Prediction of the chromium (III) separation from acidic salt solutions on nanofiltration membranes using donnan and steric partitioning pore (DSP) model

• Autorzy: Kowalik-Klimczak A. , Zalewski M. , Gierycz P.
• Języki publikacji: EN

Abstrakty

EN

This paper presents experimental and modelling analysis of the application of nanofiltration for separation of chromium (III) from acidic salt solution. In the studies commercial nanofiltration HL membrane has been used. The experimental results have been interpreted by, based on the extended Nernst-Planck equation, Donnan and Steric Partitioning Pore (DSP) model. The obtained results showed satisfactory agreement between experimental and modelling data for the pressure range 10-24 bar and different concentrations of chloride and sulfate ions. It means that the DSP model may be helpful for the monitoring of nanofiltration applied to treatment of chromium wastewater.

PL

W pracy przedstawiono doświadczalną i modelową analizę zastosowania nanofiltracji do separacji chromu (III) z kwaśnych roztworów soli. W badaniach użyto komercyjną nanofiltracyjną membranę typu HL. Wyniki badań doświadczalnych zinterpretowano za pomocą modelu Donnana i Przestrzennego Rozkładu Porów (Donnan and Steric Partitioning Pore Model – DSP Model), który oparty jest na rozszerzonym równaniu Nernsta-Plancka. Uzyskane wyniki wykazały zadawalającą zgodność pomiędzy danymi doświadczalnymi i modelowymi dla ciśnienia w zakresie 10-24 bar oraz różnych stężeń jonów chlorkowych i siarczanowych. Oznacza to, że model DSP może być pomocny podczas monitorowania możliwości zastosowania nanofiltracji do oczyszczania ścieków chromowych.

Słowa kluczowe

EN

nanofiltration; DSP model; Cr(III); acidic salt solutions

PL

nanofiltracja; model DSP; Cr(III); kwaśne roztwory soli

• Wydawca: Silesian University of Technology
• Czasopismo: Architecture Civil Engineering Environment
• Rocznik: 2016
• Tom: Vol. 9, no. 3
• Strony: 135--140
• Opis fizyczny: Bibliogr. 25 poz.

Twórcy

autor

Kowalik-Klimczak A.

• Institute for Sustainable Technologies - National Research Institute in Radom, Kazimierza Pułaskiego 6/10, 26-600 Radom, Poland

autor

Zalewski M.

• Faculty of Chemical and Process Engineering, Warsaw University of Technology, Waryńskiego 1, 00-645 Warsaw, Poland

autor

Gierycz P.

• Faculty of Chemical and Process Engineering, Warsaw University of Technology, Waryńskiego 1, 00-645 Warsaw, Poland

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