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Mineralogical characteristic and beneficiation evaluation of rare earth carbonate wall rock

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In order to rationalize the development and utilization of the wall rock discarded during rare earth mining, chemical analysis, inductively coupled plasma-atomic emission spectroscopy, X-ray diffraction analysis, artificial panning, optical microscope analysis, mineral liberation analysis and energy-dispersive spectroscopy were used to study the process mineralogy of the wall rock. The results show that the main useful elements in the rare earth wall rock were iron, light rare earth elements, fluorine and niobium. Iron was mainly occurrence as magnetic iron in magnetite, rare earth elements in bastnaesite and monazite, fluorine as a independent mineral in fluorite and niobium in columbite. The main useful minerals were finely disseminated, with magnetite (48.16%), bastnaesite (49.04%), monazite (42.18%), fluorite (39.30%) and columbite (63.26%) distributed in -0.030 mm particle size. The useful minerals were evaluated separately for beneficiation based on the process mineralogical characteristics of the rare earth wall rock, and the results showed that magnetite, rare earth and fluorite resources could be effectively recovered using magnetic separation, flotation, gravity concentration and leaching enrichment methods. The sequential recovery of iron, rare earth, fluorine and niobium elements produces iron concentrate (65.40% TFe at recovery of 38.03%), rare earth concentrate (50.66% REE at recovery of 62.73%), fluorite concentrate (95.23% CaF2 at recovery of 40.34%) and niobium iron ore concentrate (1.63% Nb2O5 at recovery of 5.56%). This study provides recommendations for the rational development and utilization of rare earth wall rock and provides reasonable levels of recovery predictions.
Rocznik
Strony
art. no. 161300
Opis fizyczny
Bibliogr. 20 poz., tab., wykr.
Twórcy
autor
  • Sinosteel Maanshan General Institute of Mining Research Co., Ltd., Maanshan 243000, China
  • National Engineering Research Center of Huawei High Efficiency Cyclic Utilization of Metal Mineral Resources Co., Ltd., Maanshan 243000, China
autor
  • Baotou Steel Group Mining Institute (Co., Ltd.)
  • Sinosteel Maanshan General Institute of Mining Research Co., Ltd., Maanshan 243000, China
  • National Engineering Research Center of Huawei High Efficiency Cyclic Utilization of Metal Mineral Resources Co., Ltd., Maanshan 243000, China
autor
  • Sinosteel Maanshan General Institute of Mining Research Co., Ltd., Maanshan 243000, China
  • National Engineering Research Center of Huawei High Efficiency Cyclic Utilization of Metal Mineral Resources Co., Ltd., Maanshan 243000, China
autor
  • Sinosteel Maanshan General Institute of Mining Research Co., Ltd., Maanshan 243000, China
  • National Engineering Research Center of Huawei High Efficiency Cyclic Utilization of Metal Mineral Resources Co., Ltd., Maanshan 243000, China
autor
  • Sinosteel Maanshan General Institute of Mining Research Co., Ltd., Maanshan 243000, China
  • National Engineering Research Center of Huawei High Efficiency Cyclic Utilization of Metal Mineral Resources Co., Ltd., Maanshan 243000, China
autor
  • Sinosteel Maanshan General Institute of Mining Research Co., Ltd., Maanshan 243000, China
  • National Engineering Research Center of Huawei High Efficiency Cyclic Utilization of Metal Mineral Resources Co., Ltd., Maanshan 243000, China
Bibliografia
  • OUYANG, H., LIU, Y., 2018. REE mineralization and characteristics of wall rocks in the Muluozhai REE deposit, Mianning county, Sichuan province. Acta Geoscientica Sinica, 39(03), 329-341.
  • POPOVA, Y. A., BYCHKOV, A. Y., MATVEEVA, S. S., SUSHCHEVSKAYA., 2014. Behavior of lanthanides during the formation of the Iul'tin deposit, Chukchi Peninsula. Geochemistry International, 52(12), 1078.
  • BAI, D., YANG, D., LI, J., LIU, J., ZHANG, K., 2021. Geochemical characteristics and geological significance of rare earth elements in fluorite deposits of Heyu ore concentrated area, western Henan province. Chinese Rare Earths, 42(05), 75-84.
  • YU, Y., 2001. Dressing technology of REO ore and its development in China. Journal of China University of Mining & Technology, (06), 11-16.
  • ZHANG, J., HAO, W., QU, Q., 2018. Development status of joint process of rare mineral processing in China. China Mining Magazine, 27(01), 127-131+142.
  • JORDEN, A., CHENG, Y., WATERS, K. E., 2013. A review of the beneficiation of rare earth element bearing minerals. Minerals Engineering, 41, 97-114.
  • BALARAM, V., 2019. Rare earth elements: a review of applications, occurrence, exploration, analysis, recycling, and environmental impact. Geosci Front, 10(4), 1285–1303.
  • BINNEMANNS, K., JONES, P. T., BLANPAIN, B., 2013. A. Walton und M. Buchert. J. Cleaner Prod, 51, 1-22.
  • WANG, Y., LI, Y., CHENG, X., FENG, J., 2021. Experimental study on beneficiation of No.12 vein ore in Weishan rare earth mine. Nonferrous Metals (Mineral Processing Section), (05), 54-59.
  • JHA, M. K., KUMARI, A., PANDA, R., KUMAR, J. R., YOO, K., LEE, J., 2016. Review on hydrometallurgical recovery of rare earth metals. Hydrometallurgy, 165, 2-26.
  • XIAO, Y., CHEN, Y., FENG, Z., HUANG, X., HUANG, L., LONG, Z., CUI, D., 2015. Leaching characteristics of ion-adsorption type rare earths ore with magnesium sulfate. Transactions of nonferrous metals society of China, 25(11), 3784-3790.
  • WANG, S., GUO, K., Qi, S., LU, L., 2018. Effect of frictional grinding on ore characteristics and selectivity of magnetic separation. Minerals Engineering, 122, 251-257.
  • LIU, C., LI, J., TANG, H., GAO, Y., 2014. Research on mineral processing for high silica low grade hematite ore in Xinjiang. Ironmaking & Steelmaking, 41(7), 481-485.
  • GE, X., 2009. Research on beneficiation tests for Masteel Heshangqiao iron ores. Metal Mine, (09), 64-69+116.
  • XIAO, Q., LI, B., LUO, C., YAN, F., 2013. A Review on the development of high pressure roller mill. Advanced Materials Research, 734, 2734-2737.
  • LI, X., LIU, Y., LI, G., LIU, M., LIU, Z., 2014. A new method about the separation and recovery of iron and rare metals from RE-Nb-Fe rough concentrate with low grade. Materials Research and Application, 8(01), 67-72.
  • WANG, W., WANG, Q., LI, E., HOU, S., WANG, J., ZHANG, L., 2021. Experimental study on beneficiation process of a sodium amphibolite low-grade rare earth-iron ore. Mining Research and Development, 41(10), 127-131.
  • GAO, Z., WANG, C., SUN, W., GAO, Y., KOWALCZUK, P., 2021. Froth flotation of fluorite: A review. Advances in Colloid and Interface Science, 290, 102382.
  • KIENKO, L. A., VORONOVA, O. V., 2012. Performance evaluation of comprehensive processing of zinc-fluorite ore in the Voznesensky mining area. Journal of Mining Science, 48(5), 928-933.
  • ZAWALA, J., DRZYMALA, J., MALYSA, K., 2007. Natural hydrophobicity and flotation of fluorite. Physicochemical Problems of Mineral Processing, 41(41), 5-11.
Uwagi
This study was supported by a joint fund project (Progect No. 20ZG054-KKN-40-0004) from Sinosteel Maanshan General Institute of Mining Research Co., Ltd. and Baotou steel Group Mining Institute Co., Ltd.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b5db770a-f35e-4fdf-90e7-c2bed52cd511
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