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Flotation of copper-bearing shale at different pH values of solutions and sodium chloride concentrations

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Języki publikacji
EN
Abstrakty
EN
Flotation of copper-bearing shale in aqueous solutions of NaCl at their different pH values was investigated. The tests were carried out in a laboratory flotation machine. The pH range was between 5 and 10 while NaCl concentrations were 0.5M, 1.0M and 2.0M. It was observed that the flotation recovery of the copper shale was increasing with the increase of pH and concentration of the salt solution. On the basis of thermodynamic and hydrodynamic considerations it was postulated that the increasing surface tension was responsible for better shale flotation observed with increasing salt concentration. The observed improved shale flotation caused by increasing pH is most likely due to changes in the properties of the thin film between particle and bubble including mosaic structure of water on the surface of shale. It was shown that the zeta potential of shale particles, zeta potential of air bubbles, solution surface tension, and shale hydrophobicity were not responsible for the increasing with pH recoveries.
Rocznik
Strony
art. no. 176242
Opis fizyczny
Bibliogr. 28 poz., wykr.
Twórcy
  • Wroclaw University of Science and Technology, Faculty of Geoengineering, Mining and Geology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland
  • Wroclaw University of Science and Technology, Faculty of Geoengineering, Mining and Geology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland
Bibliografia
  • BEATTIE, J., K., DJERDJEV, A., M., GRAY-WEALE, A., KALLAY, N., LUTZENKIRCHEN, J., PREOCˇANIN, T., SELMANI A., 2014. pH and the surface tension of water. Journal of Colloid and Interface Science, 422, 54–57.
  • CASTRO, S., 2018. Physico-chemical factors in flotation of Cu-Mo-Fe ores with seawater: a critical review, Physicochem. Probl. Miner. Process., 54(4), 1223-1236.
  • DRZYMALA, J., 2007. Mineral Processing. Foundations of theory and practice of minerallurgy, Oficyna Wyd. PWr., Wroclaw, 507 pages, http://www.dbc.wroc.pl/dlibra/docmetadata? id=2070&from=publication.
  • GHOSH, L., DAS, K.P, CHATTORAJ, D.K., 1988. Thermodynamics of adsorption of inorganic electrolytes at air/water and oil/water interfaces, Journal of Colloid and Interface Science, 121, 1, 278-288.
  • JONES, G., RAY, W.A., 1941. The surface tension of solutions of electrolytes as a function of the concentration III. Sodium chloride, J. Am. Chem. Soc., 63, 3262–3263, doi:10.1021/ja01857a007.
  • KARWOWSKI, P., 2018. Laboratory data, unpublished.
  • KIEDRACHA, M., DRZYMALA, J., 2016. Flotacja lupka miedzionosnego w zaleznosci od pH regulowanego nietypowymi reagentami, in: Lupek miedzionosny II, Kowalczuk P.B., Drzymala J. (Eds.), WGGG PWr, Wroclaw, 123-126, https://minproc.pwr.edu.pl/ materialy/lupek/lupek1617.pdf.
  • KONOPACKA, Z., ZAGOZDZON, K., 2014. Lupek miedzionosny Legnicko-Glogowskiego Okregu Miedziowego, in: Lupek miedzionosny I, Drzymala J., Kowalczuk P.B. (Eds.), WGGG PWr, Wroclaw, 2014, 7-12, https://minproc.pwr.edu.pl/materialy/lupek/lupek1401.pdf.
  • KOSINSKI, A., RATAJCZAK, T., 2021. Flotacja spieniaczowa lupka miedzionosnego, in: Lupek miedzionosny V, Ratajczak T. (Ed.), WGGG PWr, Wroclaw, 99-102, https://minproc.pwr.edu.pl/materialy/ lupek/lupek2113.pdf.
  • KURNIAWAN, A.U., OZDEMIR, O., NGUYEN, A.V., OFORI P., FIRTH B., 2011. Flotation of coal particles in MgCl2, NaCl, and NaClO3 solutions in the absence and presence of Dowfroth 250, International Journal of Mineral Processing, Volume 98, Issues 3–4, 137-144, https://doi.org/10.1016/j.minpro.2010.11.003.
  • KUKLINSKA, M., RATAJCZAK, T., 2016. Flotacja lupka miedzionosnego w wodnych roztworach soli, in: Lupek miedzionosny II, Kowalczuk P.B., Drzymala J. (Eds.), WGGG PWr, Wroclaw, 184‒187, https://minproc.pwr.edu.pl/materialy/lupek/lupek1629.pdf.
  • LASKOWSKI, J.S., CASTRO, S., 2014. Effect of seawater main components on frothability in the flotation of Cu-Mo sulfide ore, Physicochem. Probl. Miner. Process. 50(1), 17−29.
  • LASKOWSKI, J., CASTRO, S., 2015. Flotation in concentrated electrolyte solutions, International Journal of Mineral Processing, 144, pp 50–55, https://doi.org/10.1016/ j.minpro.2015.09.017.
  • LASKOWSKI, J., 1995. Coal surface chemistry and its effect on fine coal processing, High Efficiency Coal Preparation: An International Symposium, S. K. Kawatra, editor, Littleton, SME, Chapter 14, 163-175.
  • LASKOWSKI, J., 2001. Coal Flotation and Fine Coal Utilization, Developments in Mineral Processing, 14, D.W. Fuerstenau (Advisory Ed.) Elsevier, London.
  • LI, C., SOMASUNDARAN, P., 1992. Reversal of Bubble Charge in Multivalent Inorganic Salt Solutions-Effect of Aluminum, Journal and Colloid Int., 148(2).
  • LIPNIARSKI, M., RATAJCZAK T., DRZYMALA, J., 2015. Weryfikacja hipotez o roli soli we flotacji na przykladzie wegla kamiennego w wodnych roztworach NaCl, i KPF6, W: Mineralurgia i Wykorzystanie Surowcow Mineralnych w ramach III Polskiego Kongresu Gorniczego: materialy konferencyjne, Wroclaw, 14-16.09.2015 /Jan Drzymala, Przemyslaw B. Kowalczuk (Eds.), Wroclaw: Wydzial Geoinzynierii, Gornictwa iGeologii Politechniki Wroclawskiej, 2015. s. 35-39.
  • OZDEMIR, O., 2013. Specific ion effect of chloride salts on collectorless flotation of coal, Physicochem. Probl. Miner. Process. 49(2), 511−524.
  • PAZIK, P.M., DRZYMALA, J., KOWALCZUK, P.B., 2016. Flotacja lupka miedzionosnego w zaleznosci od pH w wodzie technologicznej, in: Lupek miedzionosny II, Kowalczuk P.B., Drzymala J. (Eds.), WGGG PWr, Wroclaw, 118-122, https://minproc.pwr.edu.pl/ materialy/lupek/lupek1616.pdf.
  • PENG, M., RATAJCZAK, T., DRZYMALA, J., 2014. Zeta potential of polish copper-bearing shale in the absence and presence of flotation frothers, Mining Science, 21, 57-63.
  • PAULSON, O., PUGH, R.J., 1996, Flotation of inherently hydrophobic particles in aqueous solutions of inorganic electrolytes, Langmuir, 12, 4808-4813.
  • PUGH, R.J., WEISSENBORN, P., PAULSON, O., 1997. Flotation in inorganic electrolytes: the relationship between recovery of hydrophobic particles, surface tension, bubble coalescence and gas solubility. Int. J. Miner. Process. 51(1-4), 125-138.
  • RATAJCZAK, T., DRZYMALA, J., 2003. Salt flotation, Oficyna Wydawnicza Politechniki Wroclawskiej, Wroclaw, Poland (in Polish).
  • RATAJCZAK, T., KURKIEWICZ, S., DRZYMALA, J., 2020. A procedure of Arrhenius activation energy determination for salt flotation of particles in the vicinity of one molar salt aqueous solutions. Physicochem. Probl. Miner. Process., 56(6), 1-5.
  • RATAJCZAK, T. 2017. Flotation of copper-bearing shale in solutions of inorganic salts and organic reagents. E3S Web of Conferences 18, 01028, https://www.e3s-conferences.org/articles/e3sconf/pdf/2017/06/e3sconf_ mec2017_01028.pdf
  • SMOLSKA, M., RATAJCZAK, T., 2017. Flotacja mechaniczna lupka miedzionosnego we flotowniku Hallimonda w roztworach soli podwyzszajacych i obnizajacych napiecie powierzchniowe wody, in: Lupek miedzionosny III, Kowalczuk P.B., Drzymala J. (Eds.), WGGG PWr, Wroclaw, 97-102, https://minproc.pwr.edu.pl/ materialy/lupek/lupek1710.pdf.
  • SWEBODZINSKA, A., KOWALCZUK, P.B., 2016. Naturalna flotacja i hydrofobowosc lupka miedzionosnego w zaleznosci od pH, W: Lupek miedzionosny II, Kowalczuk P.B., Drzymala J. (Eds.), WGGG PWr, Wroclaw, 113‒117, http://dx.doi.org/10.5277/lupek1615.
  • ZHANG, H., 2015. Effect of electrolyte addition on flotation response of coal, Physicochem. Probl. Miner. Process. 51(1), 257−267.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b5da93a9-931b-4a9e-ad33-85858702a8e1
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