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This article focuses on an investigation of the optical initiation of the light-sensitive energetic complex perchlorates 3(5)-hydrazino-4-amino- 1,2,4-triazole copper(II) perchlorate and 1-H-5-hydrazinotetrazole mercury(II) perchlorate. It is shown that light emission initiates an explosion in energy-rich formulations (compositions) based on these complexes, EC-1 and EC-2 respectively. It was found that the pyrotechnic formulation EC-2 containing the mercury complex may be used to initiate detonation in highly energetic materials.
Słowa kluczowe
Rocznik
Tom
Strony
671--687
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
autor
- Sarov’ Physics-Technical Institute RNU MIPhI, 607186, Sarov, Russia
- Russian Federal Nuclear Centre – All-Russian Research Institute of Experimental Physics, 607186, Sarov, Russia
- Nizhnyi Novgorod State Technical University, named after R. E. Alekseev, Russia
autor
- Saint-Petersburg State Institute of Technology (Technical University) 190013, Russia
autor
- Russian Federal Nuclear Centre – All-Russian Research Institute of Experimental Physics, 607186, Sarov, Russia
- Nizhnyi Novgorod State Technical University, named after R. E. Alekseev, Russia
autor
- Saint-Petersburg State Institute of Technology (Technical University) 190013, Russia
Bibliografia
- [1] Ilyushin M.A., Tselinskii I.V., Laser Initiation of High-energy-capacity Compounds in Science and Technology, Russ. J. Appl. Chem., 2000, 73(8),1305-1312.
- [2] Tarzhanov V.I., Preexplosion Phenomena in Prompt Initiation of Secondary Explosives (Review), Combust., Explos. Shock Waves (Engl. Transl.), 2003, 39(6), 611-618.
- [3] Bourne N.K., On the Laser Ignition and Initiation of Explosives, Proc. Roy. Society London, A, 2001, 457, 1401-1426.
- [4] Chernay A.V., Sobolev V.V., Chernay V.A., Ilyushin M.A., Bunchuk Yu.P., Ignition of Explosives by Pulse Lasers (in Russian), Ch. 11, in: Physics of Impulse Treatment of Materials (Sobolev V.V., Ed.), Dnepropetrovsk, Art-Press, 2003, pp. 267-314; ISBN 966-7985-42-3.
- [5] Ilyushin M.A., Sudarikov A.M., Tselinsky I.V., Smirnov A.V., Chernay A.V. Shugalei I.V., Metal Complexes in Energetic Formulations (in Russian), (Tselinsky I.V., Ed.), A.S. Pushkin Leningrad State University, St. Petersburg, 2010; ISBN 978-5-8290-0953-3.
- [6] Golubev V.K., Optical Initiation of Energetic Materials in Science and Technology. An Overview (in Russian), Int. Conf. “Shock Waves in Condensed Matter”, Kiev, Ukraine, 16-21 September, 2012, 425-435; ISBN 978-966-085-3.
- [7] a) Cudzilo S., Szmigielski R., Synthesis and Investigation of some di-(R-1,2,4-triazolo)copper (II) Perchlorates (in Polish), Biuletyn Wojskowej Akademii Technicznej, 2000, 49(12), 5-12; b) Ilyushin M.A., Tselinskiy I.V., Smirnov A.V., Shugalei I.V., Physicochemical Properties and Laser Initiation of a Copper Perchlorate Complex with 3(5)-Hydrazino-4-amino-1,2,4-triazole (HATr) as a Ligand, Cent. Eur. J. Energ. Mater., 2012, 9(1), 279-292.
- [8] Ilyushin M.A., Tselinsky I.V., Method of Preparation of 5-Hydrazinotetrazole Mercury (II) Perchlorate (in Russian), Russian Patent RU 2 225 840 C2, (Cl 7C01 G13/00), 2004.
- [9] a) Iljushin M.A., Ugrjumov I.A., Dolmatov V.Ju., Veretennikova M.V., Initiating Explosive Composition (in Russian), Russian Patent RU 2 309 139 C2, (Cl C06B 43/00; C06B 45/30; C06C 7/00), 2006; b) Chernay A.V., Ilyushin M.A., Sobolev V.V., Chernay V.A., Primary Explosive Formulation (in Ukrainian), Ukrainian Patent 52 997 С2, (Cl С06B 45/00), 2006.
- [10] Ilyushin M.A., Petrova N.A., Tselinsky I.V., The Correlation between Thermal Decomposition and Laser Ignition Parameters for Complexes of HAT, Hunneng Cailiao = Chin. J. Energ. Mater., 1993, 1(4), 41-43.
- [11] Ilyushin M.A., Tselinsky I.V., Zhilin A.Yu., Ugryumov I.A., Smirnov A.V., Kozlov A.S., Coordination Complexes as Inorganic Explosives for Initiation Systems, Hunneng Cailiao = Chin. J. Energ. Mater., 2004, 12(1), 15-19.
- [12] Chernay A.V., Sobolev V.V., Chernay V.A., Ilyushin M.A., Dlugashek A., Laser Ignition of Explosive Compositions Based on Di-(3-hydrazino-4-amino-1,2,4-triazole)-copper(II) Perchlorate, Combust., Explos. Shock Waves (Engl. Transl.), 2003, 39(3), 335-339.
- [13] Ugryumov I.A., Ilyushin M.A., Tselinskii I.V., Kozlov A.S., Synthesis and Properties of Photosensitive Complex Perchlorates of d-Metals with 3(5)-Hydrazino-4-amino-1,2,4-triazole as Ligand, Russ. J. Appl. Chem., 2003, 76(3), 439-441.
- [14] Ilyushin M.A., Tselinskiy I.V., Smirnov A.V., Bachurina I.V., Ostashev V.B., Blagoveschenskiy V.V., Laser Initiation of Light-Sensitive Metal Complexes of 3-Hydrazino-4-amino-1,2,4-triazole (HATr) (in Russian), Proc. SPbSIT (TU), 2012, 13(39), 56-60.
- [15] Ilyushin M.A., Tselinsky I.V., Ugryumov I.A., Dolmatov V.Yu., Shugalei I.V., Study of Submicron Structured Energetic Coordination Metal Complexes for Laser Initiation Systems, Cent. Eur. J. Energ. Mater., 2005, 2(1), 21-33.
- [16] Ilyushin M.A., Tselinsky I.V., Bachurina I.V., Seidov E.Ya., Kozlov A.S., Korolev D.V., Olenin A.E., Laser Initiation of Complex Perchlorates of d-Metals with Heterocyclic Ligands , Hunneng Cailiao = Chin. J. Energ. Mater., 2006, 14(6), 401-405.
- [17] Ugryumov I.A., Ilyushin M.A., Tselinsky I.V., Study of Nanostructured Photosensitive Primary Explosives for Laser Initiation Systems, in: Theory and Practice of Energetic Materials, (Huang P., Li S., Wang Y., Eds.), 2003, 5(B), 1151-1153.
- [18] Dilham D., Laser Diode Initiated Systems for Space Applications, The First ESANASA Working Meeting on Optoelectronics: Fiber Optic System Technologies in Space, ESA/ESTEC – October 6, 2005, 1-10.
- [19] Lien Y., Thoen G., Grasvik O., Bru J., Paulsen K., Lierstuen L. O., Chamayou B., Pinard D., McKenzie I., Opto-pyrotechnics for Space Applications, Int. Conf. Space Optics (ICSO), Rhodes, Greece, 4-8 October, 2010, 1-4.
- [20] Hand C.F., Novel 300-watt Single-emitter Laser Diodes for Laser Initiation Applications, Proc. SPIE 7795, Optical Technologies for Arming, Safing, Fuzing and Firing VI, 779507, September 03, 2010.
- [21] Gerasimov S.I., Faikov Yu.I., Kholin S.A., Cumulative Light Sources (in Russian), Sarov, RFNC-VNIIEF, 2002, ISBN 5-85165-639-5.
- [22] Gerasimov S.I., Len A.V., Ilyushin M.A., Kalmykov P.N., Definition of Diversity for Ignition of Light-sensitive Pyrotechnic Composition Pellets with Roentgraphic Method, New Trends Res. Energ. Mater., Proc. Semin., 14th, Pardubice, Czech Republic, April 13-15, 2011, Part 1, 160-162.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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