Quantitative analysis of reaction gases or exhaust using an online process mass spectrometer

• Autorzy: Wei Fu-Qiang , Huang Ze-Jian , Jian You , Dai Xin-Hua , Fang Xiang , Jin Shang-Zhong

Identyfikatory

DOI

10.24425/mms.2023.144874

• Języki publikacji: EN

Abstrakty

EN

Online quantitative analysis of reaction gases or exhaust in industrial production is of great significance to improve the production capacity and process. A novel method is developed for the online quantitative analysis of reaction gases or exhaust using quantitative mathematical models combined with the linear regression algorithm of machine learning. After accurately estimating the component gases and their contents in the reaction gases or exhaust, a ratio matrix is constructed to separate the relevant overlapping peaks. The ratio and calibration standard gases are detected, filtered, normalized, and linearly regressed with an online process mass spectrometer to correct the ratio matrices and obtain the relative sensitivity matrices. A quantitative mathematical model can be established to obtain the content of each component of the reaction gases or exhaust in real time. The maximum quantification error and relative standard deviation of the method are within 0.3% and 1%, after online quantification of the representative yeast fermenter tail gas.

Słowa kluczowe

EN

online quantitative analysis; mass spectrometers; mathematical models; monitoring

• Wydawca: Komitet Metrologii i Aparatury Naukowej PAN
• Czasopismo: Metrology and Measurement Systems
• Rocznik: 2023
• Tom: Vol. 30, nr 2
• Strony: 337--351
• Opis fizyczny: Bibliogr. 21 poz., rys., wykr., wzory

Twórcy

autor

Wei Fu-Qiang

• China Jiliang University, College of Optical and Electronic Technology, Hangzhou, Zhejiang 310018 China

autor

Huang Ze-Jian

• National Institute of Metrology, Technology Innovation Center of Mass Spectrum for State Market Regulation, Center for Advanced Measurement Science, Beijing 100029, China

autor

Jian You

• National Institute of Metrology, Technology Innovation Center of Mass Spectrum for State Market Regulation, Center for Advanced Measurement Science, Beijing 100029, China

autor

Dai Xin-Hua

• National Institute of Metrology, Technology Innovation Center of Mass Spectrum for State Market Regulation, Center for Advanced Measurement Science, Beijing 100029, China

autor

Fang Xiang

• National Institute of Metrology, Technology Innovation Center of Mass Spectrum for State Market Regulation, Center for Advanced Measurement Science, Beijing 100029, China

autor

Jin Shang-Zhong

• China Jiliang University, College of Optical and Electronic Technology, Hangzhou, Zhejiang 310018 China

Bibliografia

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Uwagi

1. This work was supported by the National Key Research and Development Plan of China (2021YFF0600202) and the Key Deployment Project of Center for Ocean Mega-Science, Chinese Academy of Sciences (COMS2020J10).

2. Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).