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Wpływ parametrów charakteryzujących wodne roztwory poli(kwasu akrylowego) na dyspersję tlenku żelaza
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Abstrakty
After preparing aqueous suspensions from magnetite particles with a poly-acrylic acid, we investigated the effects of several experimental parameters. We characterized the stability of the suspensions using visual inspection, sedimentation, adsorption, and thermal stability of the dispersant. The dispersion stability is affected by the solution pH, the concentrations of magnetite particles, the molecular weight, the concentration of the dispersants, and the temperature. The stability of the suspensions increased as the concentration of the dispersant and the temperature increased. In terms of the molecular weights of the dispersant, the suspensions with dispersant of low-molecular weight (1800) were more stable than those of high-molecular weight (250000) at room temperature. However, at high temperature the suspensions with high-molecular weight showed stability. The adsorption efficiency of the dispersant was very low. The dispersant of high-molecular weight showed a higher thermal integrity than that of low-molecular weight. From this work, we obtained the optimum conditions for stable aqueous suspensions of magnetite particles.
Wydawca
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Rocznik
Tom
Strony
1561--1564
Opis fizyczny
Bibliogr. 14 poz., rys.
Twórcy
autor
- Nuclear Materials Safety Research Division, Korea Atomic Energy Research Institute, 1045 Daedeok-Daero, Yuseong-Gu, Daejeon 305-353, Republic of Korea
autor
- Nuclear Materials Safety Research Division, Korea Atomic Energy Research Institute, 1045 Daedeok-Daero, Yuseong-Gu, Daejeon 305-353, Republic of Korea
autor
- Nuclear Materials Safety Research Division, Korea Atomic Energy Research Institute, 1045 Daedeok-Daero, Yuseong-Gu, Daejeon 305-353, Republic of Korea
autor
- Nuclear Materials Safety Research Division, Korea Atomic Energy Research Institute, 1045 Daedeok-Daero, Yuseong-Gu, Daejeon 305-353, Republic of Korea
Bibliografia
- [1] K. Fruzzetti, M. Kreider, A. Miller, J. Jevec, P. King, Int. Conf. Water Chem. NRC, (San Francisco, 2004).
- [2] A. Degan, M. Kosed, J. Am. Ceram. Soc. 86, 2001 (2003).
- [3] D. A. Skoog, D. M. West, F. J. Holler, Fundamentals of Analytical Chemistry, 6th Ed. (Harcourt Brace Jovanovich, NewYork, 1992), 118-145.
- [4] J. M. Jevec, P. J. King, K. Fruzzetti, Proc. 11th Int. Symp. on Environ. Degrad. of Mater. in Nucl. Power Syst.-Water React. (Stevenson, 2003).
- [5] J. Cesarano III, I. A. Aksay, J. Am. Ceram. Soc. 71, 250 (1988).
- [6] A. Sehgal, Y. Lalatonne, J.F. Berret, M. Morvan, Langmuir 21, 9359 (2005).
- [7] R. Crovetto, C. J. McDonough, Proc. 10th Int. Symp. on Environ. Degrad. of Mater. in Nucl. Power Syst.-Water React. (Stevenson, 2001).
- [8] A. A. Zaman, R. Tsuchiya, B. M. Moudgil, J. Colloid and Interface. Sci. 256, 73 (2002).
- [9] N. Azema, Powder Technol. 165, 133 (2006).
- [10] G. H. Kirby, D. J. Harris, Q. Li, J. A. Lewis, J. Am. Ceram. Soc. 87, 181 (2004).
- [11] J. A. Lewis, J. Am. Ceram. Soc. 83, 2341 (2000).
- [12] H. Buron, O. Mengual, G. Meunir, I. Cayre, P. Snabre, Poly. Int. 53, 1205 (2004).
- [13] E. H. Lee, M. K. Lee, C. K. Rhee, Mater. Sci. and Eng. A449-451, 765 (2007).
- [14] P. Munk, T. M. Aminabhavi, Introduction to Macromolecular Science, (John Wiley and Sons, New York, 2002), 57-70.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b5ef1622-3e17-4b4f-a059-211881fc8d65