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Iraqi bauxite ore was used in the manufacturing of geopolymer mortar and concrete. To de-hydroxylate and turn bauxite into an amorphous phase, it was heated to 650 degrees Celsius. Mixing bauxite nanoparticles with an active alkaline solution produces a geopolymer of high grade due to their high efficiency. The nano-bauxite geopolymer mortar is produced following ASTM C109 with various quantities of alkaline solution with molarity (8, 10, 12, and 14). At 3, 7, and 28 days, the maximum compressive strength of mortar with a molarity of 12 was 20.2, 49.7, and 65.3 MPa, respectively. The same quantity of molarity for the mortar was utilized for the production of geopolymer concrete using an alkaline solution. The weight of nano bauxite was substituted for the percentage of nano-glass and carbon nano-tubes that were included in the geopolymer concrete. This resulted in the utilization of nano-glass and carbon nano-tubes, the best ratios are 8% silica merge with 0.01% of carbon nano-tubes. At the age of 28 days, the water absorbency value was found to be 1.78%, and it was noted that the increased compressive strength reached 81.4 MPa. For the polymerization and performance hardening of samples at low temperatures (20±3 °C), geopolymers with nano-bauxite binders were manufactured without heat treatment. The increased compressive strength as well as resistance to freezing and thawing tests are a result of the superior performance and high requirements of nano-materials. XRD examination was performed, many geopolymer phases were generated, and the bond structures between alumina and silica were observed; these results confirm the development of geopolymer.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
305--314
Opis fizyczny
Bibliogr. 20 poz., rys., tab.
Twórcy
autor
- Wasit University, College of Science, Department of Physics, Wasit, Iraq
autor
- Wasit University, College of Science, Department of Physics, Wasit, Iraq
autor
- The University of Technology, Engineering of Materials Department, Baghdad, Iraq
Bibliografia
- 1. Davidovits, J. Geopolymers: Ceramic-like inorganic polymers. J. Ceram. Sci. Technol 2017, 8, 335–350.
- 2. Davidovits, J. Geopolymer Chemistry and Applications. 5-th edition. J. Davidovits. Saint-Quentin, France (Issue January 2008) 2020.
- 3. Kloprogge, J.T.; Ruan, H.D.; Frost, R.L. Thermal decomposition of bauxite minerals: infrared emission spectroscopy of gibbsite, boehmite and diaspore. Journal of Materials Science 2002, 37, 1121–1129.
- 4. Bakhtyar, B.; Kacemi, T.; Nawaz, M.A. A review on carbon emissions in Malaysian cement industry. International Journal of Energy Economics and Policy 2017, 7, 282–286.
- 5. Giacobello, F.; Ielo, I.; Belhamdi, H.; Plutino, M.R. Geopolymers and Functionalization Strategies for the Development of Sustainable Materials in Construction Industry and Cultural Heritage Applications: A Review. Materials 2022, 15, 1725.
- 6. Provis, J.L.; Van Deventer, J.S.J. Geopolymers: structures, processing, properties and industrial applications; Elsevier: 2009.
- 7. Abdullah, M.; Hussin, K.; Bnhussain, M.; Ismail, K.; Ibrahim, W. Mechanism and chemical reaction of fly ash geopolymer cement – a review. Int. J. Pure Appl. Sci. Technol 2011, 6, 35–44.
- 8. Davidovits, J. Geopolymers: man-made rock geosynthesis and the resulting development of very early high strength cement. Journal of Materials Education 1994, 16, 91–91.
- 9. Ding, Y.; Dai, J.-G.; Shi, C.-J. Mechanical properties of alkali-activated concrete: A state-of-the-art. review. Construction and Building Materials 2016, 127, 68–79.
- 10. Davidovits, J. Geopolymer cement. A review. Geopolymer Institute, Technical Papers 2013, 21, 1–11.
- 11. Duxson, P.; Fernández-Jiménez, A.; Provis, J.L.; Lukey, G.C.; Palomo, A.; van Deventer, J.S. Geopolymer technology: the current state of the art. Journal of Materials Science 2007, 42, 2917–2933.
- 12. Davidovits, J. Chemistry of geopolymeric systems, terminology. In: Proceedings of Geopolymer; 9–39.
- 13. Phoo-ngernkham, T.; Chindaprasirt, P.; Sata, V.; Hanjitsuwan, S.; Hatanaka, S. The effect of adding nano-SiO2 and nano-Al2O3 on properties of high calcium fly ash geopolymer cured at ambient temperature. Materials & Design 2014, 55, 58–65.
- 14. Riahi, S.; Nazari, A. The effects of nanoparticles on early age compressive strength of ash-based geopolymers. Elsevier: 2012.
- 15. Li, G. Properties of high-volume fly ash concrete incorporating nano-SiO2. Cement and Concrete Research 2004, 34, 1043–1049.
- 16. Natsuki, T.; Endo, M. Stress simulation of carbon nanotubes in tension and compression. Carbon 2004, 42, 2147–2151.
- 17. Habert, G.; De Lacaillerie, J.D.E.; Roussel, N. An environmental evaluation of geopolymer based concrete production: reviewing current research trends. Journal of Cleaner Production 2011, 19, 1229–1238.
- 18. Rees, C.; Lukey, G.; Van Deventer, J. The role of solid silicates on the formation of geopolymers derived from coal ash. In: Proceedings of International Symposium of Research Students on Material Science and Engineering; 20–22.
- 19. Pacheco-Torgal, F.; Castro-Gomes, J.; Jalali, S. Alkali-activated binders: A review. Part 2. About materials and binders manufacture. Construction and Building Materials 2008, 22, 1315–1322.
- 20. Ng, C.; Alengaram, U.J.; Wong, L.S.; Mo, K.H.; Jumaat, M.Z.; Ramesh, S. A review on microstructural study and compressive strength of geopolymer mortar, paste and concrete. Construction and Building Materials 2018, 186, 550–576.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b7d4c3cf-28ed-4888-b38b-3ffc9c81f35b