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The gas corrosion of the cobalt base clad layer at elevated temperature

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: Purpose of this paper is to evaluate the microstructural and mechanical properties evolution of the laser and PTA clad layers made of the powder containing cobalt after oxidation in air (750°C, 200 hours) and corrosion in exhaust gases (700°C, two month). Design/methodology/approach: The layers were made by cladding technique. Cladding was conducted with a high power diode laser HDPL ROFIN SINAR DL 020 and Plasma Transformed Arc method. The subsequent tracks were overlapped by 30÷40%. The performance of the hardfaced materials were evaluated by microstructure (optical and scanning electron microscope SEM), chemical analysis and micro hardness measurements. Findings: After heat treatment the microstructure of the clad layers did not change much, neither on the top part nor in the clad/steel interface. However the oxide layer on the surface is observed. The EDS analyze revile the composition of this scale which consisted generally of chromium and iron oxides. The semi-quantitative chemical analysis (EDS) of the dendritic regions and micro regions confirms changes in chemical contents before and after oxidation and after corrosion in exhaust gases. The oxidation at temperature 750°C for 200 hours in air and for two month in exhaust gases did not influence on the morphology of the clad layers neither on the top part nor in the clad/steel interface. However changes in chemical composition were observed. On the surface of both sort of clads the oxide layers were observed. These sorts of layers are resistant for the hot exhausted gases. Research limitations/implications: During the future research kinetic analyze of high temperature corrosion should be done also for different temperature and times of the process. Practical implications: The layers were designed as a method to prolong service time for the ship engine exhausted valve. Originality/value: The chemical composition of the powder was new one. Also using the laser cladding technique for ship engine parts is a subject of interest.
Rocznik
Strony
235--238
Opis fizyczny
Bibliogr. 16 poz., rys., wykr.
Twórcy
autor
  • Division Mechanical Department, Gdansk University of Technology, ul. Narutowicza 11/12, 80-952 Gdansk, Poland
Bibliografia
  • [1] D. Schlager, C. Theiler, H. Kohn, Protection against high temperature corrosion with laser welded claddings, applied and tested on exhaust valve discs of large diesel engines burning heavy fuel oil, Materials and Corrosion 53, (2002) 103-110
  • [2] P. Elliott, Choose materials for high-temperature environments, Chemical Engineering Progress, 97, 2 (2001) 75-85
  • [3] W H Jiang, X D Yao, H R Guan, Z Q Hu, Relationship between degeneration of M7C3 and precipitation of M23C6 in a cobalt base superalloy, Materials Science and Technology, 15, 5 (1999) 596-598
  • [4] A.S.C.M. D’Oliveira, R.S.C. Paredes, R.L.C. Santos, Pulsed current plasma transferred arc hardfacing, Journal of Materials Processing Technology 171 (2006) 167–174
  • [5] A.S.C. d`Oliveira, R. Vilar, C.G. Feder, High temperaturę behaviour of plasma transferred arc and laser Co-based alloy coatings, Applied Surface Science 201(2002) 154-160
  • [6] Jong-Ning Aoh, Jian-Cheng Chen, On the wear characteristics of cobalt-based hardfacing layer after thermal fatigue oxidation, Wear, 250 (2001) 611-620
  • [7] W.M. Smith, Surface Materials Processing. Second Edition, Backmann Verlag, Berlin-London-Paris-Warsaw, 2001.
  • [8] Jong-Ning Aoh, Yau-Ren Jeng, En-Lo Chu, Long-Tien Wu, On wear behaviour of surface clad layers under high temperature, Wear 225-229 (1999) 1114-1122
  • [9] R. Jendrzejewski, A. Conde, J.de Damborenea, G. Sliwinski, Characterisation of the laser-clad stellite layers for protective coatings, Materials and Design 23 (2002)
  • [10] A. Hidouci, J.M. Pelletier, F. Ducoi n, D. Dezert, R. El Guerjouma, Microstructural and mechanical characteristics of laser coatings, Surf. and Coat. Technology 123 (2000) 17–23
  • [11] Reidar Haugsrud, On the high-temperature oxidation of Fe, Co, Ni and Cu-based alloys with addition of a less noble element, Materials Science and Engineering A298 (2001) 216–226
  • [12] P. S. Liu, K. M. Liang, High-Temperature Oxidation Behavior of the Co-Base Superalloy DZ40M in Air, Oxidation of Metals, Vol. 53, Nos. 3/4, 2000
  • [13] R Zhao; G C Barber; Y S Wang; J E Larson, Wear mechanism analysis of engine exhaust valve seats with a laboratory simulaton, Tribology Transactions; Apr 1997; 40, 2; ProQuest Science Journals, 209
  • [14] P. Berthod, S. Michon, L. Aranda, S. Mathieu, J.C. Gachon, Experimental and thermodynamic study of the microstructure evolution in cobalt-base superalloys at high temperature, Computer Coupling of Phase Diagrams and Thermochemistry 27 (2003) 353–359
  • [15] Yongqiang Yang, H.C. Man, Microstructure evolution of laser clad layers of W-C-Co alloy powders, Journal of Materials Processing Technology 79
  • [16] V. Kuzucu, M. Ceylan,, H. Çelik, I. Aksoy, Phase investigation of a cobalt base alloy containing Cr, Ni, W and C, Journal of Materials Processing Technology, 74, 1-3 (1998) 137-141
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b8a19769-85a6-4a57-b568-f50565a6cd03
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