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Stabilization/solidification of spent grit in fly ash based geopolymers

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Stabilization/solidification (S/S) method is a potential solution for immobilization of heavy metals containing waste. Immobilization of heavy metals from spent grit, waste material from the shipbuilding and ship repair industry, into the fly ash based geopolymers using the S/S method was evaluated. Addition of spent grit in the quantity of 10% of total solid content of geopolymer mixture decreased the compressive strength of fly ash based geopolymers but did not affect the change of geopolymer strength in function of synthesis parameters. TCLP and EN 12457-2 leaching test were used for the evaluation of chemical stability of contaminated geopolymers with respect to the leaching of heavy metals. The both, TCLP and EN 12457 leachates fulfill the maximum acceptable limits for landfill disposal with respect to the heavy metals concentration. The highest concentration of Zn is observed in a both, TCLP and EN 12457 leachates due to the synthesis parameters.
Rocznik
Strony
5--14
Opis fizyczny
Bibliogr. 25 poz., tab., rys.
Twórcy
autor
  • Faculty of Metallurgy and Technology, University of Montenegro, Džordža Vašingtona bb, 81000 Podgorica
autor
  • Faculty of Metallurgy and Technology, University of Montenegro, Džordža Vašingtona bb, 81000 Podgorica
autor
  • Institute of Public Health of Montetegro, Džona Džeksona bb, 81000 Podgorica, Montenegro
autor
  • Faculty of Civil Engineering, University of Montenegro, Džordža Vašingtona bb, 81000 Podgorica, Montenegro
autor
  • Institute of Public Health of Montetegro, Džona Džeksona bb, 81000 Podgorica, Montenegro
Bibliografia
  • [1] DAVIDOVITS J., Geopolymers, inorganic polymeric new materials, J. Therm. Anal., 1991, 37 (8), 1633.
  • [2] DAVIDOVITS J., Application of Ca-based geopolymer with blast furnace slag, a review, 2nd International Slag Valorisation Symposium, Leuven 2011.
  • [3] MARAGKOS I., GIANNOPOULOU I.P., PANIAS D., Synthesis of ferronickel slag-based geopolymers, Mineral. Eng., 2009, 22 (2), 196.
  • [4] BAKHAREV T., Geopolymeric materials prepared using class F fly ash and elevated temperature curing, Cement Concrete Res., 2005, 35 (6), 1224.
  • [5] ANDINI S., CIOFFI R., COLANGELO F., GRIECO T., MONTAGNARO F., SANTORO L., Coal fly ash as raw material for the manufacture of geopolymer-based products, Waste Manage., 2008, 28 (2), 416.
  • [6] PALOMO A., GRUTZECK M.W., BLANCO M.T., Alkali-activated fly ashes. A cement for the future, Cement Concrete Res., 1999, 29 (8), 1323.
  • [7] PANIAS D., GIANNOPOULOU I.P., PERRAKI T., Effect of synthesis parameters on the mechanical properties of fly ash-based geopolymers, Colloid. Surface. A., 301 (1–3) 246.
  • [8] SAGOE-CRENTSIL K., WENG L., Dissolution processes, hydrolysis and condensation reactions during geopolymer synthesis. Part II. High Si/Al ratio systems, J. Mater. Sci., 2007, 42 (9), 3007.
  • [9] LUNA-GALIANO Y., FERNANDEZ PEREIRA C., VALE J., Stabilization/solidification of a municipal solid waste incineration residue using fly ash-based geopolymers, J. Hazard. Mater., 2011, 185 (1), 373.
  • [10] FERNANDEZ PEREIRA C., LUNA Y., QUEROL X., ANTENUCCI D., VALE, J., Waste stabilization/solidification of an electric arc furnace dust using fly ash-based geopolymers, Fuel, 2009, 88 (7), 1185.
  • [11] JAARSVELD VAN J.G.S., DEVENTER VAN J.S.J., The effect of metal contaminants on the formation and properties of waste-based geopolymers, Cement Concrete Res., 1999, 29 (8) 1189.
  • [12] RAM M.S., SINGH L., SURYANARAYANA M.V., ALAM S.T., Effect of iron, nickel, cobalt on bacterial activity and dynamics during anaerobic oxidation of organic matter, Water Air Soil Poll., 2000, 117 (1–4), 305.
  • [13] BURUIANA D.L., BORDE M., Minimization and use of grit waste from surface cleaning operations, Metalurgia Int., 2011, 16 (11), 159.
  • [14] USEPA, 1990. Toxicity Characteristic Leaching Procedure TCLP Fed. Regist., Appendix II. Method 1311, United States Environmental Protection Agency.
  • [15] EULFD, 2002.EN 12457. Characterisation of waste. Leaching. Compliance test for leaching of granular waste materials and sludges. Part 2. One stage batch test at a liquid to solid ratio of 10 L/kg for materials with particle size below 4 mm, European Landfill Directive, European Committee for Standardisation.
  • [16] RATTANASAK U., CHINDAPRASIRT P., Influence of NaOH solution on the synthesis of fly ash geopolymer, Mineral. Eng., 2009, 22 (12), 1073.
  • [17] PANAGIOTOPOULOU C., KONTORI E., PERRAKI T., KAKALI G., Dissolution of aluminosilicate minerals and by-products in alkaline media, J. Mater. Sci., 2007, 42 (9), 2967.
  • [18] PANIAS D., GIANNOPOULOU I.P., PERRAKI T., Effect of synthesis parameters on the mechanical properties of fly ash-based geopolymers, Colloid. Surface. A., 2007, 301 (1–3), 246.
  • [19] LI C., LI Y., SUN H., LI L., The composition of fly ash glass phase and its dissolution properties applying to geopolymeric materials, J. Am. Ceram. Soc., 2011, 94 (6), 1773.
  • [20] DUXSON P., PROVIS J.L., LUKEY G.C., MALLICOAT S.W., KRIVEN W.M., VAN DEVENTER J.S.J., Understanding the relationship between geopolymer composition, microstructure and mechanical properties, Colloid. Surface A, 2005, 269 (1–3), 47.
  • [21] PHAIR J.W., VAN DEVENTER J.S.J., SMITH J.D., Effect of Al source and alkali activation on Pb and Cu immobilisation in fly-ash based geopolymers, Appl. Geochem., 2004, 19 (3), 423.
  • [22] DUXSON P., LUKEY G.C., SEPAROVIC F., VAN DEVENTER J.S.J., Effect of alkali cations on aluminum incorporation in geopolymeric gels, Ind. Eng. Chem. Res., 2005, 44 (4), 832.
  • [23] DUXSON P., PROVIS J.L., LUKEY G.C., VAN DEVENTER J.S.J., 39 K NMR of free potassium in geopolymers, Ind. Eng. Chem. Res., 2006, 45 (26), 9208.
  • [24] ALY Z., VANCE E.R., PERERA D.S., HANNA J.V., GRIFFITH C.S., DAVIS J., DURCE D., Aqueous leachability of metakaolin-based geopolymers with molar ratios of Si/Al = 1.5–4, J. Nucl. Mater., 2008, 378 (2), 172.
  • [25] IZQUIERDO M., QUEROL X., DAVIDOVITS J., ANTENUCCI D., NUGTEREN H., FERNANDEZ PEREIRA C., Coal fly ash–slag based geopolymers. Microstructure and metal leaching, J. Hazard. Mater., 2009, 166 (1), 561.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b3844a6c-eb52-46b3-8131-f2cd2ddbfe4f
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