Comparative Analysis and Kinetic Modeling of Marbofloxacin Degradation via Electro-Fenton and Biodegradation Optimization

• Autorzy: Hakami Rabab A. , Yahya Muna Shueai , Bakkali Mohamed , Hakami Afnan A.
• Języki publikacji: EN

Abstrakty

EN

In the quest for sustainable water purification methods, electrochemical Advanced Oxidation Processes (AOPs) emerge as pivotal strategies against organic pollutants. This study delves into the efficacy of the Electro-Fenton process, a distinguished AOP that leverages the in-situ generation of hydroxyl radicals (•OH) via the electrochemical reduction of oxygen. By conducting systematic experiments in deionized water, we evaluate the influence of catalyst concentration, applied current density, and cathode material selection on the degradation kinetics of marbofloxacin – a model pharmaceutical pollutant. Employing advanced statistical and kinetic modeling, our investigation reveals critical insights into the process dynamics, uncovering the nuanced interplay between operational parameters and degradation efficiency. The findings substantiate the Electro-Fenton process as an environmentally advantageous and effective solution for water decontamination and advancing the field of water purification technology.

Słowa kluczowe

EN

Electro-Fenton; AOPs; degradation; Marbofloxacin; HPLC

• Wydawca: Politechnika Koszalińska
• Czasopismo: Rocznik Ochrona Środowiska
• Rocznik: 2024
• Tom: Tom 26
• Strony: 638--657
• Opis fizyczny: Bibliogr. 26 poz., rys., tab.

Twórcy

autor

Hakami Rabab A.

• Chemistry Department, Faculty of Science, King Khalid University, Abha, Saudi Arabia

• https://orcid.org/0009-0002-2703-7658

autor

Yahya Muna Shueai

• Department of Chemistry, Faculty of Education, Hodeidah University, Hodeidah, Yemen

• https://orcid.org/0009-0003-4316-0223

autor

Bakkali Mohamed

• Department of Biology, Faculty of Sciences, Ibn Tofail University, Morocco,
• Higher Institute of Nursing Professions and Health Technologies, Kenitra Annex, Morocco

• https://orcid.org/0000-0003-3160-8556

autor

Hakami Afnan A.

• Department of Chemistry, College of Science, Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia

• https://orcid.org/0000-0002-8936-2432

Bibliografia

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• Arhoutane, M.R., Yahya, M.Sh., El Karbane, M., El Kacemi, Kacem. (2019). Oxidative degradation of gentamicin present in water by an electro-Fenton process and biodegradability improvement. Open Chem., 17, 1017-1025. doi.org/10.1515/chem-2019-0110
• Beqqal, N., Yahya, M.S., Karbane, M., Guessous, A., El Kacemi, K. (2017). Kinetic study of the degradation/mineralization of aqueous solutions contaminated with Rosuvastatin drug by Electro-Fenton: Influence of experimental parameters. Journal of Materials and Environmental Sciences, 8(12), 4399-4407.
• Brillas, E., Sirés, I., Oturan, M.A.(2009). Electro-Fenton process and related electrochemical technologies based on Fenton's reaction chemistry. Chemical reviews, 109(12), 6570-6631. https://doi.org/10.1021/cr900136g
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• http://dx.doi.org/10.1016/B978-0-12-813160-2.00008-0
• Özcan, A., Şahin, Y., Koparal, A.S., Oturan, M.A. (2008). Carbon Sponge as a New Cathode Material for the Electro-Fenton Process: Comparison with Carbon Felt Cathode and Application to Degradation of Synthetic Dye Basic Blue 3 in Aqueous Medium. Journal of Electroanalytical Chemistry, 616(1-2), 71-78. http://dx.doi.org/10.1016/j.jelechem.2008.01.002
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• Yahya, M.S., El Karbane, M., Oturan, N., El Kacemi, K., Oturan, M.A. (2015). Mineralization of the antibiotic levofloxacin in aqueous medium by electro-Fenton process: Kinetics and intermediate products analysis. Environmental technology, 37(10), 1276-1287. http://dx.doi.org/10.1080/09593330.2015.1111427
• Yahya, M.S., Oturan, N., El Kacemi, K., El Karbane, M., Aravindakumar, C., Oturan, M.A. (2014). Oxidative degradation study on antimicrobial agent ciprofloxacin by electro-fenton process: Kinetics and oxidation products. Chemosphere, 117, 447-454. http://dx.doi.org/10.1016/j.chemosphere.2014.08.016
• Yang, W.L, Oturan, N., Raffy, S., Zhou, M.H., Oturan, M.A. (2020). Electrocatalytic generation of homogeneous and heterogeneous hydroxyl radicals for cold mineralization of anticancer drug Imatinib. Chemical Engineering Journal, 383, 123155. https://doi.org/10.1016/j.cej.2019.123155
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