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The influence of hydrodynamic conditions on the recovery of acetone, butanol and ethanol in pervaporation membrane modules

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In order to assess the influence of hydrodynamic effects on the recovery of n-butanol by means of pervaporation, a commercial PERVAP 4060 membrane was investigated. Laboratory pervaporation experiments were carried out providing a comparison of the permeation fluxes and enrichment factors. While the enrichment factors achieved in both modules under the same process conditions were comparable, the permeation fluxes differed from each other. In order to explain the observed differences, hydrodynamic conditions in the membrane module were examined by means of CFD simulation performed with ANSYS Fluent 14.5 software. Two different modules having membrane diameters of 80 mm and 150 mm were analyzed. As a result, different velocity profiles were obtained, which served to estimate the mass transfer coefficients of butanol, ethanol and acetone.
Rocznik
Strony
155–--163
Opis fizyczny
Bibliogr. 14 poz., rys.
Twórcy
  • Lodz University of Technology, Faculty of Process and Environmental Engineering, 90-924 Lodz, Wolczanska 213, Poland
autor
  • Lodz University of Technology, Faculty of Process and Environmental Engineering, 90-924 Lodz, Wolczanska 213, Poland
autor
  • Lodz University of Technology, Faculty of Process and Environmental Engineering, 90-924 Lodz, Wolczanska 213, Poland
autor
  • Lodz University of Technology, Faculty of Process and Environmental Engineering, 90-924 Lodz, Wolczanska 213, Poland
Bibliografia
  • 1. Abdehagh N., Tezel F.H., Thibault J., 2014. Separation techniques in butanol production: Challenges and developments. Biomass bioenerg., 60, 222–246. DOI: 10.1515/cpe-2017-0008.
  • 2. Baig F.U., 2008. Pervaporation, In: Li N.N., Fane A.G., Ho W.S.W., Matsuura T. (Eds.), Advanced membranę technology and applications, John Wiley & Sons, Inc., 469–488. DOI: 10.1002/9780470276280.ch17.
  • 3. Baker R.W.,Wijmans J.G., Athayde, A.L., Daniels, R., Ly, J.H., Le, M., 1997. The effect of concentarion polarization on the separation of volatile organic compounds from water by pervaporation. J. Membr. Sci., 137, 159–172. DOI: 10.1016/S0376-7388(97)00189-0.
  • 4. Basile A. Figoli A. Khayet M., 2015. Pervaporation, vapour permeation and membrane distillation, 1st edition, Woodhead Publishing.
  • 5. George S.C., Thomas, S., 2001. Transport phenomena through polymeric systems. Prog. Polym. Sci., 26, 985– 1017. PII: S0079-6700700)00036-8. DOI: 10.1016/S0079-6700(00)00036-8.
  • 6. Hills E., Abraham M.H., Hersey A., Beval C.D., 2011. Diffusion coefficients in ethanol and water at 298 K: Linear free energy relationships. Fluid Phase Equilib., 303, 45–55. DOI: 10.1016/j.fluid.2011.01.002.
  • 7. Huang H.-J., Ramaswamy S., Liu Y., 2014. Separation and purification of biobutanol during bioconversion of biomass. Sep. Pur. Techn., 132, 513–540. DOI: 10.1016/j.seppur.2014.06.013.
  • 8. Krawczyk M., Kaminski K., Petera J., 2012. Experimental and numerical investigation of electrostatic spray liquidliquid extraction with ionic liquidsChem. Process Eng., 33, 167–183. DOI: 10.2478/v10176-012-0015-0.
  • 9. Kubaczka A., KaminskiW., Marszalek J., 2018. Predicting mass fluxes in the pervaporation process using Maxwell–Stefan diffusion coefficients. J. Mem. Sci., 546, 11–119. DOI: 10.1016/j.memsci.2017.08.074.
  • 10. Liu F., Liu L., Feng X., 2005. Separation of acetone-butanol-ethanol (ABE) from dilute aqueous solution by pervaporation. Sep. Pur. Techn., 42, 273–282. DOI: 10.1016/j.seppur.2004.08.005.
  • 11. Marszałek J., Kami´nskiW., 2012. Efficiency of acetone-butanol-ethanol-water system separation by pervaporation. Chem. Process Eng., 33, 131–140. DOI: 10.2478/v10176-012-0012-3.
  • 12. Moraveji M.K., Raisi A., Hosseini S.M., Esmaeeli E., Pazuki G., 2013. CFD modelling of hydrophobic pervaporation process: ethanol/water separation. Desalin. Water Treat., 51, 16–18, 3445–3453. DOI: 10.1080/19443994. 2012.749325.
  • 13. Rousseau R.W., 1987. Handbook of separation process technology. John Wiley & Sons.
  • 14. Schafer T., Crespo J.G., 2007. Study and optimization of hydrodynamic upstream conditions during recovery of a complex aroma profile by pervaporation. J. Membr. Sci., 301, 46–56. DOI: 10.1016/j.memsci.2007.05.034.
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b66af2bc-56ad-436c-a2eb-b227c7f8e268
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