PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Phosphogypsum (PG) crystal size distributions in presence and absence of PG seed crystals and sorbitol surfactant

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Leaching of calcium phosphate with sulfuric acid was carried out to study phosphogypsum (PG) crystal growth and size distributions in presence and absence of phosphogypsum seed crystals (PGSC) and sorbitol surfactant (SS) additives. PG crystallization simulates industrial Dihydrate process for phosphoric acid production. PG crystals grow in a medium containing 26±1% P2O5 phosphoric acid and 2±0.5 % free sulfuric acid. Better filterability of phosphoric acid can be achieved with large crystals. The formed PG crystals are larger with addition of either 100 ppm Sorbitol surfactant, 5%, 10% or 15% PGSC compared to the baseline (without additives). With addition of surfactant or increasing the % of PGSC from 5% to 15%, both the mean diameter and d90 of crystalized PG are increased due to enhancing the crystallization growth rates.
Rocznik
Strony
art. no. 193615
Opis fizyczny
Bibliogr. 22 poz., rys., tab., wykr.
Twórcy
  • Central Metallurgical Research and Development Institute (CMRDI), P.O. Box: 87 Helwan, Cairo, Egypt
  • Central Metallurgical Research and Development Institute (CMRDI), P.O. Box: 87 Helwan, Cairo, Egypt
  • Central Metallurgical Research and Development Institute (CMRDI), P.O. Box: 87 Helwan, Cairo, Egypt
  • Department of Chemistry, College of Science, Taif University, P.O. Box 11099, Taif, 21944, Saudi Arabia
Bibliografia
  • ABDEL-AAL E.A., 2004. Crystallization of phosphogypsum in continuous phosphoric acid industrial plant, Crystal Research Technology 39, No. 2, pp.121–128.
  • ABDEL-AAL, E.A., MAHMOUD M.H.H., EL-SHALL H., ISMAIL A.K., 2007. Increasing the filtration rate of phospho-gypsum using surfactant, Hydrometallurgy, Vol. 85, pp. 53-58.
  • ARHOUNI F.E., HAKKAR M., MAHROU A., BELAHBIB L., HANEKLAUS N., PAVON S., BERTAU M., BOUKHAIR A., MAZOUZ H., OUAKKAS S., ABDO M.A.S., BENJELLOUN M., 2022. Better filterability and reduced radioactivity of phosphogypsum during phosphoric acid production in Morocco using a fly ash waste and pure silica additive, Journal of Radioanalytical and Nuclear Chemistry 331, 1609–1617.
  • BADENS E., VEESLER S., BOISTELLE R., 1999. Crystallization of Gypsum from Hemihydrate in Presence of Additives, Journal of Crystal Growth 198/199. pp. 704-709 .
  • BECKER P., (1989). Phosphates and Phosphoric Acid: Raw Materials Technology and Economics of the Wet Processes, Marcel-Dekker Inc., New York.
  • CHOI J., LEE T., CHENG Y., 2019. Observed Crystallization Induction Time in Seeded Gypsum Crystallization, Industrial and Engineering Chemistry Research. 58(51) 23359-23365.
  • DE VREUGD, C.H., WITKAMP, G.J., ROSMALEN, G.M.V., 1994. Growth of gypsum: III. Influence and incorporation of lanthanide and chromium ions. Journal of Crystal Growth, 144, pp. 70–78.
  • EL-SAYED ABDEL-AAL, EMAD ABDEL RAHMAN, ABDEL-HAKIM KANDIL, 2016. ENHANCING FILTRATION RATE OF NEW VALLEY OXIDIZED PHOSPHATE CONCENTRATE WITH ADDITIVES, Physicochem. Probl. Miner. Process. 52(1), 2016, 124−135.
  • EL-SHALL H., JEONL J.-H., ABDEL-AAL E.A., KHAN S., GOWER L. and RABINOVICH Y, 2004. A study of primary nucleation of calcium oxalate monohydrate: II. Effect of urinary species, Cryst. Res. Technol. 39, No. 3, 222 – 229.
  • EL-SHALL H., RASHAD M.M., ABDEL-AAL E.A., 2002. Effect of phosphonate additive on crystallization of gypsum in phosphoric and sulfuric acid medium. Crystal Research and Technology 37 (12), pp. 1264–1273 .
  • EL-SHALL, H., ABDEL-AAL, E. A., and MOUDIGL, B. 1999. Cost Effective Reagents as Defoamers and Crystal Modifiers to Enhance the Filtration of Phosphogypsum. FIPR publication, 01-141.
  • GAYEVSKII V.R., KOCHMARSKII V.Z., GAYEVSKA S.G., 2020. Nucleation and crystal growth of calcium sulfate dihydrate from aqueous solutions: Speciation of solution components, kinetics of growth, and interfacial tension, Journal of Crystal Growth, 548.
  • GEORGIEV C.S., DJAROVA M.D., PETKOVA J.I., KOSEVA N.S., 1995. Effect of Poly (Acrylic-Co-N-Vinylpyrrolidone) on Calcium Oxalate Crystallization, Polymer Journal, 27(4), pp. 441-444 .
  • HAKKAR M., ARHOUNI F. E., MAHROU A., BILAL E., BERTAU M., ROY A., STEINER G., HANEKLAUS N., MAZOUZ H., BOUKHAIR A., BENJELLOUN M., 2021. Enhancing rare earth element transfer from phosphate rock to phosphoric acid using an inexpensive fly ash additive, Minerals Engineering 172, 107166.
  • LIU S.T., NANCOLLAS G.H., (1973). The Crystal Growth of Calcium Sulfate Dihydrate in the Presence of Additives. Journal of Colloid and Interface Science, 44(3), PP.422-429 .
  • NYVLT J., ULRICH J., (1995). Admixtures in Crystallization, Chapter 2, VCH, Weinheim. https://books.google.com.eg/books?hl=en&lr=&id=JaMrS4H4dCwC&oi=fnd&pg=PP2&dq=24.%2509Nyvlt+J.,+Ulrich+J.,+(1995)
  • RABIZADEH T., MORGAN D., PEACOCK C., BENNING L. 2019. Effectiveness of Green Additives vs. Poly(acrylic acid) in Inhibiting Calcium Sulfate Dihydrate Crystallization, Industrial and Engineering Chemistry Research, 58(4) 1561-1569.
  • RASHAD M.M., MAHMOUD M.H.H., IBRAHIM I.A., ABDEL-AAL E.A., 2005. Effect of Citric Acid and 1,2- Dihydroxybenzene 3,5-disulfonic Acid on Crystallization of calcium sulfate dihydrate Under Simulated Conditions of Phosphoric Acid Production, Crystal Research and Technology, 40, No. 8, pp. 741-747.
  • ROCHA S.D.F., CIMINALLI V.S.T., 1995. Effect of surfactants on calcium sulfate crystallization in phosphoric acid solutions, Mining, Metallurgy & Exploration, 12, pp. 166–171.
  • TADROS M.E., MAYES I., 1979. Linear growth rates of calcium sulfate dihydrate crystals in the presence of additives. J. Colloid Interface Science 72, pp. 245–254.
  • TANQUERO J.G., ABDEL-AAL E.A., FARINATO R.S., EL-SHALL H., MOUDGIL B.M., 2022. Inhibition of calcium sulphate hemihydrate crystallization under simulated conditions of phosphoric acid evaporation; Canadian Journal of Chemical Engineering, Canadian Society for Chemical Engineering, https://doi.org/10.1002/cjce.24210 .
  • WANG J., FAN S., HOU S., CHEN R., XIANG L., YANG C., 2019. Effects of Cationic Polyacrylamide on Hydrothermal Formation of Ultralong α-CaSO4.0.5H2O Whiskers; Crystal Research and Technology, 54(4), DOI: 10.1002/crat.201800224.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b834bb1b-61f6-4c62-8555-bb974f37167d
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.