Facile Synthesis and Li-Electroactivity of Cobalt Oxide Based on Resources Recovered from Waste Lithium-Ion Batteries

• Autorzy: Shim Hyun-Woo , Im Byoungyong , Joo Soyeong , Kim Dae-Guen

Identyfikatory

DOI

10.24425/amm.2024.147787

• Języki publikacji: EN

Abstrakty

EN

In this study, cobalt oxide (Co₃O₄) powder was prepared by simple precipitation and heat-treatment process of cobalt sulfate that is recovered from waste lithium-ion batteries (LIBs), and the effect of heat-treatment on surface properties of as-synthesized Co(OH)₂ powder was systematically investigated. With different heat-treatment conditions, a phase of Co(OH)₂ is transformed into CoOOH and Co₃O₄. The result showed that the porous and large BET surface area (ca. 116 m²/g) of Co₃O₄ powder was prepared at 200°C for 12 h. In addition, the lithium electroactivity of Co₃O₄ powder was investigated. When evaluated as an anode material for LIB, it exhibited good electrochemical performance with a specific capacity of about 500 mAh g^-1 at a current density of C/5 after 50 cycles, which indicates better than those of commercial graphite anode material.

Słowa kluczowe

EN

waste lithium-ion battery; recycling; Co3O4 powder; anode material

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2024
• Tom: Vol. 69, iss. 1
• Strony: 67--72
• Opis fizyczny: Bibliogr. 25 poz., fot., rys., tab.

Twórcy

autor

Shim Hyun-Woo

• Resources Utilization Research Division, Korea Institute of Geoscience & Mineral Resources (KIGAM)

• https://orcid.org/0000-0002-6745-9663

autor

Im Byoungyong

• Materials Science and Chemical Engineering Center, Institute for Advanced Engineering (IAE), 51 Goan Rd., Baegam-myeon, Yongin-si, Gyeonggi 17180, Yongin, Republic of Korea
• Sejong University, Department of Nanotechnology and Advanced Materials Engineering, Seoul, Republic of Korea

• https://orcid.org/0000-0002-5197-2702

autor

Joo Soyeong

• Materials Science and Chemical Engineering Center, Institute for Advanced Engineering (IAE), 51 Goan Rd., Baegam-myeon, Yongin-si, Gyeonggi 17180, Yongin, Republic of Korea

• https://orcid.org/0009-0009-5829-1764

autor

Kim Dae-Guen

• Materials Science and Chemical Engineering Center, Institute for Advanced Engineering (IAE), 51 Goan Rd., Baegam-myeon, Yongin-si, Gyeonggi 17180, Yongin, Republic of Korea

• https://orcid.org/0000-0002-2861-8510

Bibliografia

• [1] J.Y. Mo, W. Jeon, Sustainability 10, 2870 (2018).
• [2] C.B. Tabelin, J. Dallas, S. Casanova, T. Pelech, G. Bournival, S. Saydam, Canbulat, I., Miner. Eng. 163, 106743 (2021).
• [3] E.A. Olivetti, G. Ceder, G.G. Gaustad, X. Fu, Joule 1, 229-243 (2017).
• [4] D.L. Thompson, J.M. Hartley, S.M. Lambert, M. Shiref, G.D. Harper, E. Kendrick, P. Anderson, K.S. Ryder, L. Gaines, A.P. Abbott, Green Chem. 22, 7585 (2020).
• [5] C. Peng, K. Lahtinen, E. Medina, P. Kauranen, M. Karppinen, T. Kallio, B.P. Wilson, M. Lundström, J. Power Sources 450, 227630 (2020).
• [6] H. Ali, H.A. Khan, M.G. Pecht, J. Energy Storage 40, 102690 (2021).
• [7] K. Vojisavljević, S. Wicker, I. Can, A. Benčan, N. Barsan, B. Malič, Adv. Powder. Technol. 28, 1118 (2017).
• [8] V. Bhalla, H. Tyagi, Sustain. Energy Technol. Assess. 24, 45 (2017).
• [9] L.D. Kadam, P.S. Patil, Sol. Energy Mater. Sol. Cells 70, 15 (2001).
• [10] C. Yan, Y. Zhu, Y. Li, Z. Fang, L. Peng, X. Zhou, G. Chen, G. Yu, Adv. Funct. Mater. 28, 1705951 (2018).
• [11] H. Wang, L. Zhang, X. Tan, C.M. Holt, B. Zahiri, B.C. Olsen, D. Mitlin, J. Phys. Chem. C 115, 17599 (2011).
• [12] H. Adhikari, M. Ghimire, C.K. Ranaweera, S. Bhoyate, R.K. Gupta, J. Alam, S.R. Mishra, J. Alloys Compd. 708, 628 (2017).
• [13] J. Jiang, W. Shi, S. Song, Q. Hao, W. Fan, X. Xia, X. Zhang, Q. Wang, C. Liu, D. Yan, J. Power Sources 248, 1281 (2014).
• [14] D.Y. Shin, G.H. An, H.J. Ahn, J. Powder Mater. 22 (5), 350 (2015).
• [15] W. Du, R. Liu, Y. Jiang, Q. Lu, Y. Fan, F. Gao, J. Power Sources 227, 101 (2013).
• [16] K. Thangavelu, K. Parameswari, K. Kuppusamy, Y. Haldorai, Mater. Lett. 65, 1482 (2011).
• [17] M. Hassanpour, H. Safardoust-Hojaghan, M. Salavati-Niasari, J. Mol. Liq. 229, 293 (2017).
• [18] Z.Y. Li, P.T. Bui, D.H. Kwak, M.S. Akhtar, O.B. Yang, Ceram. Int. 42, 1879 (2016).
• [19] H.W. Shim, Y.H. Jin, S.D. Seo, S.H. Lee, D.W. Kim, ACS Nano 5, 443 (2011).
• [20] C.M. Hull, J.A. Koza, A. Switzer, J. Mater. Res. 31, 3324 (2016).
• [21] S. Kwon, H.T. Lee, J.H. Lee, Chem. Eur. J. 26, 14359 (2020).
• [22] K.T. Nam, D.W. Kim, P.J. Yoo, C.Y. Chiang, N. Meethong, P.T. Hammond, Y.M. Chiang, A.M. Belcher, Science 312, 885 (2006).
• [23] F. Li, Q.Q. Zou, Y.Y. Xia, J. Power Sources 177, 546 (2008).
• [24] P.L.S.G. Poizot, S. Laruelle, S. Grugeon, L. Dupont, J.M. Tarascon, Nature 407, 496 (2000).
• [25] P.L Taberna, S. Mitra, P. Poizot, P. Simon, J.M. Tarascon, Nat. Mater. 5, 567 (2006).

Uwagi

This work was supported by the Materials & Components Technology Development Program (20011176), funded by the Ministry of Trade, Industry & Energy (MI, Korea), and by the Korea Environmental Industry & Technology Institute (KEITI) grant by the Korean government (Ministry of Environment) (no. 2022003500006, 22-9876).