8. https://doi.org/10.1016/j.msea.2008.10.002
  • [11] Wang FL, Li YP, Yamanaka K, Wakon K, Harata K, Chiba A. Influence of two-step ball-milling condition on electrical and mechanical properties of TiC-dispersion-strengthened Cu alloys. Mater Des. 2014;64:441–9. https://doi.org/10.1016/j.matdes.2014.08.027
  • [12] Wang FL, Li YP, Wang XY, Koizumi Y, Kenta Y, Chiba A. In-situ fabrication and characterization of ultrafine structured Cu-TiC composites with high strength and high conductivity by mechanical milling. J Alloys Compd. 2016;657:122–32. https://doi.org/10.1016/j.jallcom.2015.10.061
  • [13] Zhang D, Shen P, Shi LX, Jiang QC. Wetting of B 4 C, TiC and graphite substrates by molten Mg. Mater Chem Phys. 2011;130:665–71. https://doi.org/10.1016/j.matchemphys.2011.07.040
  • [14] Wang XL, Ding HM, Qi FG, Liu Q, Fan XL, Shi Y. Mechanism of in situ synthesis of TiC in Cu melts and its microstructures. J Alloys Compd. 2017;695:3410–18. https://doi.org/10.1016/j.jallcom.2016.12.018
  • [15] Liu Q, Miao WZ, Ding HM, Glandut N, Jia H, Li CY. The introduction of SiC into Cu melts based on Ti-SiC system and its transformation. J Mater Res Technol. 2020;9:2881–91. https://doi.org/10.1016/j.jmrt.2020.01.039
  • [16] Ding HM, Wang XL, Liu Q, Wang JF, Li CY, Zhang XC. The stability and transformation of TiC with different stoichiometries in Cu-Si melts. Mater Des. 2017;135:232–8. https://doi.org/10.1016/j.matdes.2017.09.030
  • [17] Isaza Merino CA, Ledezma Sillas JE, Meza JM, Herrera Ramirez JM. Metal matrix composites reinforced with carbon nanotubes by an alternative technique. J Alloys Compd. 2017;707:257–63. https://doi.org/10.1016/j.jallcom.2016.11.348
  • [18] Wang H, Zhang ZH, Zhang HM, Hu ZY, Li SL, Cheng XW. Novel synthesizing and characterization of copper matrix composites reinforced with carbon nanotubes. Mater Sci Eng A. 2017;696:80–9. https://doi.org/10.1016/j.msea.2017.04.055
  • [19] Mendoza ME, Campos AP, Xing Y, Bell DC, Solórzano IG. Significant decrease of electrical resistivity by carbon nanotube networks in copper-MWCNTs nanocomposites: A detailed microstructure study. Diam Relat Mater. 2020;110:108083. https://doi.org/10.1016/j.diamond.2020.108083
  • [20] Rathinavel S, Priyadharshini K, Panda D. A review on carbon nanotube: An overview of synthesis, properties, functionalization, characterization, and the application. Mater Sci Eng B. 2021;268:115095. https://doi.org/10.1016/j.mseb.2021.115095
  • [21] Ding HM, Chu WW, Liu Q, Wang HQ, Hao C, Jia HR, et al. Microstructure evolution of Cu-TiC composites with the change of Ti/C ratio. Results Phys. 2019;14:102369. https://doi.org/10.1016/j.rinp.2019.102369
  • [22] Liu Q, Zhang XC, Wang Q, Miao WZ, Li CY, Ding HM. Microstructure evolution of Ti5Si3 in Cu-Ti-Si alloys. China Foundry. 2020;17:286–92. https://doi.org/10.1007/s41230-020-9140-4
  • [23] Xu XX, Li WB, Wang Y, Dong GZ, Jing SQ, Wang Q, et al. Study of the preparation of Cu-TiC composites by reaction of soluble Ti and ball-milled carbon coating TiC. Results Phys. 2018;9:486–92. https://doi.org/10.1016/j.rinp.2018.02.059
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b9040aee-0d31-4409-acaa-367cc0ba5a26
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